Search Results - "Royal, Titouan"

Intermolecular Palladium(0)-Catalyzed Atropo-enantioselective C–H Arylation of Heteroarenes by Nguyen, Qui-Hien, Guo, Shu-Min, Royal, Titouan, Baudoin, Olivier, Cramer, Nicolai

“…Atropisomeric (hetero)­biaryls are motifs with increasing significance in ligands, natural products, and biologically active molecules. The straightforward…”
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Pd-catalyzed γ-arylation of γ,δ-unsaturated O -carbamates via an unusual haptotropic rearrangement by Royal, Titouan, Baudoin, Olivier

“…An unusual -selectivity was observed in the arylation of γ,δ-unsaturated -carbamates involving directed lithiation, transmetallation to zinc and Negishi…”
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Pd-catalyzed γ-arylation of γ,δ-unsaturated O-carbamates via an unusual haptotropic rearrangement† †Electronic supplementary information (ESI) available: Full optimization tables, procedural, spectral and X-ray crystallographic (CIF) data. CCDC 1878132 and 1884922. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc05058a by Royal, Titouan, Baudoin, Olivier

“…An unusual γ -selectivity was observed in the arylation of α-zincated γ,δ-unsaturated O -carbamates, which arose from the haptotropic rearrangement of the…”
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Enantioselective α‑Arylation of O‑Carbamates via Sparteine-Mediated Lithiation and Negishi Cross-Coupling by Royal, Titouan, Baumgartner, Yann, Baudoin, Olivier

“…A general and highly enantioselective arylation of carbamates derived from primary alcohols was developed by combining Hoppe’s sparteine-mediated asymmetric…”
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Pd-catalyzed γ-arylation of γ,δ-unsaturated -carbamates an unusual haptotropic rearrangement by Royal, Titouan, Baudoin, Olivier

“…An unusual γ -selectivity was observed in the arylation of γ,δ-unsaturated O -carbamates involving directed lithiation, transmetallation to zinc and Negishi…”
Get full text