Search Results - "Sankaralingam, Muniyandi"

Alkane and alkene oxidation reactions catalyzed by nickel(II) complexes: Effect of ligand factors by Sankaralingam, Muniyandi, Balamurugan, Mani, Palaniandavar, Mallayan

“…•Introduces the various oxidation reactions catalysed by various nickel(II) complexes.•Ligand stereoelectronic factors affect alkane hydroxylation…”
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Amphoteric reactivity of metal–oxygen complexes in oxidation reactions by Sankaralingam, Muniyandi, Lee, Yong-Min, Nam, Wonwoo, Fukuzumi, Shunichi

“…•Electrophilic reactivity of metal–oxygen complexes.•Nucleophilic reactivity of metal–oxygen complexes.•Tuning the amphoteric reactivity of metal–oxygen…”
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Selective Oxygenation of Cyclohexene by Dioxygen via an Iron(V)-Oxo Complex-Autocatalyzed Reaction by Sankaralingam, Muniyandi, Lee, Yong-Min, Nam, Wonwoo, Fukuzumi, Shunichi

“…An iron complex with a tetraamido macrocyclic ligand, [(TAML)­FeIII]−, was found to be an efficient and selective catalyst for allylic oxidation of cyclohexene…”
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Redox Reactivity of a Mononuclear Manganese-Oxo Complex Binding Calcium Ion and Other Redox-Inactive Metal Ions by Sankaralingam, Muniyandi, Lee, Yong-Min, Pineda-Galvan, Yuliana, Karmalkar, Deepika G, Seo, Mi Sook, Jeon, So Hyun, Pushkar, Yulia, Fukuzumi, Shunichi, Nam, Wonwoo

“…Mononuclear nonheme manganese­(IV)-oxo complexes binding calcium ion and other redox-inactive metal ions, [(dpaq)­MnIV(O)]+-M n+ (1-Mn+, M n+ = Ca2+, Mg2+,…”
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A Manganese(V)–Oxo Complex: Synthesis by Dioxygen Activation and Enhancement of Its Oxidizing Power by Binding Scandium Ion by Hong, Seungwoo, Lee, Yong-Min, Sankaralingam, Muniyandi, Vardhaman, Anil Kumar, Park, Young Jun, Cho, Kyung-Bin, Ogura, Takashi, Sarangi, Ritimukta, Fukuzumi, Shunichi, Nam, Wonwoo

“…A mononuclear non-heme manganese­(V)–oxo complex, [MnV(O)­(TAML)]− (1), was synthesized by activating dioxygen in the presence of olefins with weak allylic C–H…”
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Nickel(II) Complexes of Pentadentate N5 Ligands as Catalysts for Alkane Hydroxylation by Using m-CPBA as Oxidant: A Combined Experimental and Computational Study by Sankaralingam, Muniyandi, Balamurugan, Mani, Palaniandavar, Mallayan, Vadivelu, Prabha, Suresh, Cherumuttathu H.

“…A new family of nickel(II) complexes of the type [Ni(L)(CH3CN)](BPh4)2, where L=N‐methyl‐N,N′,N′‐tris(pyrid‐2‐ylmethyl)‐ethylenediamine (L1, 1),…”
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Tuning the olefin epoxidation by manganese(III) complexes of bisphenolate ligands: effect of Lewis basicity of ligands on reactivity by Sankaralingam, Muniyandi, Palaniandavar, Mallayan

“…A new family of manganese(iii) complexes of the type [Mn(L)Cl], where H2L is 1,4-bis(2-hydroxy-benzyl)-1,4-diazepane (),…”
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A High‐Valent Manganese(IV)–Oxo–Cerium(IV) Complex and Its Enhanced Oxidizing Reactivity by Karmalkar, Deepika G., Sankaralingam, Muniyandi, Seo, Mi Sook, Ezhov, Roman, Lee, Yong‐Min, Pushkar, Yulia N., Kim, Won‐Suk, Fukuzumi, Shunichi, Nam, Wonwoo

“…A mononuclear nonheme manganese(IV)–oxo complex binding the Ce4+ ion, [(dpaq)MnIV(O)]+–Ce4+ (1‐Ce4+), was synthesized by reacting [(dpaq)MnIII(OH)]+ (2) with…”
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Mixed ligand nickel(II) complexes as catalysts for alkane hydroxylation using m-chloroperbenzoic acid as oxidant by Sankaralingam, Muniyandi, Vadivelu, Prabha, Suresh, Eringathodi, Palaniandavar, Mallayan

