Impact of Zr precursor on the electrochemical properties of V2O5 sol-gel films

Impact of Zr precursor on the electrochemical properties of V2O5 sol-gel films

In this work, we explore the impact of Zr precursor on the electrochemical and optical properties of V2O5 thin films. These films were synthesized by the combination of the sol-gel route with dip-coating deposition on the electron conducting (fluorine tin oxide; FTO) substrate. We used vanadium oxyt...

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Bibliographic Details
Published in:Journal of electroanalytical chemistry (Lausanne, Switzerland) Vol. 839; pp. 67 - 74
Main Authors: Loi, Monique R., Moura, Elton A., Westphal, Talita M., Balboni, Raphael. D.C., Gündel, André, Flores, Wladimir H., Pereira, Marcelo B., Santos, Marcos J.L., Santos, Jaqueline F.L., Pawlicka, Agnieszka, Avellaneda, César O.
Format: Journal Article
Language:English
Published: Amsterdam Elsevier B.V 15-04-2019
Elsevier Science Ltd
Subjects:
Acetic acid
Atomic force microscopy
Densification
Deposition
Dip coatings
Discoloration
Electrochemical analysis
Electrochromic cells
Electrochromic properties
Electrochromism
Fluorine
Immersion coating
Microscopy
Morphology
Optical properties
Precursors
Scanning electron microscopy
Sol-gel processes
Spectrum analysis
Substrates
Thin films
Tin oxides
V2O5:ZrO2
Vanadium pentoxide
X-ray diffraction
Zirconium dioxide
Thin films
Electrochromic properties
V2O5:ZrO2
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Summary:In this work, we explore the impact of Zr precursor on the electrochemical and optical properties of V2O5 thin films. These films were synthesized by the combination of the sol-gel route with dip-coating deposition on the electron conducting (fluorine tin oxide; FTO) substrate. We used vanadium oxytriisopropoxide (V) - [OV(OC3H7)3] and zirconium isopropoxide (IV) - [Zr(OCH2CH2CH3)4] as precursors, isopropanol as solvent, and glacial acetic acid as a catalyst. After the deposition, the thin films were subjected to densification at 350°C for 30min. We characterized these films by electrochemical techniques (cyclic voltammetry, chronoamperometry and chronocoulometry) and we obtained the best result of the load density of 109mC·cm−2 for V2O5 sample prepared with 5mol% of Zr precursor; this sample also presented satisfactory responses of cyclic stability. We used atomic force microscopy (AFM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) to obtain morphology and crystallinity of this film. Its optical properties, we studied by UV–vis spectroscopy and the transmittance results were of 82% for the discolored and 39% for colored states, both measured at 633nm. In summary, we show that V2O5:ZrO2 thin films have quite attractive properties for their application as a working electrode in electrochromic devices. [Display omitted] •Different V2O5:ZrO2 thin films were synthesized and characterized.•V2O5 doped with 5 mol% ZrO2 had the best value of charge density of 109 mC/cm2.•The ΔT between colored and discolored states of this film was 43% at 633 nm.•This film had an orthorhombic structure with the preferential (001) orientation in the crystalline plane.•The AFM topography evidenced dense and compact structure and RMS roughness of 7.06 nm.
ISSN:1572-6657
1873-2569
DOI:10.1016/j.jelechem.2019.03.012