Search Results - "Ruthven, Douglas M"
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The Nature of Surface Barriers on Nanoporous Solids Explored by Microimaging of Transient Guest Distributions
Published in Journal of the American Chemical Society (09-03-2011)“…Nanoporous solids are attractive materials for energetically efficient and environmentally friendly catalytic and adsorption separation processes. Although the…”
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2
Uphill diffusion and overshooting in the adsorption of binary mixtures in nanoporous solids
Published in Nature communications (16-07-2015)“…Under certain conditions, during binary mixture adsorption in nanoporous hosts, the concentration of one component may temporarily exceed its equilibrium…”
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3
Adsorptive separation of light olefins from paraffins
Published in Microporous and mesoporous materials (23-08-2007)“…Equilibrium and kinetic data for the sorption of light olefins and paraffins are reviewed. The equilibrium selectivities of cation rich zeolites are about 12…”
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The Effect of Water on the Adsorption of CO2 and C3H8 on Type X Zeolites
Published in Industrial & engineering chemistry research (22-12-2004)“…The effect of small amounts of water, in regard to inhibiting the adsorption of carbon dioxide (CO2), on several different cationic forms of zeolite X has been…”
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Diffusion in type A zeolites: New insights from old data
Published in Microporous and mesoporous materials (01-11-2012)“…Structure of zeolite A showing exchangeable cation sites. [Display omitted] ► Sorption rates in type A zeolites vary widely depending on sample pre-treatment…”
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6
Analysis and Interpretation of Zero Length Column Response Curves
Published in Chemie ingenieur technik (01-11-2013)“…To obtain reliable diffusivity data it is essential that the zero length columns (ZLC) response curve is measured under conditions of kinetic control. For…”
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Surface barriers and symmetry of adsorption and desorption processes
Published in Adsorption : journal of the International Adsorption Society (01-07-2021)“…Adsorption and desorption of hydrocarbons in a realistic model (2496 atoms) of ZSM-5 zeolite (MFI), including an external surface and a reservoir for…”
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8
Molecular Dynamics Study of Diffusion and Surface Permeation of Benzene in Silicalite
Published in Journal of physical chemistry. C (05-04-2018)“…Molecular dynamics simulations have been carried out to determine the uptake and release rates for benzene in an idealized crystal of silicalite (the pure…”
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Past Progress and Future Challenges in Adsorption Research
Published in Industrial & engineering chemistry research (03-07-2000)Get full text
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A review of common practices in gravimetric and volumetric adsorption kinetic experiments
Published in Adsorption : journal of the International Adsorption Society (01-04-2021)“…The availability of commercial gravimetric and volumetric systems for the measurement of adsorption equilibrium has seen also a growth of the use of these…”
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11
Diffusion Path Reversibility Confirms Symmetry of Surface Barriers
Published in Journal of physical chemistry. C (15-08-2019)“…The mass transfer resistance encountered by guest molecules entering or leaving a microporous host material (the “surface barrier”) is often comparable with or…”
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12
A rigorous criterion for approach to cyclic steady-state in PSA simulations
Published in Chemical engineering science (16-03-2017)“…An algorithm based on rigorous mathematical analysis is presented for determining the cyclic steady-state (CSS) in the simulation of Pressure Swing Adsorption…”
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13
CO2 capture: Value functions, separative work and process economics
Published in Chemical engineering science (26-07-2014)“…The relationship between the thermodynamic minimum work of separation and the “separative work” from the theory of staged separation processes is examined…”
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14
Diffusion in nanopores: inspecting the grounds
Published in Adsorption : journal of the International Adsorption Society (01-04-2021)“…This paper provides a general overview of the phenomenon of guest diffusion in nanoporous materials. It introduces the different types of diffusion measurement…”
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15
Transport in Nanoporous Materials Including MOFs: The Applicability of Fick's Laws
Published in Angewandte Chemie International Edition (23-11-2015)“…Diffusion in nanoporous host–guest systems is often considered to be too complicated to comply with such “simple” relationships as Fick’s first and second law…”
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16
Sorption kinetics: measurement of surface resistance
Published in Adsorption : journal of the International Adsorption Society (01-07-2021)“…The problem of measuring sorption kinetics in microporous adsorbents and distinguishing experimentally between surface resistance and internal diffusion is…”
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17
ZLC diffusion measurements: Combined effect of surface resistance and internal diffusion
Published in Chemical engineering science (26-03-2012)“…The mathematical model for a zero length column (ZLC) system has been extended to the practically important situation in which the sorption kinetics are…”
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Comment on “On Asymmetric Surface Barriers in MFI Zeolites Revealed by Frequency Response”
Published in Journal of physical chemistry. C (31-12-2015)Get full text
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Synergies between adsorption and energy conversion technologies
Published in Adsorption : journal of the International Adsorption Society (01-02-2021)“…The analogy between heat uptake in a thermal regenerator and selective uptake of gas components in an adsorbent bed has inspired development of alternative…”
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20
Diffusion of C2H6 and C2H4 in DDR Zeolite
Published in Industrial & engineering chemistry research (25-01-2012)“…Diffusion of ethane and ethylene in large crystals of DDR clathrisil (the pure silica analogue of ZSM-58) has been studied in detail by the zero length column…”
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