Search Results - "Saito, Teruhiko"

Selective C–O Bond Reduction and Borylation of Aryl Ethers Catalyzed by a Rhodium–Aluminum Heterobimetallic Complex by Seki, Rin, Hara, Naofumi, Saito, Teruhiko, Nakao, Yoshiaki

“…We report the catalytic reduction of a C–O bond and the borylation by a rhodium complex bearing an X-type PAlP pincer ligand. We have revealed the reaction…”
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Crystalline Copper(II) Phthalocyanine Catalysts for Electrochemical Reduction of Carbon Dioxide in Aqueous Media by Kusama, Shoko, Saito, Teruhiko, Hashiba, Hiroshi, Sakai, Akihiro, Yotsuhashi, Satoshi

“…We achieved highly selective electrochemical reduction of CO2 to C2H4 (faradaic efficiency of 25%) by crystalline copper phthalocyanine (CuPc) supported on…”
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para-Selective Alkylation of Benzamides and Aromatic Ketones by Cooperative Nickel/Aluminum Catalysis by Okumura, Shogo, Tang, Shuwei, Saito, Teruhiko, Semba, Kazuhiko, Sakaki, Shigeyoshi, Nakao, Yoshiaki

“…We report a method that ensures the selective alkylation of benzamides and aromatic ketones at the para-position via cooperative nickel/aluminum catalysis…”
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Synthesis, Electronic Properties, and Lewis Acidity of Rhodium Complexes Bearing X-Type PBP, PAlP, and PGaP Pincer Ligands by Hara, Naofumi, Yamamoto, Konosuke, Tanaka, Yuuki, Saito, Teruhiko, Sakaki, Shigeyoshi, Nakao, Yoshiaki

“…We have synthesized rhodium complexes that bear X-type PBP and PGaP pincer ligands. X-ray diffraction analysis and IR spectroscopy of the PBP– and PGaP–Rh(CO)2…”
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Salt-Free Reducing Reagent of Bis(trimethylsilyl)­cyclohexadiene Mediates Multielectron Reduction of Chloride Complexes of W(VI) and W(IV) by Tsurugi, Hayato, Tanahashi, Hiromasa, Nishiyama, Haruka, Fegler, Waldemar, Saito, Teruhiko, Sauer, Andreas, Okuda, Jun, Mashima, Kazushi

“…We developed a salt-free reduction of WCl6 using 1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene (MBTCD) in toluene to give a low-valent trinulcear…”
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Palladium Complexes Bearing Z-type PAlP Pincer Ligands by Saito, Teruhiko, Hara, Naofumi, Nakao, Yoshiaki

“…Palladium complexes with pincer-type ligands containing a Z-type aluminum moiety are synthesized by the reaction of palladium(0) precursors with…”
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New Tantalum Ligand-Free Catalyst System for Highly Selective Trimerization of Ethylene Affording 1-Hexene: New Evidence of a Metallacycle Mechanism by Arteaga-Müller, Rocío, Tsurugi, Hayato, Saito, Teruhiko, Yanagawa, Masao, Oda, Seiji, Mashima, Kazushi

“…Mild and salt-free reduction of MCl5 (M = Nb, Ta) has been achieved by using 3,6-bis(trimethylsilyl)-1,4-hexadiene derivatives as reducing reagents. The…”
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Rhodium Complexes Bearing PAlP Pincer Ligands by Hara, Naofumi, Saito, Teruhiko, Semba, Kazuhiko, Kuriakose, Nishamol, Zheng, Hong, Sakaki, Shigeyoshi, Nakao, Yoshiaki

“…We report rhodium complexes bearing PAlP pincer ligands with an X-type aluminyl moiety. IR spectroscopy and single-crystal X-ray diffraction analysis of a…”
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Palladium Complexes Bearing Z-type PAlP Pincer Ligands by Saito, Teruhiko, Hara, Naofumi, Nakao, Yoshiaki

“…Palladium complexes with pincer-type ligands containing a Z-type aluminum moiety are synthesized by the reaction of palladium(0) precursors with…”
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1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadienes as Strong Salt-Free Reductants for Generating Low-Valent Early Transition Metals with Electron-Donating Ligands by Saito, Teruhiko, Nishiyama, Haruka, Tanahashi, Hiromasa, Kawakita, Kento, Tsurugi, Hayato, Mashima, Kazushi

“…Electron-rich organosilicon compounds, such as 1,4-bis­(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene (2a),…”
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Structural and Electronic Noninnocence of α‑Diimine Ligands on Niobium for Reductive C–Cl Bond Activation and Catalytic Radical Addition Reactions by Nishiyama, Haruka, Ikeda, Hideaki, Saito, Teruhiko, Kriegel, Benjamin, Tsurugi, Hayato, Arnold, John, Mashima, Kazushi

