Search Results - "SHANNON, Matthew S"
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Free Volume as the Basis of Gas Solubility and Selectivity in Imidazolium-Based Ionic Liquids
Published in Industrial & engineering chemistry research (18-04-2012)“…While molar volume-based models for gas solubility in ionic liquids (ILs) have been proposed, free volume within the IL can be shown to be the underlying…”
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Chemical and Physical Absorption of SO2 by N‑Functionalized Imidazoles: Experimental Results and Molecular-level Insight
Published in Industrial & engineering chemistry research (14-01-2015)“…Sulfur dioxide (SO2) removal is a key component of many industrial processes, especially coal-fired power generation. Controlling SO2 emissions is vital to…”
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3
Properties and Performance of Ether-Functionalized Imidazoles as Physical Solvents for CO2 Separations
Published in Energy & fuels (20-06-2013)“…Previously, we investigated 1-n-alkylimidazoles as low viscosity, low vapor pressure physical solvents for CO2/CH4 separation and noted a decrease in…”
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4
Enhanced photopolymerization rate & conversion of 1-vinylimidazole in the presence of lithium bistriflimide
Published in European polymer journal (01-11-2014)“…[Display omitted] •LiTf2N is highly soluble in Vim, producing a coordinated ionic liquid monomer.•Photopolymerization rate & conversion of Vim are greatly…”
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5
Properties of alkylbenzimidazoles for CO2 and SO2 capture and comparisons to ionic liquids
Published in Science China. Chemistry (01-08-2012)“…To date, few reports have been concerned with the physical properties of the liquid phases of imidazoles and benzimidazoles- potential starting materials for a…”
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6
Ionic Polyimides: Hybrid Polymer Architectures and Composites with Ionic Liquids for Advanced Gas Separation Membranes
Published in Industrial & engineering chemistry research (03-05-2017)“…Polyimides and ionic liquids (ILs) are two classes of materials that have been widely studied as gas separation membranes, each demonstrating respective…”
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7
Reactive and Reversible Ionic Liquids for CO2 Capture and Acid Gas Removal
Published in Separation science and technology (01-01-2012)“…The use of ionic liquids (ILs) for CO 2 capture and the removal of acid gases from natural gas and other industrial processes has been one of the foremost…”
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Correlating fractional free volume to CO2 selectivity in [Rmim][Tf2N] ionic liquids
Published in The Journal of chemical thermodynamics (01-10-2014)“…•Fractional free volumes of [Rmim][Tf2N] ILs were simulated in COSMOTherm.•When ‘R’ is a polar group, FFV is reduced compared to when ‘R’ is alkyl.•Reduced FFV…”
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Understanding Carbon Dioxide Solubility in Ionic Liquids by Exploring the Link with Liquid Clathrate Formation
Published in Chemistry : a European journal (12-10-2017)“…The solubilities of the quadrupolar molecules benzene and CO2 in various ionic liquids (ILs) are compared in order to determine the connection between aromatic…”
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Experimental Densities and Calculated Fractional Free Volumes of Ionic Liquids with Tri- and Tetra-substituted Imidazolium Cations
Published in Journal of chemical and engineering data (12-07-2018)“…Although it has been estimated that there are at least 1 million ionic liquids (ILs) that are accessible using commercially available starting materials, a…”
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Poly(Ionic Liquid) Superabsorbent for Polar Organic Solvents
Published in ACS applied materials & interfaces (06-05-2015)“…A simple, polymerized ionic liquid (poly(IL)) based on methylimidazolium cations tethered to a polystyrene backbone exhibits superabsorbent behavior toward…”
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12
Properties of Alkylimidazoles as Solvents for CO2 Capture and Comparisons to Imidazolium-Based Ionic Liquids
Published in Industrial & engineering chemistry research (20-07-2011)“…Density, viscosity, and CO2 solubility of a series of 10 1-n-alkylimidazoles with chain lengths ranging from methyl (C1) to tetradecyl (C14) were…”
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13
Evaluation of Alkylimidazoles as Physical Solvents for CO2/CH4 Separation
Published in Industrial & engineering chemistry research (11-01-2012)“…1-n-Alkylimidazoles are a class of tunable solvents with low volatility and low viscosities. Although imidazoles have been known for some time in the…”
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14
Effect of branched and cycloalkyl functionalities on CO2 separation performance of poly(IL) membranes
Published in Separation and purification technology (26-11-2015)“…•IL monomers synthesized with branched/cyclic groups.•Monomers photopolymerized into poly(IL) membranes.•Branched/cyclic groups affect performance relative to…”
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15
Molecular Simulation of the Thermophysical Properties of N-Functionalized Alkylimidazoles
Published in The journal of physical chemistry. B (07-06-2012)“…Molecular simulations are used to probe the thermophysical properties of a series of N-functionalized alkylimidazoles, ranging from N-methylimidazole to…”
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Synthesis of 1,2-Dialkyl‑, 1,4(5)-Dialkyl‑, and 1,2,4(5)-Trialkylimidazoles via a One-Pot Method
Published in Industrial & engineering chemistry research (28-08-2013)“…Despite the utility of imidazoles for a wide variety of chemical and biological applications as well as the growing research in imidazolium-based ionic liquids…”
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Accelerated Aging and Qualitative Degradation Pathway Analysis of CO2 Capture Solvents Containing Ionic Liquids
Published in Energy & fuels (16-08-2012)“…A qualitative study was conducted to analyze degradation of CO2 capture solvents containing ionic liquids by GC/MS under a variety of conditions representative…”
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Systematic Investigation of the Photopolymerization of Imidazolium‐Based Ionic Liquid Styrene and Vinyl Monomers
Published in Journal of polymer science. Part A, Polymer chemistry (15-10-2018)“…ABSTRACT The use of ionic liquids (ILs) as media in radical polymerizations has demonstrated the ability of these unique solvents to improve both reaction…”
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19
Reactive and Reversible Ionic Liquids for CO 2 Capture and Acid Gas Removal
Published in Separation science and technology (15-01-2012)Get full text
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20
Evaluation of Alkylimidazoles as Physical Solvents for CO 2 /CH 4 Separation
Published in Industrial & engineering chemistry research (11-01-2012)Get full text
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