Search Results - "SCHMIDT, MICHAEL W."
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Persistence of soil organic matter as an ecosystem property
Published in Nature (London) (06-10-2011)“…Soil carbon stability revisited The mechanisms underpinning soil carbon stability are complicated. The future response of soil carbon to climate change is…”
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Tropical forest soil carbon stocks do not increase despite 15 years of doubled litter inputs
Published in Scientific reports (02-12-2019)“…Soil organic carbon (SOC) dynamics represent a persisting uncertainty in our understanding of the global carbon cycle. SOC storage is strongly linked to plant…”
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3
Spin–Orbit Coupling Constants in Atoms and Ions of Transition Elements: Comparison of Effective Core Potentials, Model Core Potentials, and All-Electron Methods
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (28-03-2019)“…The spin–orbit coupling constants (SOCC) in atoms and ions of the first- through third-row transition elements were calculated for the low-lying atomic states…”
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4
Transformation and stabilization of pyrogenic organic matter in a temperate forest field experiment
Published in Global change biology (01-05-2014)“…Pyrogenic organic matter (PyOM) decomposes on centennial timescale in soils, but the processes regulating its decay are poorly understood. We conducted one of…”
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5
Nitrogen deposition promotes the production of new fungal residues but retards the decomposition of old residues in forest soil fractions
Published in Global change biology (01-01-2014)“…Atmospheric nitrogen (N) deposition has frequently been observed to increase soil carbon (C) storage in forests, but the underlying mechanisms still remain…”
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Valence Virtual Orbitals: An Unambiguous ab Initio Quantification of the LUMO Concept
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (15-10-2015)“…Many chemical concepts hinge on the notion of an orbital called the lowest unoccupied molecular orbital, or LUMO. This hypothetical orbital and the much more…”
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7
Climate warming and elevated CO2 alter peatland soil carbon sources and stability
Published in Nature communications (20-11-2023)“…Peatlands are an important carbon (C) reservoir storing one-third of global soil organic carbon (SOC), but little is known about the fate of these C stocks…”
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8
Rapid loss of complex polymers and pyrogenic carbon in subsoils under whole-soil warming
Published in Nature geoscience (2023)“…Subsoils contain more than half of soil organic carbon (SOC) and are expected to experience rapid warming in the coming decades. Yet our understanding of the…”
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9
Belowground plant allocation regulates rice methane emissions from degraded peat soils
Published in Scientific reports (25-06-2024)“…Carbon-rich peat soils have been drained and used extensively for agriculture throughout human history, leading to significant losses of their soil carbon. One…”
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10
Ab Initio Molecular Orbital Study of the First Four Si/C Alternately Substituted Annulenes
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (30-05-2019)“…The ground and low-lying excited states of four alternating Si/C annulenes, H n Si n/2C n/2 with n = 4, 6, 8, and 10, have been investigated by ab initio…”
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Warming and elevated CO2 promote rapid incorporation and degradation of plant‐derived organic matter in an ombrotrophic peatland
Published in Global change biology (01-02-2022)“…Rising temperatures have the potential to directly affect carbon cycling in peatlands by enhancing organic matter (OM) decomposition, contributing to the…”
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12
Nine years of warming and nitrogen addition in the Tibetan grassland promoted loss of soil organic carbon but did not alter the bulk change in chemical structure
Published in Biogeosciences (26-01-2024)“…Nitrogen (N) and warming effects on ecosystem carbon (C) budgets and stabilization are critical to understand as C sequestration is considered as a mechanism…”
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13
What on Earth Have We Been Burning? Deciphering Sedimentary Records of Pyrogenic Carbon
Published in Environmental science & technology (07-11-2017)“…Humans have interacted with fire for thousands of years, yet the utilization of fossil fuels marked the beginning of a new era. Ubiquitous in the environment,…”
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14
F-Box-Directed CRL Complex Assembly and Regulation by the CSN and CAND1
Published in Molecular cell (11-09-2009)“…The COP9 signalosome (CSN) is thought to maintain the stability of cullin-RING ubiquitin ligases (CRL) by limiting the autocatalytic destruction of substrate…”
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15
Black carbon in soils and sediments: Analysis, distribution, implications, and current challenges
Published in Global biogeochemical cycles (01-09-2000)“…This review highlights the ubiquity of black carbon (BC) produced by incomplete combustion of plant material and fossil fuels in peats, soils, and lacustrine…”
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16
Marked isotopic variability within and between the Amazon River and marine dissolved black carbon pools
Published in Nature communications (05-09-2019)“…Riverine dissolved organic carbon (DOC) contains charcoal byproducts, termed black carbon (BC). To determine the significance of BC as a sink of atmospheric CO…”
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17
Electronic Structure Analysis of the Ground-State Potential Energy Curve of Be2
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (26-08-2010)“…The recently measured ground-state potential energy curve of the diatomic beryllium molecule is reproduced to within an accuracy of 20 cm−1 by a full valence…”
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18
Improved assessment of pyrogenic carbon quantity and quality in environmental samples by high-performance liquid chromatography
Published in Journal of Chromatography A (23-08-2013)“…•A molecular marker method to quantify pyrogenic carbon (PyC) was improved.•Required sample amounts decreased while sample throughput increased.•Better PyC…”
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19
Why does electron sharing lead to covalent bonding? A variational analysis
Published in Journal of computational chemistry (15-01-2007)“…Ground state energy differences between related systems can be elucidated by a comparative variational analysis of the energy functional, in which the concepts…”
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20
Solvent-Induced Shifts in Electronic Spectra of Uracil
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (12-05-2011)“…Highly accurate excitation spectra are predicted for the low-lying n−π* and π−π* states of uracil for both the gas phase and in water employing the complete…”
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