Protective Cr coatings with CrN/Cr multilayers for zirconium fuel claddings

Cr coatings with CrN/Cr multilayers with a layer thickness of 100, 250 and 750 nm were deposited by a multi-cathode magnetron sputtering on E110 zirconium alloy in Ar and Ar + N2 atmosphere. The mechanical properties of the as-deposited coatings were measured by scratch testing and tribometry. A com...

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Bibliographic Details
Published in:Surface & coatings technology Vol. 433; p. 128131
Main Authors: Sidelev, D.V., Ruchkin, S.E., Syrtanov, M.S., Kashkarov, E.B., Shelepov, I.A., Malgin, A.G., Polunin, K.K., Stoykov, K.V., Mokrushin, A.A.
Format: Journal Article
Language:English
Published: Lausanne Elsevier B.V 15-03-2022
Elsevier BV
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Summary:Cr coatings with CrN/Cr multilayers with a layer thickness of 100, 250 and 750 nm were deposited by a multi-cathode magnetron sputtering on E110 zirconium alloy in Ar and Ar + N2 atmosphere. The mechanical properties of the as-deposited coatings were measured by scratch testing and tribometry. A comparative study of crack and oxidation resistance of the Cr-coated E110 alloy was performed under thermal cycling (1000 °С) and high-temperature (1200–1400 °С) steam oxidation conditions. The influence of the CrN/Cr multilayers and their thickness on the mechanical properties and oxidation resistance of the coated E110 alloy is discussed. It is found that the CrN/Cr multilayers can limit interdiffusion between the coating and E110 alloy at high temperatures only for a short period. •Increase in wear resistance of Cr-coated Zr alloy•CrN/Cr multilayers use as a barrier layer for CrZr interdiffusion•Role of thickness layer of CrN/Cr multilayers on cracking resistance•Nitrogen-stabilization of α-Zr phase underneath Cr coating•Deceleration of CrZr interdiffusion due to α-Zr(N) layer
ISSN:0257-8972
1879-3347
DOI:10.1016/j.surfcoat.2022.128131