Search Results - "Rumyantsev, Andrey V."
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Catalytic Imido-Transfer Reactions of Well-Defined Silica-Supported Titanium Imido Complexes Prepared via Surface Organometallic Chemistry
Published in Organometallics (13-04-2020)“…We expand the series of well-defined silica-supported titanium imido complexes of general formula (SiO)Ti(NtBu)X(py) n prepared via surface…”
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The Role of L‐Ligands in Silica‐Supported Ti Oxo/Imido Heterometathesis Catalysts
Published in Applied organometallic chemistry (01-12-2024)“…ABSTRACT We report here the preparation and characterization of new well‐defined silica‐supported Ti imido complexes that present an L‐ligand variation in a…”
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Tungsten Oxide Dispersed on Silica as Robust and Readily Available Oxo/Imido Heterometathesis Catalyst
Published in ChemPlusChem (Weinheim, Germany) (01-08-2024)“…Continuing our investigation of catalytic oxo/imido heterometathesis as novel water‐free method for C=N bond construction, we report here the application of…”
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Design of 4‐Coordinate Ti Imido Aryloxide on the Surface of Silica for Catalytic Oxo/Imido Heterometathesis
Published in Helvetica chimica acta (01-06-2022)“…We report here the synthesis of 4‐coordinate Ti imido complexes Ti(=NtBu)(OArtBu)2(py) (2) and Ti(=NtBu)(OArtBu)(Me2Pyr)(py) (3) (ArtBu=O‐2,6‐tBu2‐4‐MeC6H2,…”
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Ti-catalyzed heterometathetical condensation of N-sulfinylamines into sulfurdiimines
Published in Mendeleev communications (01-07-2024)“…[Display omitted] Well-defined silica-supported Ti imido complex (SiO)Ti(NBut)(Me2Pyr)(Py)2 (Me2Pyr = 2,5-dimethyl- pyrrolyl) catalyzes condensation of…”
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Vanadium(V) imido chlorides and n-propoxides — Towards a rational design of vanadium imido precatalysts for ethylene polymerization
Published in Journal of organometallic chemistry (15-02-2021)“…•3 chloride and 5 n-propoxide vanadium(V) imido complexes have been synthesized and characterized.•All complexes are active in ethylene polymerization upon…”
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