Search Results - "Sanoja, Gabriel E."
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Anhydrous Proton Transport in Polymerized Ionic Liquid Block Copolymers: Roles of Block Length, Ionic Content, and Confinement
Published in Macromolecules (12-01-2016)“…Anhydrous proton transport has been investigated in a series of proton conducting polystyrene-block-polymerized ionic liquid (PS-b-PIL) copolymers spanning a…”
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2
Ion Transport in Dynamic Polymer Networks Based on Metal–Ligand Coordination: Effect of Cross-Linker Concentration
Published in Macromolecules (13-03-2018)“…The development of high-performance ion conducting polymers requires a comprehensive multiscale understanding of the connection between ion–polymer…”
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3
Decoupling Bulk Mechanics and Mono- and Multivalent Ion Transport in Polymers Based on Metal–Ligand Coordination
Published in Chemistry of materials (28-08-2018)“…Decoupling bulk mechanics and ion conduction in conventional ion conducting polymers is challenging due to their mutual dependence on segmental chain dynamics…”
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4
Role of Tethered Ion Placement on Polymerized Ionic Liquid Structure and Conductivity: Pendant versus Backbone Charge Placement
Published in ACS macro letters (16-08-2016)“…The role of ion placement was systematically investigated in imidazolium bis(trifluoromethane)sulfonimide (ImTFSI) polymerized ionic liquids (PILs)…”
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5
Structure–Conductivity Relationships of Block Copolymer Membranes Based on Hydrated Protic Polymerized Ionic Liquids: Effect of Domain Spacing
Published in Macromolecules (22-03-2016)“…Elucidating the relationship between chemical structure, morphology, and ionic conductivity is essential for designing novel high-performance materials for…”
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6
Real-Time Early Detection of Crack Propagation Precursors in Delayed Fracture of Soft Elastomers
Published in Physical review. X (01-05-2023)“…The fracture of materials can take place below the critical failure condition via the slow accumulation of internal damage followed by fast crack propagation…”
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7
The Nature of Protein Interactions Governing Globular Protein–Polymer Block Copolymer Self-Assembly
Published in Biomacromolecules (14-04-2014)“…The effects of protein surface potential on the self-assembly of protein–polymer block copolymers are investigated in globular proteins with controlled shape…”
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8
Simple and Accurate Determination of Reactivity Ratios Using a Nonterminal Model of Chain Copolymerization
Published in Macromolecules (13-10-2015)“…We propose a new method for the determination of reactivity ratios based on a nonterminal model of copolymerization kinetics. Within the context of this model,…”
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9
Role of molecular damage in crack initiation mechanisms of tough elastomers
Published in Proceedings of the National Academy of Sciences - PNAS (05-11-2024)“…Tough soft materials such as multiple network elastomers (MNE) or filled elastomers are typically stretchable and include significant energy dissipation…”
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10
Unveiling the Role of Compositional Drifts on the Tack of Pressure‐Sensitive‐Adhesives
Published in Macromolecular chemistry and physics (01-12-2023)“…Pressure‐sensitive‐adhesives (PSAs) are pervasive in electronic, automobile, packaging, and biomedical applications due to their ability to stick to numerous…”
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11
Polymeric multimaterials by photochemical patterning of crystallinity
Published in Science (American Association for the Advancement of Science) (14-10-2022)“…An organized combination of stiff and elastic domains within a single material can synergistically tailor bulk mechanical properties. However, synthetic…”
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12
Digital Light Processing 3D Printing of Soft Semicrystalline Acrylates with Localized Shape Memory and Stiffness Control
Published in ACS applied materials & interfaces (19-07-2023)“…Multimaterial three-dimensional (3D) printing of objects with spatially tunable thermomechanical properties and shape-memory behavior provides an attractive…”
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13
Why is mechanical fatigue different from toughness in elastomers? The role of damage by polymer chain scission
Published in Science advances (15-10-2021)“…Although elastomers often experience 10 to 100 million cycles before failure, there is now a limited understanding of their resistance to fatigue crack…”
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14
Mixed Conductive Soft Solids by Electrostatically Driven Network Formation of a Conjugated Polyelectrolyte
Published in Chemistry of materials (27-02-2018)“…A conjugated polyelectrolyte (poly[2,6-(4,4-bis-potassium butanylsulfonate-4H-cyclopenta-[2,1-b;3,4-b’]-dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)],…”
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15
Decoupling Mechanical and Conductive Dynamics of Polymeric Ionic Liquids via a Trivalent Anion Additive
Published in Macromolecules (28-11-2017)“…The mechanical and conductive properties of a polymeric ionic liquid (PIL) are decoupled through the addition of a fraction of trivalent anions to a chloride…”
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16
Tailoring Network Topology in Mechanically Robust Hydrogels for 3D Printing and Injection
Published in ACS applied materials & interfaces (15-05-2024)“…Tissue engineering and regenerative medicine are confronted with a persistent challenge: the urgent demand for robust, load-bearing, and biocompatible…”
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17
Evolution of the Nanostructure and Viscoelastic Properties of Nitrile Rubber upon Mechanical Rejuvenation and Physical Aging
Published in Macromolecules (23-03-2021)“…Extending the mechanical lifetime of NBR (i.e., poly(acrylonitrile-co-butadiene)), a large-volume synthetic rubber, requires a better understanding of its…”
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18
Impact of Reversible Deactivation Radical Copolymerizations (RDRPs) on Gelation, Phase Separation, and Mechanical Properties of Polymer Networks
Published in Macromolecules (10-09-2024)“…Polymer networks are widely used in engineering and biomedical applications because they can sustain large deformations. However, their mechanical properties,…”
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Tailoring Rate and Temperature-Dependent Fracture of Polyether Networks with Organoaluminum Catalysts
Published in Macromolecules (10-01-2023)“…Polyethers are ubiquitous in engineering and biomedical applications because their oxygen-rich backbone allows them to interact with a variety of polar small…”
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Leveraging Impurities in Macromonomers from Direct-Growth Polymerizations to Produce Supersoft Bottlebrush Networks with Tunable Mechanical Properties
Published in Macromolecules (23-07-2024)“…Bottlebrush polymers are coveted for their supersoft, tissue-like properties. Accordingly, several approaches have emerged to create these materials, yet…”
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