Search Results - "Rubial, Belén"

Ring‐Opening Lithiation–Borylation of 2‐Trifluoromethyl Oxirane: A Route to Versatile Tertiary Trifluoromethyl Boronic Esters by Nandakumar, Meganathan, Rubial, Belén, Noble, Adam, Myers, Eddie L., Aggarwal, Varinder K.

“…Stereogenic trifluoromethyl‐substituted carbon centers are highly sought‐after moieties in pharmaceutical and agrochemical discovery. Here, we show that…”
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Silylium‐Catalyzed Alkynylation and Etherification Reactions of Benzylic Acetates by Rubial, Belén, Ballesteros, Alfredo, González, José M.

“…Addition of catalytic amounts of bistriflimide triggers useful coupling reactions of benzyl acetates with trimethyl(alkynyl)silanes and…”
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Silylium‐Catalyzed Carbon–Carbon Coupling of Alkynylsilanes with (2‐Bromo‐1‐methoxyethyl)arenes: Alternative Approaches by Rubial, Belén, Ballesteros, Alfredo, González, José M.

“…The catalytic activation of alkynylsilanes towards 2‐halo‐1‐alkoxyalkyl arenes gives β‐halo‐substituted alkynes. It involves the chemoselective substitution of…”
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Gold(I)-Catalyzed Bis-Alkynylation Reaction of Aromatic Aldehydes with Alkynylsilanes by Rubial, Belén, Ballesteros, Alfredo, González, José M.

“…The first successful gold(I)‐catalyzed reaction of aryl aldehydes with trimethyl(arylethynyl)silanes to furnish bis‐alkynylated derivatives is reported. Key…”
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Front Cover: Silylium‐Catalyzed Carbon–Carbon Coupling of Alkynylsilanes with (2‐Bromo‐1‐methoxyethyl)arenes: Alternative Approaches (Eur. J. Org. Chem. 45/2018) by Rubial, Belén, Ballesteros, Alfredo, González, José M.

“…The Front Cover shows the coupling reaction of trimethyl alkynyl silanes and (2‐bromo‐1‐methoxyethyl)arenes catalyzed by trimethylsilyl bis(triflimidate), at…”
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Enantiospecific Synthesis of ortho-Substituted 1,1-Diarylalkanes by a 1,2-Metalate Rearrangement/anti-SN 2' Elimination/Rearomatizing Allylic Suzuki-Miyaura Reaction Sequence by Rubial, Belén, Collins, Beatrice S L, Bigler, Raphael, Aichhorn, Stefan, Noble, Adam, Aggarwal, Varinder K

“…The one-pot sequential coupling of benzylamines, boronic esters, and aryl iodides has been investigated. In the presence of an N-activator, the boronate…”
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Enantiospecific Synthesis of ortho-Substituted 1,1-Diarylalkanes by a 1,2-Metalate Rearrangement/anti-S N 2' Elimination/Rearomatizing Allylic Suzuki-Miyaura Reaction Sequence by Rubial, Belén, Collins, Beatrice S L, Bigler, Raphael, Aichhorn, Stefan, Noble, Adam, Aggarwal, Varinder K

“…The one-pot sequential coupling of benzylamines, boronic esters, and aryl iodides has been investigated. In the presence of an N-activator, the boronate…”
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Enantiospecific Synthesis of ortho‐Substituted 1,1‐Diarylalkanes by a 1,2‐Metalate Rearrangement/anti‐SN2′ Elimination/Rearomatizing Allylic Suzuki–Miyaura Reaction Sequence by Rubial, Belén, Collins, Beatrice S. L., Bigler, Raphael, Aichhorn, Stefan, Noble, Adam, Aggarwal, Varinder K.

“…The one‐pot sequential coupling of benzylamines, boronic esters, and aryl iodides has been investigated. In the presence of an N‐activator, the boronate…”
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Enantiospecific Synthesis of ortho ‐Substituted 1,1‐Diarylalkanes by a 1,2‐Metalate Rearrangement/ anti ‐S N 2′ Elimination/Rearomatizing Allylic Suzuki–Miyaura Reaction Sequence by Rubial, Belén, Collins, Beatrice S. L., Bigler, Raphael, Aichhorn, Stefan, Noble, Adam, Aggarwal, Varinder K.

“…The one‐pot sequential coupling of benzylamines, boronic esters, and aryl iodides has been investigated. In the presence of an N‐activator, the boronate…”
Get full text

Ring‐Opening Lithiation–Borylation of 2‐Trifluoromethyl Oxirane: A Route to Versatile Tertiary Trifluoromethyl Boronic Esters by Nandakumar, Meganathan, Rubial, Belén, Noble, Adam, Myers, Eddie L., Aggarwal, Varinder K.

“…Stereogenic trifluoromethyl‐substituted carbon centers are highly sought‐after moieties in pharmaceutical and agrochemical discovery. Here, we show that…”
Get full text

Enantiospecific Synthesis of ortho‐Substituted 1,1‐Diarylalkanes by a 1,2‐Metalate Rearrangement/anti‐SN2′ Elimination/Rearomatizing Allylic Suzuki–Miyaura Reaction Sequence by Rubial, Belén, Collins, Beatrice S. L., Bigler, Raphael, Aichhorn, Stefan, Noble, Adam, Aggarwal, Varinder K.

“…The one‐pot sequential coupling of benzylamines, boronic esters, and aryl iodides has been investigated. In the presence of an N‐activator, the boronate…”
Get full text