Search Results - "Rumyantcev, Roman V"
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Novel Oxidovanadium Complexes with Redox-Active R-Mian and R-Bian Ligands: Synthesis, Structure, Redox and Catalytic Properties
Published in Molecules (Basel, Switzerland) (21-09-2021)“…A new monoiminoacenaphthenone 3,5-(CF3)2C6H3-mian (complex 2) was synthesized and further exploited, along with the already known monoiminoacenaphthenone…”
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2
Synthesis of Trifluoromethylated Monoterpene Amino Alcohols
Published in Molecules (Basel, Switzerland) (01-10-2022)“…For the first time, monoterpene trifluoromethylated β-hydroxy-benzyl-O-oximes were synthesized in 81–95% yields by nucleophilic addition of the Ruppert–Prakash…”
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3
Water-Soluble Bismuth(III) Polynuclear Tyrosinehydroximate Metallamacrocyclic Complex: Structural Parallels to Lanthanide Metallacrowns
Published in Molecules (Basel, Switzerland) (23-09-2020)“…Recently there has been a great deal of interest and associated research into aspects of the coordination chemistry of lanthanides and bismuth-elements that…”
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4
Synthesis and Biological Activity of Unsymmetrical Monoterpenylhetaryl Disulfides
Published in Molecules (Basel, Switzerland) (01-08-2022)“…New unsymmetrical monoterpenylhetaryl disulfides based on heterocyclic disulfides and monoterpene thiols were synthesized for the first time in 48–88% yields…”
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5
Features of the Molecular Structure and Luminescence of Rare-Earth Metal Complexes with Perfluorinated (Benzothiazolyl)phenolate Ligands
Published in Molecules (Basel, Switzerland) (27-06-2019)“…A set of Sc, Nd, Sm, Eu, Ho, Gd, Er, Yb complexes with perfluorinated 2-(benzothiazol-2-yl)phenolate ligands Ln(SON ) (DME) were synthesized by the reactions…”
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6
Luminescent properties of 2-mercaptobenzothiazolates of trivalent lanthanides
Published in Physical chemistry chemical physics : PCCP (28-04-2015)“…A series of lanthanide complexes (Ln = Nd, Sm, Eu, Gd and Yb) with anionic 2-mercaptobenothiazolate (mbt) ligands were synthesized. Depending on the solvents…”
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Imine-Based Catechols and o‑Benzoquinones: Synthesis, Structure, and Features of Redox Behavior
Published in ACS omega (08-09-2020)“…Novel sterically hindered catechols of the type 3-(RNCH)-4,6-DBCatH2 with iminoalkyl or iminoaryl groups in the third position of the aromatic ring have been…”
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8
Synthesis and Antimicrobial Activity of Sulfenimines Based on Pinane Hydroxythiols
Published in Antibiotics (Basel) (01-11-2022)“…The widespread presence of multidrug-resistant pathogenic microorganisms challenges the development of novel chemotype antimicrobials, insensitive to microbial…”
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Single Crystal X‑ray Diffraction Studies of Two Polymorphic Modifications of the Dicarbonyl‑o‑Semiquinonato Rhodium Complex at Different Temperatures. Destruction Stimulated by Cooling Versus Stability
Published in ACS omega (22-12-2020)“…It was found that the dicarbonyl-rhodium-o-semiquinonate complex (which thread-like crystals can bend reversibly under light/warm activation) can form two…”
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10
Coordination polymers derived from gallium and zinc metal–metal bonded species
Published in Mendeleev communications (01-11-2022)“…[Display omitted] The reaction of (dpp-bian)Ga–Zn(dpp-bian) (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with 1,3-di(4-pyridyl)propane…”
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11
Praseodymium Metallacrown-Based NMR Probe for Enantioselective Discrimination of Mandelate Anions in Water
Published in Inorganic chemistry (06-03-2023)“…Recently, the enhanced interest in water-soluble aminohydroximate Ln(III)–Cu(II) metallacrowns (MC) is largely due to their fascinating structural chemistry,…”
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12
Lanthanide Coordination Polymers with Soft-Base Ditopic Bisthiazolate Ligands
Published in Inorganic chemistry (14-08-2023)“…In order to prepare the first lanthanide coordination polymers (CPs) based on ditopic sulfide ligands, benzo[1,2-d:4,5-d′]bisthiazole-2,6(3H,7H)-dithione…”
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13
Metal–Organic Frameworks Derived from Calcium and Strontium Complexes of a Redox-Active Ligand
Published in Inorganic chemistry (01-03-2021)“…The reactions of monomeric [(dpp-Bian)M(thf)4] (M = Ca (1a), Sr (1b); dpp-Bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with 4,4′-bipyridyl…”
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14
Reduction of CO 2 with Aluminum Hydrides Supported with Ar-BIAN Radical-Anions (Ar-BIAN = 1,2-Bis(arylimino)acenaphthene)
Published in Inorganic chemistry (10-01-2022)“…The reactions of H AlCl with [(dpp-Bian)Na(Et O) ] and [(Ar -Bian)Na(THF)] produce respective aluminum hydrides supported by radical-anionic…”
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Reactivity of Aluminum Complexes of Redox-Active Ligand toward N‑Heterocyclic Carbene and Its Thione
Published in Organometallics (13-01-2020)“…The reaction of dialane (dpp-Bian)Al–Al(dpp-Bian) (1) (dpp-Bian is dianion of 1,2-bis[(2,6-diisopropylphenyl)imino]-acenaphthene) with 1 mol equiv of…”
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Valence–Tautomeric Interconversion in a Bis(dioxolene)cobalt Complex with Iminopyridine Functionalized by a TEMPO Moiety. Phase Transition Coupled with Monocrystal Destruction
Published in Inorganic chemistry (18-12-2017)“…Iminopyridine modified by TEMPO nitroxide was utilized for the synthesis of an octahedral bis(o-semiquinonato)cobalt complex. Variable-temperature magnetic…”
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Dual Reactivity of 3a,6a-Diaza-1,4-diphosphapentalene: π‑Donor versus n‑Donor
Published in Inorganic chemistry (17-08-2020)“…Herein, we present the synthesis, single-crystal X-ray structures, and spectroscopic properties for the 1:1 donor–acceptor complexes of…”
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18
One‐Electron Reduction of 2‐Mono(2,6‐diisopropylphenylimino)acenaphthene‐1‐one (dpp‐mian)
Published in Chemistry : a European journal (12-03-2019)“…The electrochemical characteristics of 2‐mono(2,6‐diisopropylphenylimino)acenaphthene‐1‐one (dpp‐mian) have been investigated. One‐electron reduction of…”
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19
Unexpected Findings in a Simple Metathesis Reaction of Europium and Ytterbium Diiodides with Perfluorinated Mercaptobenzothiazolates of Alkali Metals
Published in Organometallics (24-08-2020)“…In the search for new f–d luminescent complexes of Eu(II) and Yb(II) the metathesis reactions of diiodides of these metals with perfluorinated…”
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20
Synthesis, Structure and Luminescent Properties of Rare‐Earth‐Metal Oxyacridinates
Published in European journal of inorganic chemistry (22-04-2021)“…Complexes of Sc, La, Sm, Gd, Tb and Yb with 1,3‐di‐tert‐butyl‐7‐methylacridin‐4‐olate (AcrMe) and 1,3‐di‐tert‐butyl‐7‐bromoacridin‐4‐olate (AcrBr) ligands were…”
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