Search Results - "Sandzhieva, Maria A"
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Reactions of 3,3,3-Trihalogeno-1-nitropropenes with Arenes in the Superacid CF3SO3H: Synthesis of (Z)‑3,3,3-Trihalogeno-1,2-diarylpropan-1-one Oximes and Study on the Reaction Mechanism
Published in Journal of organic chemistry (07-09-2018)“…3,3,3-Trihalogeno-1-nitropropenes C(Hal3)CHCH(NO2) (Hal = F, Cl, Br) in reaction with arenes in the superacid CF3SO3H (TfOH) at room temperature in 1 h…”
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Friedel–Crafts Alkylation of Arenes with 2‑Halogeno-2-CF3‑styrenes under Superacidic Conditions. Access to Trifluoromethylated Ethanes and Ethenes
Published in Journal of organic chemistry (17-06-2016)“…The formation of the corresponding benzyl cations [ArHC+–CH(X)CF3] takes place under protonation of E-/Z-2-halogeno-2-CF3 styrenes [ArCHC(X)CF3, X = F,…”
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Reactions of 3,3,3-Trihalogeno-1-nitropropenes with Arenes in the Superacid CF 3 SO 3 H: Synthesis of ( Z)-3,3,3-Trihalogeno-1,2-diarylpropan-1-one Oximes and Study on the Reaction Mechanism
Published in Journal of organic chemistry (07-09-2018)“…3,3,3-Trihalogeno-1-nitropropenes C(Hal )CH═CH(NO ) (Hal = F, Cl, Br) in reaction with arenes in the superacid CF SO H (TfOH) at room temperature in 1 h afford…”
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Protonation and transformations of α-diazo-β-dicarbonyl compounds in superacids: generation of the strongest carbon-centered cationic electrophiles at the protonation of diazomalonates in Friedel–Crafts reactions
Published in Tetrahedron (11-08-2016)“…Protonation of diazodiketones N2C(COR)2 in Brønsted superacids (TfOH, FSO3H, TfOH–SbF5) gives rise to stable and non-reactive O,O-diprotonated at carbonyl…”
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