Search Results - "Sandee, Albertus J"
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Application of a Supramolecular‐Ligand Library for the Automated Search for Catalysts for the Asymmetric Hydrogenation of Industrially Relevant Substrates
Published in Chemistry : a European journal (05-10-2009)“…A procedure is described for the automated screening and lead optimization of a supramolecular‐ligand library for the rhodium‐catalyzed asymmetric…”
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METAMORPhos: Adaptive Supramolecular Ligands and Their Mechanistic Consequences for Asymmetric Hydrogenation
Published in Angewandte Chemie (International ed.) (14-04-2008)“…Adapt to react: METAMORPhos ligands are a class of flexible and adaptive hydrogen‐bonded multidentate sulfonamide‐based phosphorus ligands. Selective formation…”
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Phosphinoureas: Cooperative Ligands in Rhodium-Catalyzed Hydroformylation? On the Possibility of a Ligand-Assisted Reductive Elimination of the Aldehyde
Published in Organometallics (14-06-2010)“…We report the synthesis of a novel type of phosphinourea ligand, its coordination chemistry with rhodium, its use in the asymmetric hydroformylation of…”
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A Silica-Supported, Switchable, and Recyclable Hydroformylation−Hydrogenation Catalyst
Published in Journal of the American Chemical Society (05-09-2001)“…A homogeneous hydroformylation catalyst, designed to produce selectively linear aldehydes, was covalently tethered to a polysilicate support. The immobilized…”
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Asymmetric Hydroformylation Using Taddol-Based Chiral Phosphine−Phosphite Ligands
Published in Organometallics (25-01-2010)“…A small library of 17 modular and easily accessible phenol-derived chiral phosphine−phosphite ligands was evaluated in the asymmetric Rh-catalyzed…”
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Solution-Processible Conjugated Electrophosphorescent Polymers
Published in Journal of the American Chemical Society (09-06-2004)“…We report the synthesis and photophysical study of a series of solution-processible phosphorescent iridium complexes. These comprise bis-cyclometalated iridium…”
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Ureaphosphanes as Hybrid, Anionic or Supramolecular Bidentate Ligands for Asymmetric Hydrogenation Reactions
Published in European Journal of Inorganic Chemistry (01-07-2010)“…We report the coordination behavior of ureaphosphane ligand 1‐[2‐(diphenylphosphanyl)ethyl]‐3‐phenylurea (L1) towards different rhodium precursor complexes…”
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Sulfonamido−Phosphoramidite Ligands in Cooperative Dinuclear Hydrogenation Catalysis
Published in Journal of the American Chemical Society (20-05-2009)“…Sulfonamido−phosphoramidite ligands lead to the formation of Rh−Rh dinuclear complexes through the anionic P−N− bridging character. The resulting “boat-shaped”…”
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A Robust, Environmentally Benign Catalyst for Highly Selective Hydroformylation
Published in Angewandte Chemie International Edition (02-11-1999)“…By a sol–gel process a rhodium complex containing a diphosphane with a large natural P‐Rh‐P bite angle is covalently anchored in a silica matrix (see picture)…”
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Xantphos-based, silica-supported, selective, and recyclable hydroformylation catalysts: a review
Published in Journal of molecular catalysis. A, Chemical (31-05-2002)“…Immobilization on silica of selective homogeneous hydroformylation catalysts based on xanthene ligands is reviewed. Various immobilized catalysts are compared,…”
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Synthesis of Host Polymers and Guests for Electrophosphorescence
Published in Macromolecular research (01-03-2007)“…Significant progress has been realized in the design and synthesis of light emitting polymers that emit over the entire visible spectrum. However, up to…”
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Silica immobilised palladium phosphine complexes as recyclable, regioselective catalysts for the allylic alkylation
Published in Journal of molecular catalysis. A, Chemical (31-05-2002)“…The covalent immobilisation of palladium phosphine complexes on silica is demonstrated to be a viable method for the recovery of allylic alkylation catalysts…”
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ROTACAT: A Rotating Device Containing a Designed Catalyst for Highly Selective Hydroformylation
Published in Advanced synthesis & catalysis (26-02-2001)“…A novel concept is presented for the immobilization of a homogeneous catalyst. A hydroformylation catalyst was covalently anchored to monoliths that were…”
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Synthesis of Host Polymers and Guests for Electrophosphorescence
Published in Macromolecular research (2007)Get full text
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Supramolecular Hydrogen-Bonding Tautomeric Sulfonamido-Phosphinamides: A Perfect P-Chirogenic Memory
Published in European Journal of Inorganic Chemistry (01-01-2012)“…P‐chirogenic, supramolecular hydrogen‐bonding C1‐symmetrical sulfonamido–phosphinamides (METAMORPhos) have been successfully prepared. They were all found to…”
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Book Review Journal Article -
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Phenol-derived chiral phosphine–phosphite ligands in the rhodium-catalyzed enantioselective hydrogenation of functionalized olefins
Published in Tetrahedron: asymmetry (25-11-2010)“…A set of 15 chiral Taddol- and Binol-based phosphine–phosphite ligands were tested in the Rh-catalyzed asymmetric hydrogenation of three olefins, methyl…”
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Solid-Phase Synthesis of Homogeneous Ruthenium Catalysts on Silica for the Continuous Asymmetric Transfer Hydrogenation Reaction
Published in Chemistry : a European journal (16-03-2001)“…The solid‐phase synthesis of new asymmetric transfer hydrogenation catalysts as well as the use of these silica supported systems in batch and flow reactors is…”
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METAMORPhos: Adaptive Supramolecular Ligands and Their Mechanistic Consequences for Asymmetric Hydrogenation
Published in Angewandte Chemie (14-04-2008)“…Anpassungsfähig: METAMORPhos‐Liganden sind eine Klasse von flexiblen und adaptiven wasserstoffverbrückten mehrzähnigen Phosphorliganden mit Sulfonamidfunktion…”
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Diversity in Complexation of [RhI(cod)]+ and [IrI(cod)]+ by Pyridine-Amine-Pyrrole Ligands
Published in European journal of inorganic chemistry (01-09-1999)“…Complexation of [RhI(cod)]+ and [IrI(cod)]+ by the new pyridine‐amine‐pyrrole ligands Py–CH2–N(R)–CH2–Pyr–H (HLR; R = H, Bzl, Bu) and the corresponding…”
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METAMORPhos: Adaptive Supramolecular Ligands and Their Mechanistic Consequences for Asymmetric Hydrogenation
Published in Angewandte Chemie (14-04-2008)Get full text
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