Search Results - "Sajjad, M. Arif"

Steric and Electronic Manipulation of the Agostic and π‐Syndetic Donations in a Known Iminophosphane Ni(II) Complex Containing a Rotatable In‐Plane Aromatic Ring by Sajjad, M. Arif, Schwerdtfeger, Peter, Harrison, John A., Nielson, Alastair J.

“…Density functional theory (DFT) calculations show that in a known nickel(II) complex containing a chelating iminophosphane ligand, where a pendant aromatic…”
Get full text

A Gold(I)–Acetylene Complex Synthesised using Single‐Crystal Reactivity by Johnson, Chloe L., Storm, Daniel J., Sajjad, M. Arif, Gyton, Matthew R., Duckett, Simon B., Macgregor, Stuart A., Weller, Andrew S., Navarro, Miquel, Campos, Jesús

“…Using single‐crystal to single‐crystal solid/gas reactivity the gold(I) acetylene complex [Au(L1)(η2‐HC≡CH)][BArF4] is cleanly synthesized by addition of…”
Get full text

Bis‐Anagostic Structures in N,N’‐Chelate Ligand Complexes of Palladium(II) by Sajjad, M. Arif, Schwerdtfeger, Peter, Cai, Yichao, Waters, Joyce M., Harrison, John A., Nielson, Alastair J.

“…Reaction of N,N’‐dibenzylidene‐2,2‐dimethylpropylenediamine with Pd(OAc)2 produces essentially one product which NMR spectroscopy indicates has a bis‐anagostic…”
Get full text

Electronic and Steric Manipulation of the Preagostic Interaction in Isoquinoline Complexes of RhI by Nielson, Alastair J., Harrison, John A., Sajjad, M. Arif, Schwerdtfeger, Peter

“…Structures and properties were obtained by density functional calculations for the complexes [RhCl(CO)2(L)] (L = isoquinoline ligands) containing close Rh····H…”
Get full text

Weak M···H–C Interactions in Neutral Complexes, Anions and Cations of Palladium(II) and Rhodium(I) Containing the iso‐Quinoline Ligand – Anagostic or Preagostic? by Sajjad, M. Arif, Schwerdtfeger, Peter, Harrison, John A., Nielson, Alastair J.

“…DFT‐D calculations show that the above‐plane M···H–C separations in square‐planar complexes of PdII and RhI containing the iso‐quinoline ligand are influenced…”
Get full text

Steric and Electronic Manipulation of the Anagostic Interaction in 1-Tetralone Oxime and Imine Complexes of Rhodium(I) by Harrison, John A., Nielson, Alastair J., Sajjad, M. Arif, Saunders, Graham C., Schwerdtfeger, Peter

“…Structures and properties for the complexes [RhCl(CO)2(L)] (L = 1‐tetralone oximes and imines) containing anagostic C–H separations were obtained from density…”
Get full text

A Gold(I)–Acetylene Complex Synthesised using Single‐Crystal Reactivity by Johnson, Chloe L., Storm, Daniel J., Sajjad, M. Arif, Gyton, Matthew R., Duckett, Simon B., Macgregor, Stuart A., Weller, Andrew S., Navarro, Miquel, Campos, Jesús

“…Using single‐crystal to single‐crystal solid/gas reactivity the gold(I) acetylene complex [Au(L1)(η2‐HC≡CH)][BArF4] is cleanly synthesized by addition of…”
Get full text

Chasing the CMD/AMLA Mechanism C–H···Pd Interactions in the Cyclopalladation Reaction of N,N‑Dimethylbenzylamine with Pd(OAc)2 by Sajjad, M. Arif, Schwerdtfeger, Peter, Edwards, Patrick J. B., Harrison, John A., Nielson, Alastair J.

“…700 MHz 1H NMR spectral examination of the reaction between Me2NCH2Ph and Pd­(OAc)2 in CDCl3 reveals that several anagostic complexes form, but an agostic…”
Get full text

A Search by NBO Analysis for Syndetic Donation in Known X‐ray Structures of Transition Metal Complexes with Close Aromatic Ring C–H···Metal Approaches by Sajjad, M. Arif, Schwerdtfeger, Peter, Harrison, John A., Nielson, Alastair J.