“…A series of mixed ligand nickel(II) complexes has been isolated and studied as catalysts for alkane hydroxylation reaction using m-CPBA as oxidant. The π-back…”
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A Manganese(V)–Oxo Tetraamido Macrocyclic Ligand (TAML) Cation Radical Complex: Synthesis, Characterization, and Reactivity Studies by Karmalkar, Deepika G., Li, Xiao‐Xi, Seo, Mi Sook, Sankaralingam, Muniyandi, Ohta, Takehiro, Sarangi, Ritimukta, Hong, Seungwoo, Nam, Wonwoo

“…A mononuclear manganese(V)–oxo complex with tetraamido macrocyclic ligand (TAML), [MnV(O)(TAML)]− (1), is a sluggish oxidant in oxidation reactions. Herein, a…”
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Investigation of structural dynamics of Thrombocytopenia Cargeeg mutants of human apoptotic cytochrome c: A molecular dynamics simulation approach by Muneeswaran, Gurusamy, Kartheeswaran, Subramanian, Pandiaraj, Manickam, Muthukumar, Kaliappan, Sankaralingam, Muniyandi, Arunachalam, Saravanavadivu

“…Naturally occurring mutations to cytochrome c (cyt-c) have been identified recently in patients with mild autosomal dominant thrombocytopenia (low platelet…”
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Molecular dynamics simulation approach to explore atomistic molecular mechanism of peroxidase activity of apoptotic cytochrome c mutants by Muneeswaran, Gurusamy, Pandiaraj, Manickam, Kartheeswaran, Subramanian, Sankaralingam, Muniyandi, Muthukumar, Kaliappan, Karunakaran, Chandran

“…Mutations in cytochrome c (Cyt c) have been reported in tuning peroxidase activity, which in-turn cause Cyt c release from mitochondria and early apoptosis…”
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Rational Design of First-Row Transition Metal Complexes as the Catalysts for Oxidation of Arenes: A Homogeneous Approach by Rajeev, Anjana, Balamurugan, Mani, Sankaralingam, Muniyandi

“…Researchers have always been intrigued by one-step selective hydroxylation of aromatic compounds since achieving adequate selectivity toward the target product…”
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Copper(II) complex of pentadentate N5 ligand as catalyst for 2-aminophenol oxidation by Mohammed, Thasnim P, Roy, Sharmi, Sankaralingam, Muniyandi

“…[Display omitted] •Design and synthesis of copper(II) complex of nitrogen containing pentadentate ligand.•Characterization copper(II) complex using modern…”
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Selective synthesis of cyclic alcohols from cycloalkanes using nickel(ii) complexes of tetradentate amidate ligands by Rajeev, Anjana, Muthuramalingam, Sethuraman, Sankaralingam, Muniyandi

“…Selective functionalisation of hydrocarbons using transition metal complexes has evoked significant research interest in industrial chemistry. However,…”
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Biological activity of copper porphyrins by Das, Athulya, Mohammed, Thasnim P, Sankaralingam, Muniyandi

“…[Display omitted] •Introduces the importance of copper and porphyrins in biomedical applications.•All the applications are divided into subsections after…”
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Biomimetic Methodology as a Sustainable Tool for Enhanced Photocatalytic Reduction of CO2 by Kandy, Mufeedah Muringa, Mohammed, Thasnim P, George, Akhila, Sankaralingam, Muniyandi

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Deciphering the Mechanism of MRSA Targeting Copper(II) Complexes of NN2 Pincer-Type Ligands by Das, Athulya, Sangavi, Ravichellam, Gowrishankar, Shanmugaraj, Kumar, Rajesh, Sankaralingam, Muniyandi

“…WHO lists AMR as one of the top ten global public health issues. Therefore, constant effort is needed to develop more efficient antimicrobial drugs. As a…”
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Deciphering the Mechanism of MRSA Targeting Copper(II) Complexes of NN 2 Pincer-Type Ligands by Das, Athulya, Sangavi, Ravichellam, Gowrishankar, Shanmugaraj, Kumar, Rajesh, Sankaralingam, Muniyandi

“…WHO lists AMR as one of the top ten global public health issues. Therefore, constant effort is needed to develop more efficient antimicrobial drugs. As a…”
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Electrocatalytic production of hydrogen using nickel complexes with tridentate N3 ligands by Patra, Suman, Das, Athulya, Bhunia, Sarmistha, Rajeev, Anjana, Sankaralingam, Muniyandi

“…The octahedrally coordinated nickel(II) complexes of the type [Ni(L)2](ClO4)2 (1, 2) have been isolated and characterised, where L is (pyridin-2-ylmethyl)amine…”
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