“…A d0 niobium­(V) complex, NbCl3(α-diimine) (1a), supported by a dianionic redox-active N,N′-bis­(2,6-diisopropyl­phenyl)-1,4-diaza-2,3-dimethyl-1,3-butadiene…”
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Characterization of Rh-Al Bond in Rh(PAlP) (PAlP = Pincer-type Diphosphino-Aluminyl Ligand) in Comparison with Rh(L)(PMe 3 ) 2 (L = AlMe 2 , Al(NMe 2 ) 2 , BR 2 , SiR 3 , CH 3 , Cl, or OCH 3 ): Theoretical Insight by Kuriakose, Nishamol, Zheng, Jia-Jia, Saito, Teruhiko, Hara, Naofumi, Nakao, Yoshiaki, Sakaki, Shigeyoshi

“…The unique Rh-Al bond in recently synthesized Rh(PAlP) 1 {PAlP = pincer-type diphosphino-aluminyl ligand Al[NCH (P Pr )] (C H ) NMe} was investigated using the…”
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Characterization of Rh–Al Bond in Rh(PAlP) (PAlP = Pincer-type Diphosphino-Aluminyl Ligand) in Comparison with Rh(L)(PMe3)2 (L = AlMe2, Al(NMe2)2, BR2, SiR3, CH3, Cl, or OCH3): Theoretical Insight by Kuriakose, Nishamol, Zheng, Jia-Jia, Saito, Teruhiko, Hara, Naofumi, Nakao, Yoshiaki, Sakaki, Shigeyoshi

“…The unique Rh–Al bond in recently synthesized Rh­(PAlP) 1 {PAlP = pincer-type diphosphino-aluminyl ligand Al­[NCH2­(P i Pr2)]2­(C6H4)2­NMe} was investigated…”
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Reduction of ( t BuN)NbCl3(py)2 in a Salt-Free Manner for Generating Nb(IV) Dinuclear Complexes and Their Reactivity toward Benzo[c]cinnoline by Saito, Teruhiko, Nishiyama, Haruka, Kawakita, Kento, Nechayev, Michael, Kriegel, Benjamin, Tsurugi, Hayato, Arnold, John, Mashima, Kazushi

“…The organosilicon reducing reagent 2,3,5,6-tetramethyl-1,4-bis­(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene (1a) was used for the one-electron, salt-free…”
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Converting Commodity Polyolefins to Electronic Materials through Borane-Catalyzed Alkene Isomerization by Saito, Teruhiko, Hill, Megan R., Lennon Luo, Shao-Xiong, Ye, Hong-Zhou, Van Voorhis, Troy, Johnson, Jeremiah A.

“…Novel approaches to the functionalization of commodity polymers could provide avenues for the synthesis of materials for next-generation electronic devices…”
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Reduction of ( t BuN═)NbCl 3 (py) 2 in a Salt-Free Manner for Generating Nb(IV) Dinuclear Complexes and Their Reactivity toward Benzo[ c ]cinnoline by Saito, Teruhiko, Nishiyama, Haruka, Kawakita, Kento, Nechayev, Michael, Kriegel, Benjamin, Tsurugi, Hayato, Arnold, John, Mashima, Kazushi

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Carbon Radical Generation by d0 Tantalum Complexes with α-Diimine Ligands through Ligand-Centered Redox Processes by Tsurugi, Hayato, Saito, Teruhiko, Tanahashi, Hiromasa, Arnold, John, Mashima, Kazushi

“…High-valent tantalum complexes having redox-active α-diimine ligands, (α-diimine)TaCl n (n = 3, 4), are prepared by the reaction of TaCl5, α-diimine ligands,…”
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Carbon Radical Generation by d 0 Tantalum Complexes with α-Diimine Ligands through Ligand-Centered Redox Processes by Tsurugi, Hayato, Saito, Teruhiko, Tanahashi, Hiromasa, Arnold, John, Mashima, Kazushi

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C–H bond activation of N-heterocyclic carbene IMes by rare-earth metal alkyl complexes by Fegler, Waldemar, Saito, Teruhiko, Mashima, Kazushi, Spaniol, Thomas P., Okuda, Jun

“…Excess N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) reacted with the tris(trimethylsilylmethyl) rare-earth metal complex…”
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Reduction of ((t)BuN═)NbCl3(py)2 in a Salt-Free Manner for Generating Nb(IV) Dinuclear Complexes and Their Reactivity toward Benzo[c]cinnoline by Saito, Teruhiko, Nishiyama, Haruka, Kawakita, Kento, Nechayev, Michael, Kriegel, Benjamin, Tsurugi, Hayato, Arnold, John, Mashima, Kazushi

“…The organosilicon reducing reagent 2,3,5,6-tetramethyl-1,4-bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene (1a) was used for the one-electron, salt-free…”
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