“…Natural bond orbital (NBO) analysis obtained from density functional theory (DFT) calculations shows that where close approaches of aromatic ring C–H bond…”
Get full text

NBO Orbital Interaction Analysis for the Ambiphilic Metal–Ligand Activation/Concerted Metalation Deprotonation (AMLA/CMD) Mechanism Involved in the Cyclopalladation Reaction of N,N‑Dimethylbenzylamine with Palladium Acetate by Sajjad, M. Arif, Harrison, John A, Nielson, Alastair J, Schwerdtfeger, Peter

“…Natural bond orbital (NBO) analysis obtained from density functional theory (DFT) calculations on the intermediates and transition states in the ambiphilic…”
Get full text

Evaluation of the Agostic and Syndetic Donations in Aromatic Ring Agostic Interactions Involved in Heteroatom Ligand-Directed C–H Bond Activation by Harrison, John A, Nielson, Alastair J, Sajjad, M. Arif, Schwerdtfeger, Peter

“…Natural bond orbital (NBO) analysis obtained from density functional theory (DFT) calculations was used to show whether syndetic donation (π or σ-electron…”
Get full text

Electronic and Steric Manipulation of the Agostic Interaction in benzo[ h ]quinoline Complexes of Pd(II) and Implications for the Formation of η 1 ‐Pd–C Bonds by Nielson, Alastair J., Harrison, John A., Sajjad, M. Arif, Schwerdtfeger, Peter

“…Structures and properties were obtained by density functional (DFT) calculations for the complexes [PdCl 2 (L)] (L = benzo[ h ]quinolines) containing aromatic…”
Get full text

In crystallo lattice adaptivity triggered by solid–gas reactions of cationic Group 7 pincer complexes by Goodall, J. C., Arif Sajjad, M., Thompson, E. A., Page, Samuel J., Kerrigan, Adam M., Jenkins, H. T., Lynam, J. M., Macgregor, Stuart A., Weller, A. S.

“…Abstract only…”
Get full text

Growth and characterization of GeSnO thin films for thermoelectric power generation applications by Ullah, Inaam, Al-Harbi, F.F., ul Ahmad, Aqrab, Mahmood, K., Ali, A., Ikram, Salma, Amin, N., Javaid, K., Amami, Mongi, Arif Sajjad, M., Yasir Ali, M., Sharafat Hussain, M.

“…[Display omitted] •Growth of GeSnO thin films using PVD.•Annealing of grown samples.•Enhancement of thermoelectric properties by annealing.•Argument was…”
Get full text

Interplay of Steric and Electronic Effects on the Bonding Components in Aromatic Ring Agostic Interactions by Sajjad, M. Arif, Harrison, John A, Nielson, Alastair J, Schwerdtfeger, Peter

“…Density functional theory (DFT) calculations on the effect of steric size adjacent to an agostic interaction in ligand assisted Pd–C bond formation involving…”
Get full text

Electronic manipulation of the agostic and syndetic components in 1-tetralone oxime and imine complexes of palladium (II) by Sajjad, M. Arif, Schwerdtfeger, Peter, Harrison, John A., Nielson, Alastair J.

“…DFT-D calculations show that the agostic and syndetic components of the in-plane interactions of aromatic ring CH bonds in 1-tetralone oxime and imine…”
Get full text

Electronic and Steric Manipulation of the Preagostic Interaction in Isoquinoline Complexes of Rh I by Nielson, Alastair J., Harrison, John A., Sajjad, M. Arif, Schwerdtfeger, Peter

“…Structures and properties were obtained by density functional calculations for the complexes [RhCl(CO) 2 (L)] (L = isoquinoline ligands) containing close Rh…”
Get full text

A new approach for the growth of copper nitrides thin films by thermal evaporation using nitrogen as source gas by Ali, Hafiz T., Tanveer, Z., Javed, Muhammad Rizwan, Mahmood, K., Amin, N., Ikram, Salma, Ali, A., Shah Gilani, M. Rehan H., Sajjad, M. Arif, Yusuf, Mohammad

“…Thin films of copper nitride (Cu3N) were successfully synthesized by thermal evaporation method. The Cu powder was evaporated on glass substrate ina horizontal…”
Get full text