Search Results - "SELS, Bert F"
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Sulfonated mesoporous carbon and silica-carbon nanocomposites for biomass conversion
Published in Applied catalysis. B, Environmental (15-11-2018)“…[Display omitted] •Various synthesis approaches especially those via soft-templating for mesoporous carbon or silica-carbon nanocomposites are…”
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State of the Art and Perspectives of Hierarchical Zeolites: Practical Overview of Synthesis Methods and Use in Catalysis
Published in Advanced materials (Weinheim) (01-11-2020)“…Microporous zeolites have proven to be of great importance in many chemical processes. Yet, they often suffer from diffusion limitations causing inefficient…”
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Potential and challenges of zeolite chemistry in the catalytic conversion of biomass
Published in Chemical Society reviews (07-02-2016)“…Increasing demand for sustainable chemicals and fuels has pushed academia and industry to search for alternative feedstocks replacing crude oil in traditional…”
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4
A sustainable wood biorefinery for low-carbon footprint chemicals production
Published in Science (American Association for the Advancement of Science) (20-03-2020)“…The profitability and sustainability of future biorefineries are dependent on efficient feedstock use. Therefore, it is essential to valorize lignin when using…”
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Shape-selective zeolite catalysis for bioplastics production
Published in Science (American Association for the Advancement of Science) (03-07-2015)“…Biodegradable and renewable polymers, such as polylactic acid, are benign alternatives for petrochemical-based plastics. Current production of polylactic acid…”
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Shape selectivity vapor-phase conversion of lignin-derived 4-ethylphenol to phenol and ethylene over acidic aluminosilicates: Impact of acid properties and pore constraint
Published in Applied catalysis. B, Environmental (15-10-2018)“…[Display omitted] •Both Brønsted and Lewis acid sites catalyse ethylphenol dealkylation to phenol and ethylene.•ZSM-5 shows a shape selective dealkylation and…”
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7
Top chemical opportunities from carbohydrate biomass: a chemist's view of the Biorefinery
Published in Topics in current chemistry (01-01-2014)“…Cheap fossil oil resources are becoming depleted and crude oil prices are rising. In this context, alternatives to fossil fuel-derived carbon are examined in…”
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Rational Positioning of Metal Ions to Stabilize Open Tin Sites in Beta Zeolite for Catalytic Conversion of Sugars
Published in Angewandte Chemie International Edition (01-02-2023)“…Via hydrothermal synthesis of Sn‐Al gels, mild dealumination and ion exchange, a bimetallic Sn‐Ni‐Beta catalyst was prepared which can convert glucose to…”
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9
Catalytic Gas‐Phase Production of Lactide from Renewable Alkyl Lactates
Published in Angewandte Chemie International Edition (12-03-2018)“…A new route to lactide, which is a key building block of the bioplastic polylactic acid, is proposed involving a continuous catalytic gas‐phase…”
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10
Cage effects control the mechanism of methane hydroxylation in zeolites
Published in Science (American Association for the Advancement of Science) (16-07-2021)“…Catalytic conversion of methane to methanol remains an economically tantalizing but fundamentally challenging goal. Current technologies based on zeolites…”
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The active site of low-temperature methane hydroxylation in iron-containing zeolites
Published in Nature (London) (18-08-2016)“…Iron-containing zeolites have an exceptional ability to convert methane into methanol, but their active site have been hard to study; now, magnetic circular…”
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12
Perspective on Overcoming Scale-Up Hurdles for the Reductive Catalytic Fractionation of Lignocellulose Biomass
Published in Industrial & engineering chemistry research (30-09-2020)“…In the last 5 years, reductive catalytic fractionation of lignocellulose biomass has emerged as a promising biorefinery concept that combines biomass…”
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13
Spectroscopic Definition of the Copper Active Sites in Mordenite: Selective Methane Oxidation
Published in Journal of the American Chemical Society (20-05-2015)“…Two distinct [Cu–O–Cu]2+ sites with methane monooxygenase activity are identified in the zeolite Cu-MOR, emphasizing that this Cu–O–Cu active site geometry,…”
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14
Patterned Growth of Metal-Organic Framework Coatings by Electrochemical Synthesis
Published in Chemistry of materials (14-07-2009)Get full text
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15
Synthesis–Structure–Activity Relations in Fe-CHA for C–H Activation: Control of Al Distribution by Interzeolite Conversion
Published in Chemistry of materials (14-01-2020)“…The search for structurally relevant Al arrangements in zeolites is an important endeavor for single-site catalysis. Little is known about the mechanisms and…”
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Interfacial synthesis of hollow metal–organic framework capsules demonstrating selective permeability
Published in Nature chemistry (01-05-2011)“…Metal–organic frameworks (MOFs) are a class of crystalline materials that consist of metal ions and organic ligands linked together by coordination bonds…”
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17
Tin triflate-catalyzed conversion of cellulose to valuable (α-hydroxy-) esters
Published in Catalysis today (01-01-2017)“…[Display omitted] •SnII(OTf)2 has unique properties to convert cellulose to valuable esters in MeOH.•Main esters are methyl lactate, methyl vinyl glycolate and…”
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Low‐Temperature Reductive Aminolysis of Carbohydrates to Diamines and Aminoalcohols by Heterogeneous Catalysis
Published in Angewandte Chemie International Edition (13-11-2017)“…Short amines, such as ethanolamines and ethylenediamines, are important compounds in today's bulk and fine chemicals industry. Unfortunately, current…”
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[Cu2O]2+ Active Site Formation in Cu–ZSM-5: Geometric and Electronic Structure Requirements for N2O Activation
Published in Journal of the American Chemical Society (05-03-2014)“…Understanding the formation mechanism of the [Cu2O]2+ active site in Cu–ZSM-5 is important for the design of efficient catalysts to selectively convert methane…”
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How Trace Impurities Can Strongly Affect the Hydroconversion of Biobased 5‑Hydroxymethylfurfural?
Published in ACS catalysis (06-08-2021)“…Selective conversion of 5-hydroxymethylfurfural (HMF) to liquid fuels is an important step in the valorization of carbohydrates. Although not paid much…”
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