Search Results - "Rury, Aaron S"

Energy Cascades, Excited State Dynamics, and Photochemistry in Cob(III)alamins and Ferric Porphyrins by Rury, Aaron S, Wiley, Theodore E, Sension, Roseanne J

“…CONSPECTUS Porphyrins and the related chlorins and corrins contain a cyclic tetrapyrrole with the ability to coordinate an active metal center and to perform a…”
Get full text

Deciphering between enhanced light emission and absorption in multi-mode porphyrin cavity polariton samples by Odewale, Elizabeth O., Avramenko, Aleksandr G., Rury, Aaron S.

“…It remains unclear how the collective strong coupling of cavity-confined photons to the electronic transitions of molecular chromophore leverages the distinct…”
Get full text

Quantum Control of Ultrafast Internal Conversion Using Nanoconfined Virtual Photons by Avramenko, Aleksandr G, Rury, Aaron S

“…The rational control of nonradiative relaxation remains an unfulfilled goal of synthetic chemistry. In this study, we show how strongly coupling an ensemble of…”
Get full text

Light Emission from Vibronic Polaritons in Coupled Metalloporphyrin-Multimode Cavity Systems by Avramenko, Aleksandr G., Rury, Aaron S.

“…In this study, we explore how one can use cavity polariton formation and a non-Condon vibronic coupling mechanism to form a type of hybrid light–matter state…”
Get full text

Motional Narrowing through Photonic Exchange: Rational Suppression of Excitonic Disorder from Molecular Cavity Polariton Formation by Wanasinghe, Sachithra T., Gjoni, Adelina, Burson, Wade, Majeski, Caris, Zaslona, Bradley, Rury, Aaron S.

“…Maximizing the coherence between the constituents of molecular materials remains a crucial goal toward the implementation of these systems into everyday…”
Get full text

Assessing the Determinants of Cavity Polariton Relaxation Using Angle-Resolved Photoluminescence Excitation Spectroscopy by Odewale, Elizabeth O., Wanasinghe, Sachithra T., Rury, Aaron S.

“…The strong coupling of light and matter within electromagnetic resonators leads to the formation of cavity polaritons whose hybrid nature may help certain…”
Get full text

Kinetic Molecular Cationic Control of Defect-Induced Broadband Light Emission in 2D Hybrid Lead Iodide Perovskites by Sanni, Adedayo M, Rury, Aaron S

“…In this study, we examine the effects of changing organic cation concentrations on the efficiency and photophysical implications of exciton trapping in…”
Get full text

Interrogating the Structure of Molecular Cavity Polaritons with Resonance Raman Scattering: An Experimentally Motivated Theoretical Description by Avramenko, Aleksandr G, Rury, Aaron S

“…The formation of exciton polaritons by strongly coupling molecular electronic transitions to spatially confined photons may change photochemical processes…”
Get full text

Probing Fabry–Perot Interference in Self-Assembled Excitonic Microcrystals with Subgap Light Emission by Sanni, Adedayo M, Shuhag, Shofikur, Rury, Aaron S

“…Establishing a fundamental understanding of the range of optical effects possible in self-assembled excitonic materials remains crucial to the utility of these…”
Get full text

Anharmonic Molecular Vibrational Probes of Dynamical Organic–Inorganic Interactions in Two-Dimensional Hybrid Lead Iodide Perovskites by Sanni, Adedayo M, Lavan, Sydney N, Rury, Aaron S

“…There remains a gap in our knowledge of the fundamental physical determinants of dynamical interactions between the constituents of two-dimensional hybrid…”
Get full text

Defect-Induced Narrowband Light Emission from a 2D Hybrid Lead Iodide Perovskite by Sanni, Adedayo M, Lavan, Sydney N, Liu, Zhen-Fei, Rury, Aaron S

“…The formation of color centers capable of emitting narrowband light emission from solution-phase precursors would enable a new direction in the design and…”
Get full text

Coherent control of plasmonic spectra using the orbital angular momentum of light by Rury, Aaron S.

“…This study proposes a method to control the frequency-dependent scattering spectra from plasmonic spheres via the conservation of incident orbital angular…”
Get full text

Decorrelated singlet and triplet exciton delocalization in acetylene-bridged Zn-porphyrin dimers by Medagedara, Hasini, Teferi, Mandefro Y, Wanasinghe, Sachithra T, Burson, Wade, Kizi, Shahad, Zaslona, Bradly, Mardis, Kristy L, Niklas, Jens, Poluektov, Oleg G, Rury, Aaron S

“…The controlled delocalization of molecular excitons remains an important goal towards the application of organic chromophores in processes ranging from…”
Get full text

Room-Temperature Broadband Light Emission from Hybrid Lead Iodide Perovskite-Like Quantum Wells: Terahertz Spectroscopic Investigation of Metastable Defects by Sanni, Adedayo M, Lavan, Sydney N, Avramenko, Aleksandr, Rabuffetti, Federico A, Suescun, Leopoldo, Rury, Aaron S

“…The properties of mid-band-gap electronic states are central to the potential application of self-assembled, hybrid organic–inorganic perovskite-like quantum…”
Get full text

Electronic State-Resolved Electron–Phonon Coupling in an Organic Charge Transfer Material from Broadband Quantum Beat Spectroscopy by Rury, Aaron S, Sorenson, Shayne, Driscoll, Eric, Dawlaty, Jahan M

“…The coupling of electron and lattice phonon motion plays a fundamental role in the properties of functional organic charge-transfer materials. In this Letter…”
Get full text

Coherent Vibrational Probes of Hydrogen Bond Structure Following Ultrafast Electron Transfer by Rury, Aaron S, Sorenson, Shayne A, Dawlaty, Jahan M

“…We report measurements, ab initio calculations, and analytical models that reveal the coupling of low-frequency phonons to localized vibrations of a…”
Get full text

Evidence of Ultrafast Charge Transfer Driven by Coherent Lattice Vibrations by Rury, Aaron S, Sorenson, Shayne A, Dawlaty, Jahan M

“…We report evidence that intermolecular vibrations coherently drive charge transfer between the sites of a material on ultrafast time scales. Following a…”
Get full text

Defects Cause Subgap Luminescence from a Crystalline Tetracene Derivative by McAnally, R. Eric, Bender, Jon A, Estergreen, Laura, Haiges, Ralf, Bradforth, Stephen E, Dawlaty, Jahan M, Roberts, Sean T, Rury, Aaron S

“…We use steady-state and ultrafast nonlinear spectroscopies in combination with density functional theory calculations to explain light emission below the…”
Get full text

Solvent Thermodynamic Driving Force Controls Stacking Interactions between Polyaromatics by Rury, Aaron S, Ferry, Christine, Hunt, Jonathan Ryan, Lee, Myungjin, Mondal, Dibyendu, O’Connell, Sean M. O, Phan, Ethan N. H, Peng, Zaili, Pokhilko, Pavel, Sylvinson, Daniel, Zhou, Yingsheng, Mak, Chi H

“…Polyaromatic dye molecules employed in photovoltaic and electronic applications are often processed in organic solvents. The aggregation of these dyes is key…”
Get full text

Ligand Recruitment and Spin Transitions in the Solid-State Photochemistry of Fe(III)TPPCl by Rury, Aaron S, Goodrich, Lauren E, Galinato, Mary Grace I, Lehnert, Nicolai, Sension, Roseanne J

“…We report evidence for the formation of long-lived photoproducts following excitation of iron(III) tetraphenylporphyrin chloride (Fe(III)TPPCl) in a 1:1 glass…”
Get full text