Search Results - "SHIELDS, J"
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Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals
Published in Journal of the American Chemical Society (05-10-2016)“…Here we report the development of a C(sp3)–H cross-coupling platform enabled by the catalytic generation of chlorine radicals by nickel and photoredox…”
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2
Overcoming the rate–distance limit of quantum key distribution without quantum repeaters
Published in Nature (London) (01-05-2018)“…Quantum key distribution (QKD) 1 , 2 allows two distant parties to share encryption keys with security based on physical laws. Experimentally, QKD has been…”
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3
Bayesian reaction optimization as a tool for chemical synthesis
Published in Nature (London) (04-02-2021)“…Reaction optimization is fundamental to synthetic chemistry, from optimizing the yield of industrial processes to selecting conditions for the preparation of…”
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4
Long-Lived Charge-Transfer States of Nickel(II) Aryl Halide Complexes Facilitate Bimolecular Photoinduced Electron Transfer
Published in Journal of the American Chemical Society (28-02-2018)“…Here we investigate the photophysics and photochemistry of Ni(II) aryl halide complexes common to cross-coupling and Ni/photoredox reactions. Computational…”
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Beneficial and Detrimental Effects of Reactive Oxygen Species on Lifespan: A Comprehensive Review of Comparative and Experimental Studies
Published in Frontiers in cell and developmental biology (11-02-2021)“…Aging is the greatest risk factor for a multitude of diseases including cardiovascular disease, neurodegeneration and cancer. Despite decades of research…”
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6
Efficient readout of a single spin state in diamond via spin-to-charge conversion
Published in Physical review letters (03-04-2015)“…Efficient readout of individual electronic spins associated with atomlike impurities in the solid state is essential for applications in quantum information…”
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The ASAS-SN catalogue of variable stars – V. Variables in the Southern hemisphere
Published in Monthly notices of the Royal Astronomical Society (01-01-2020)“…ABSTRACT The All-Sky Automated Survey for Supernovae (ASAS-SN) provides long baseline (∼4 yr) light curves for sources brighter than V ≲ 17 mag across the…”
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The ASAS-SN catalogue of variable stars I: The Serendipitous Survey
Published in Monthly notices of the Royal Astronomical Society (01-07-2018)Get full text
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9
Nanoscale mechanics of antiferromagnetic domain walls
Published in Nature physics (01-05-2021)“…Antiferromagnets can encode information in their ordered magnetic structure, providing the basis for future spintronic devices 1 – 3 . The control and…”
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Nickel/Photoredox-Catalyzed Methylation of (Hetero)aryl Chlorides Using Trimethyl Orthoformate as a Methyl Radical Source
Published in Journal of the American Chemical Society (22-04-2020)“…Methylation of organohalides represents a valuable transformation, but typically requires harsh reaction conditions or reagents. We report a radical approach…”
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11
The ASAS-SN Catalog of Variable Stars II: Uniform Classification of 412,000 Known Variables
Published in Monthly notices of the Royal Astronomical Society (01-06-2019)Get full text
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12
Predicting Reaction Yields via Supervised Learning
Published in Accounts of chemical research (20-04-2021)“…Conspectus Numerous disciplines, such as image recognition and language translation, have been revolutionized by using machine learning (ML) to leverage big…”
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13
Mild, Redox‐Neutral Formylation of Aryl Chlorides through the Photocatalytic Generation of Chlorine Radicals
Published in Angewandte Chemie International Edition (12-06-2017)“…We report a redox‐neutral formylation of aryl chlorides that proceeds through selective 2‐functionalization of 1,3‐dioxolane through nickel and photoredox…”
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14
A quantum light-emitting diode for the standard telecom window around 1,550 nm
Published in Nature communications (28-02-2018)“…Single photons and entangled photon pairs are a key resource of many quantum secure communication and quantum computation protocols, and non-Poissonian sources…”
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The ASAS-SN catalogue of variable stars III: variables in the southern TESS continuous viewing zone
Published in Monthly notices of the Royal Astronomical Society (01-05-2019)Get full text
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16
Regioselective Cross-Electrophile Coupling of Epoxides and (Hetero)aryl Iodides via Ni/Ti/Photoredox Catalysis
Published in ACS catalysis (15-05-2020)“…A cross-electrophile coupling reaction of epoxides and (hetero)aryl iodides that operates via the merger of three catalytic cycles involving a Ni-, Ti-, and…”
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17
Mapping Native R-Loops Genome-wide Using a Targeted Nuclease Approach
Published in Cell reports (Cambridge) (29-10-2019)“…R-loops are three-stranded DNA:RNA hybrids that are implicated in many nuclear processes. While R-loops may have physiological roles, the formation of stable,…”
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Practical Security Bounds Against the Trojan-Horse Attack in Quantum Key Distribution
Published in Physical review. X (09-09-2015)“…In the quantum version of a Trojan-horse attack, photons are injected into the optical modules of a quantum key distribution system in an attempt to read…”
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Deterministic Enhancement of Coherent Photon Generation from a Nitrogen-Vacancy Center in Ultrapure Diamond
Published in Physical review. X (07-09-2017)“…The nitrogen-vacancy (NV) center in diamond has an optically addressable, highly coherent spin. However, a NV center even in high-quality single-crystalline…”
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20
Quantum key distribution without detector vulnerabilities using optically seeded lasers
Published in Nature photonics (01-05-2016)“…Quantum cryptography immune from detector attacks is realized by the development of a source of indistinguishable laser pulses based on optically seeded…”
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