Search Results - "S. Groysman"
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Recyclable chemosensor for oxalate based on bimetallic complexes of a dinucleating bis(iminopyridine) ligand
Published in Dalton transactions : an international journal of inorganic chemistry (07-06-2014)“…Herein we describe bimetallic di-nickel and di-copper complexes [Ni2(L)Br4] (1) and [Cu2(L)Br4(NCMe)2] (2) (L =…”
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HIERARCHY OF NORMATIVE LEGAL ACTS IN RUSSIA AND BULGARIA: ON THE ISSUE OF THE LAW ON NORMATIVE LEGAL ACTS
Published in Rossijsko-aziatskij pravovoj žurnal (25-02-2022)“…The article analyzes the problem of developing and adopting a law on normative legal acts in the RussianFederation as a way to establish a uniform approach to…”
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HIERARCHY OF RUSSIAN LAW SOURCES: AN ANALYSIS OF LEGISLATION AND DOCTRINE THROUGH THE COMPARATIVE LEGAL PRISM OF BULGARIAN LAW
Published in Vestnik Permskogo universiteta. Ûridičeskie nauki (Online) (2023)“…Introduction: the article analyzes the conceptual problem of the formation of the ‘law on laws’, evaluates different approaches to the study of the system of…”
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ИЕРАРХИЯ НОРМАТИВНЫХ ПРАВОВЫХ АКТОВ В РОССИИ И БОЛГАРИИ: К ВОПРОСУ О ЗАКОНЕ О НОРМАТИВНЫХ ПРАВОВЫХ АКТАХ
Published in Rossijsko-aziatskij pravovoj žurnal (01-02-2022)“…В статье анализируется проблема разработки и принятия закона о нормативных правовых актах в Российской Федерации как способа установления единообразного…”
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5
Novel Alkoxide Cluster Topologies Featuring Rare Seesaw Geometry at Transition Metal Centers
Published in Chemistry : a European journal (09-09-2013)“…Caution! Chemists playing: Novel clusters of the form [M2Li2Cl2(OR)4] featuring rare seesaw geometry at the transition metal centers were synthesized for…”
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[ONXO]-Type Amine Bis(phenolate) Zirconium and Hafnium Complexes as Extremely Active 1-Hexene Polymerization Catalysts
Published in Organometallics (18-02-2002)“…Several [ONXO]-type zirconium and hafnium dibenzyl complexes of amine bis(phenolate) ligands, where X is a heteroatom donor located on a pendant arm, were…”
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Diastereoisomerically Selective Enantiomerically Pure Titanium Complexes of Salan Ligands: Synthesis, Structure, and Preliminary Activity Studies
Published in Inorganic chemistry (27-06-2005)“…The degree of diastereoselectivity in the wrapping of four new chiral Salan ligands to form chiral-at-metal titanium complexes ranged from mild to perfect as a…”
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From THF to Furan: Activity Tuning and Mechanistic Insight via Sidearm Donor Replacement in Group IV Amine Bis(phenolate) Polymerization Catalysts
Published in Organometallics (21-07-2003)“…Weakening the sidearm donor of amine bis(phenolate) titanium and zirconium polymerization catalysts causes a 10-fold enhancement in activity of the former and…”
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9
Salophan Complexes of Group IV Metals
Published in European Journal of Inorganic Chemistry (01-06-2005)“…The coordination chemistry of tetradentate Salophan ligands with titanium and zirconium alkoxides is described for the first time. Three new Salophan ligand…”
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Book Review Journal Article -
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Diverse Structure−Activity Trends in Amine Bis(phenolate) Titanium Polymerization Catalysts
Published in Organometallics (25-10-2004)“…The activity of amine bis(phenolate) Ti dibenzyl complexes in 1-hexene polymerization catalysis as a function of the phenolate substituents was investigated…”
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Salalen: a hybrid Salan/Salen tetradentate [ONNO]-type ligand and its coordination behavior with group IV metals
Published in Inorganic chemistry communications (01-02-2004)“…A straightforward synthesis of Salalens, tetradentate [ONNO]-type ligands comprised of an amine-phenolate and an imine-phenolate subunits is introduced. The…”
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Group IV Complexes of a Tetradentate Amine Mono(phenolate) Ligand: a Second Side-Arm Donor Stabilizes Cationic Species
Published in Inorganic chemistry (14-11-2005)“…An amine mono(phenolate) ligand bearing two side-arm donors led to octahedral trialkoxo and trialkyl group IV metal complexes, in which one of the donors was…”
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13
Tribenzyl Tantalum(V) Complexes of Amine Bis(phenolate) Ligands: Investigation of α-Abstraction vs Ligand Backbone β-Abstraction Paths
Published in Organometallics (12-04-2004)“…The synthesis, structure, and reactivity of tribenzyl Ta(V) complexes of amine bis(phenolate) ligands were investigated as a function of the ligands'…”
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14
Vanadium(III) and Vanadium(V) Amine Tris(Phenolate) Complexes
Published in Inorganic chemistry (11-07-2005)“…The coordination chemistry of amine tris(phenolate) ligands around V(III) and V(V) is described for the first time. Three amine tris(phenolate) ligands were…”
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Exploring Routes to Tantalum(V) Alkylidene Complexes Supported by Amine Tris(phenolate) Ligands
Published in Advanced synthesis & catalysis (01-02-2005)“…Two basic organometallic species, tris(neopentyl)mono(neopenylidene)tantalum and pentabenzyltantalum, were evaluated as starting materials on the route to…”
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Group IV complexes of an amine bis(phenolate) ligand featuring a THF sidearm donor: from highly active to living polymerization catalysts of 1-hexene
Published in Inorganica Chimica Acta (10-03-2003)“…A new amine bis(phenolate) ligand bearing a THF donor on a sidearm and several dialkyl complexes of the group IV triad are introduced. The crystal structures…”
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Pentabenzyltantalum: Straightforward Synthesis, X-ray Structure, and Application in the Synthesis of [O2N]TaBn3-Type and [O3N]TaBn2-Type Complexes
Published in Organometallics (15-09-2003)“…The direct reaction between tantalum pentachloride and benzylmagnesium chloride leads to pentabenzyltantalum, previously prepared by a two-step synthesis. The…”
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Ta(V) complexes of a bulky amine tris(phenolate) ligand: steric inhibition vs. chelate effect
Published in Inorganic chemistry communications (01-08-2004)“…The reactivity of a bulky amine tris(phenolate) ligand toward Ta(NMe 2) 5 was investigated. The reaction leading to the final product LigTa(NMe 2) 2 was slow…”
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High Molecular Weight Atactic Polypropylene prepared by Zirconium Complexes of an Amine Bis(phenolate) Ligand
Published in Israel journal of chemistry (01-12-2002)“…The polymerization of propylene employing the recently developed amine bis(phenolate) zirconium catalysts is reported for the first time. The polymerizations…”
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Polymerization of 4-methylpentene and vinylcyclohexane by amine bis(phenolate) titanium and zirconium complexes
Published in Journal of polymer science. Part A, Polymer chemistry (01-02-2006)“…The polymerization of the substituted olefins 4‐methylpentene and vinylcyclohexane by dibenzyl titanium and zirconium complexes of three amine bis(phenolate)…”
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