Search Results - "Rybáček, Jiří"
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1
From helical to planar chirality by on-surface chemistry
Published in Nature chemistry (01-03-2017)“…The chirality of molecular structures is paramount in many phenomena, including enantioselective reactions, molecular self-assembly, biological processes and…”
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2
Cycloiridated Helicenes as Chiral Catalysts in the Asymmetric Transfer Hydrogenation of Imines
Published in ACS catalysis (02-09-2022)“…The asymmetric synthesis of optically pure and conformationally locked oxabenzo[5]helicenes bearing pyridin-2-yl or isoquinolin-3-yl substituents and their…”
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3
An Ultimate Stereocontrol in Asymmetric Synthesis of Optically Pure Fully Aromatic Helicenes
Published in Journal of the American Chemical Society (08-07-2015)“…The role of the helicity of small molecules in enantioselective catalysis, molecular recognition, self-assembly, material science, biology, and nanoscience is…”
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4
Chlorinated Cubane-1,4-dicarboxylic Acids
Published in Journal of organic chemistry (16-08-2024)“…Herein, we report radical chlorination of cubane-1,4-dicarboxylic acid leading preferentially to one monochlorinated cubane dicarboxylate (ca. 70%) that is…”
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Helical Bilayer Nanographenes: Impact of the Helicene Length on the Structural, Electrochemical, Photophysical, and Chiroptical Properties
Published in Journal of the American Chemical Society (31-05-2023)“…Helical bilayer nanographenes (HBNGs) are chiral π-extended aromatic compounds consisting of two π–π stacked hexabenzocoronenes (HBCs) joined by a helicene,…”
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6
Twinned Growth of Metal‐Free, Triazine‐Based Photocatalyst Films as Mixed‐Dimensional (2D/3D) van der Waals Heterostructures
Published in Advanced materials (Weinheim) (01-10-2017)“…Design and synthesis of ordered, metal‐free layered materials is intrinsically difficult due to the limitations of vapor deposition processes that are used in…”
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7
Quantum dissipation driven by electron transfer within a single molecule investigated with atomic force microscopy
Published in Nature communications (12-03-2020)“…Intramolecular charge transfer processes play an important role in many biological, chemical and physical processes including photosynthesis, redox chemical…”
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8
Triptycene‐Based Tripodal Molecular Platforms
Published in Chemistry : a European journal (08-10-2024)“…Molecular platforms are essential components of various surface‐mounted molecular devices. Here, we document the synthesis of two universal triptycene‐based…”
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Antimicrobial peptides prevent bacterial biofilm formation on the surface of polymethylmethacrylate bone cement
Published in Journal of medical microbiology (01-06-2019)“…Antibiotic-loaded polymethylmethacrylate-based bone cement has been implemented in orthopaedics to cope with implant-related infections associated with the…”
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10
Electrochemistry of Tetrathiafulvalene Ligands Assembled on the Surface of Gold Nanoparticles
Published in Molecules (Basel, Switzerland) (07-11-2022)“…The synthesis of a tetrathiafulvalene (TTF) derivative, S-[4-({4-[(2,2′-bi-1,3-dithiol-4-ylmethoxy)methyl] phenyl}ethynyl)phenyl] ethanethioate, suitable for…”
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11
Synthesis of Racemic, Diastereopure, and Enantiopure Carba- or Oxa[5]‑, [6]‑, [7]‑, and -[19]helicene (Di)thiol Derivatives
Published in Journal of organic chemistry (03-01-2020)“…A series of carba- or oxa[5]-, [6]-, [7]-, and -[19]helicene (di)thiols was prepared. The Miyazaki–Newman–Kwart rearrangement of (dimethylcarbamothioyl)oxy…”
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12
Helicenes as Chirality‐Inducing Groups in Transition‐Metal Catalysis: The First Helically Chiral Olefin Metathesis Catalyst
Published in Chemistry : a European journal (01-08-2018)“…Helical chirality is a novel enantioselectivity‐inducing property in transition‐metal‐catalyzed transformations. The principle is illustrated herein for the…”
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13
Preparation of a Key Tetraene Precursor for the Synthesis of Long Acenes
Published in European journal of organic chemistry (22-03-2020)“…The tetraene 7,7‐dimethoxy‐2,3,5,6‐tetramethylenebicyclo[2.2.1]heptane is a key compound for the preparation of a large variety of acenes protected by a…”
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14
β-Disubstituted Pentacene Derivatives: Thin Film StructuralProperties and Four-Probe Field Effect Mobility
Published in ChemPlusChem (Weinheim, Germany) (01-04-2024)“…2,9- and 2,10-diphenylpentacene were synthesized by direct C-H borylation of ketal-protected pentacene, followed by halodeboronation, resolution of the dihalo…”
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15
Molecular Self-Assembly of Enantiopure Heptahelicene-2-Carboxylic Acid on Calcite (101̅4)
Published in Journal of physical chemistry. C (23-02-2012)“…Chirality can have a decisive influence on the molecular structure formation upon self-assembly on surfaces. In this paper, we study the structures formed by…”
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Toward Molecular Nanowires Self-Assembled on an Insulating Substrate: Heptahelicene-2-carboxylic acid on Calcite (101̅4)
Published in Journal of physical chemistry. C (28-01-2010)“…Molecular self-assembly is employed for creating unidirectional molecular nanostructures on a truly insulating substrate, namely the (101̅4) cleavage plane of…”
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Chirality‐Controlled Self‐Assembly of Amphiphilic Dibenzo[6]helicenes into Langmuir–Blodgett Thin Films
Published in Chemistry : a European journal (02-09-2019)“…Racemic and highly enantioenriched 3‐methoxycarbonyl, 3‐carboxy, and 3‐hydroxymethyl derivatives of dibenzo[6]helicene were prepared. The Langmuir layers of…”
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18
Synthesis of (Di)thiahelicenes and Dithiophenohelicenes by [2+2+2] Cycloisomerization of Alkynes
Published in Helvetica chimica acta (01-03-2022)“…A series of inherently chiral (di)thiahelicenes/dithiophenohelicenes containing 5, 6, 9 or 11 (hetero)cycles in their helical backbone with thiophene…”
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Discovery of a Druggable, Cryptic Pocket in SARS-CoV‑2 nsp16 Using Allosteric Inhibitors
Published in ACS infectious diseases (13-10-2023)“…A collaborative, open-science team undertook discovery of novel small molecule inhibitors of the SARS-CoV-2 nsp16-nsp10 2′-O-methyltransferase using a high…”
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Racemic and Optically Pure Heptahelicene-2-carboxylic Acid: Its Synthesis and Self-Assembly into Nanowire-Like Aggregates
Published in European Journal of Organic Chemistry (01-02-2011)“…Heptahelicene‐2‐carboxylic acid was effectively synthesised from suitably functionalised naphthalene building blocks. Methoxy‐substituted…”
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