Search Results - "Roy, Amalesh"
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Transition metal catalyzed asymmetric cyclopropanation via diazo decomposition: Ligand architecture defining stereoselectivity
Published in Synthetic communications (18-08-2018)“…Asymmetric cyclopropanation of alkenes through diazo decomposition mediated by transition metal complexes is a widely investigated catalytic reaction to obtain…”
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Radical induced fragmentation in a benzoxocane ring system: application to the synthesis of elvirol and a formal synthesis of 7,8-dihydroxycalamenene
Published in Tetrahedron (12-08-2012)“…A novel radical induced fragmentation in a benzoxocane ring system has been employed for a synthesis of elvirol 8 and an advanced intermediate in the synthesis…”
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3
Total synthesis of heliannuol B, an allelochemical from Helianthus annuus
Published in Tetrahedron letters (24-09-2007)“…A total synthesis of the allelochemical heliannuol B 1 is described employing ring closing metathesis to generate the central benzoxepane ring system…”
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Synthesis of (±)-heliannuol C
Published in Synthetic communications (17-09-2017)“…A synthesis of (±)-heliannuol C is described involving Bargellini condensation, Dieckmann cyclization and ortho-ester Claisen rearrangement followed by a…”
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5
Diverse Reactivities of Corey-Chaykovsky Ylides: Synthesis of 10-Hydroxyaplysin
Published in Synthetic communications (01-03-2012)“…The diverse reactivity patterns of the two sulfur ylides 7 and 8 were employed to convert the tricyclic ketone 5 to the isomeric methylene epoxides 9 and 6…”
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