Search Results - "Sandmeier, Tobias"
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1
Total Synthesis of (±)-Hippolachnin A
Published in Angewandte Chemie International Edition (16-02-2015)“…The first total synthesis of the marine polyketide (±)‐hippolachnin A has been achieved in nine linear steps and an overall yield of 9 %. Rapid access to the…”
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2
Algorithm-Based Hearing and Speech Therapy Rehabilitation after Cochlear Implantation
Published in Brain sciences (29-04-2022)“…Due to the changes in the indication range for cochlear implants and the demographic development towards an aging society, more and more people are in receipt…”
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3
Enantioselective Synthesis of Cyclic Nitrones by Chemoselective Intramolecular Allylic Alkylation of Oximes
Published in Angewandte Chemie International Edition (26-04-2021)“…The enantio‐ and chemoselective iridium‐catalyzed N‐allylation of oximes is described for the first time. Intramolecular kinetic resolution provides access to…”
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4
Stereodivergent Dual Catalytic α-Allylation of Protected α-Amino- and α-Hydroxyacetaldehydes
Published in Angewandte Chemie International Edition (23-11-2015)“…Fully stereodivergent dual‐catalytic α‐allylation of protected α‐amino‐ and α‐hydroxyacetaldehydes is achieved through iridium‐ and amine‐catalyzed…”
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Journal Article -
5
Enantio- and Chemoselective Intramolecular Iridium-Catalyzed O‑Allylation of Oximes
Published in Organic letters (02-04-2021)“…A method for the enantio- and chemoselective iridium-catalyzed O-allylation of oximes is described. Kinetic resolution in an intramolecular setting provides…”
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6
Stereoselective Synthesis of Piperidines by Iridium‐Catalyzed Cyclocondensation
Published in Angewandte Chemie International Edition (11-09-2017)“…An iridium‐catalyzed cyclocondensation of amino alcohols and aldehydes is reported. Intramolecular allylic substitution by an enamine intermediate and…”
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7
Enantioselective Iridium-Catalyzed α‑Allylation with Aqueous Solutions of Acetaldehyde
Published in Organic letters (07-02-2020)“…The enantioselective α-allylation of aqueous solutions of acetaldehyde using iridium- and amine-catalyzed substitution of racemic allylic alcohols is…”
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8
Derailed Ohira‐Bestmann Reaction of γ,δ‐Unsaturated Aldehydes for the Stereoselective Synthesis of Cyclopenta[c]pyrazoles
Published in Helvetica chimica acta (01-06-2020)“…The synthesis of cyclopenta[c]pyrazoles from γ,δ‐unsaturated aldehydes by a domino sequence involving one‐carbon homologation and intramolecular azomethine…”
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9
Iridium-Catalyzed Enantioselective Allylic Substitution with Aqueous Solutions of Nucleophiles
Published in Journal of the American Chemical Society (07-08-2019)“…The iridium-catalyzed asymmetric allylic substitution under biphasic conditions is reported. This approach allows the use of various unstable and/or volatile…”
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10
Derailed Ohira‐Bestmann Reaction of γ,δ‐Unsaturated Aldehydes for the Stereoselective Synthesis of Cyclopentapyrazoles
Published in Helvetica chimica acta (01-06-2020)“…The synthesis of cyclopenta[c]pyrazoles from γ,δ‐unsaturated aldehydes by a domino sequence involving one‐carbon homologation and intramolecular azomethine…”
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Journal Article -
11
Dynamic crosslinking compatibilizes immiscible mixed plastics
Published in Nature (London) (27-04-2023)“…The global plastics problem is a trifecta, greatly affecting environment, energy and climate 1 – 4 . Many innovative closed/open-loop plastics recycling or…”
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12
Stereodivergent Dual Catalytic [alpha]-Allylation of Protected [alpha]-Amino- and [alpha]-Hydroxyacetaldehydes
Published in Angewandte Chemie International Edition (23-11-2015)“…Fully stereodivergent dual-catalytic [alpha]-allylation of protected [alpha]-amino- and [alpha]-hydroxyacetaldehydes is achieved through iridium- and…”
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Journal Article -
13
Enantioselective Synthesis of Cyclic Nitrones by Chemoselective Intramolecular Allylic Alkylation of Oximes
Published in Angewandte Chemie (26-04-2021)“…The enantio‐ and chemoselective iridium‐catalyzed N‐allylation of oximes is described for the first time. Intramolecular kinetic resolution provides access to…”
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Journal Article -
14
Total Synthesis of (±)-HippolachninA
Published in Angewandte Chemie International Edition (16-02-2015)“…The first total synthesis of the marine polyketide (±)-hippolachninA has been achieved in nine linear steps and an overall yield of 9%. Rapid access to the…”
Get full text
Journal Article -
15
Stereoselective Synthesis of Piperidines by Iridium‐Catalyzed Cyclocondensation
Published in Angewandte Chemie (11-09-2017)“…An iridium‐catalyzed cyclocondensation of amino alcohols and aldehydes is reported. Intramolecular allylic substitution by an enamine intermediate and…”
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Journal Article -
16
Stereodivergent Dual Catalytic [alpha]-Allylation of Protected [alpha]-Amino- and [alpha]-Hydroxyacetaldehydes
Published in Angewandte Chemie (23-11-2015)“…Fully stereodivergent dual-catalytic [alpha]-allylation of protected [alpha]-amino- and [alpha]-hydroxyacetaldehydes is achieved through iridium- and…”
Get full text
Journal Article -
17
Total Synthesis of (±)-HippolachninA
Published in Angewandte Chemie (16-02-2015)“…The first total synthesis of the marine polyketide (±)-hippolachninA has been achieved in nine linear steps and an overall yield of 9%. Rapid access to the…”
Get full text
Journal Article -
18
Total Synthesis of (±)-Hippolachnin A
Published in Angewandte Chemie (16-02-2015)“…The first total synthesis of the marine polyketide (±)‐hippolachnin A has been achieved in nine linear steps and an overall yield of 9 %. Rapid access to the…”
Get full text
Journal Article -
19
Stereodivergent Dual Catalytic α-Allylation of Protected α-Amino- and α-Hydroxyacetaldehydes
Published in Angewandte Chemie (23-11-2015)“…Fully stereodivergent dual‐catalytic α‐allylation of protected α‐amino‐ and α‐hydroxyacetaldehydes is achieved through iridium‐ and amine‐catalyzed…”
Get full text
Journal Article