Search Results - "Rowlands, Gareth J."

The synthesis of enantiomerically pure [2.2]paracyclophane derivatives by Rowlands, Gareth J

“…[2.2]Paracyclophane is a fascinating molecule that offers great potential in a wide range of chemical disciplines. Currently, the synthesis of the majority of…”
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The concise synthesis and resolution of planar chiral [2.2]paracyclophane oxazolines by C-H activation by Tewari, Shashank, Mungalpara, Maulik N, Patel, Suraj, Rowlands, Gareth J

“…Planar chiral [2.2]paracyclophanes are resolved through the direct C-H arylation of enantiopure oxazolines, providing a convenient route to ligands and chiral…”
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Planar Chiral Phosphines Derived from [2.2]Paracyclophane by Rowlands, Gareth J.

“…[2.2]Paracyclophane offers an exciting framework for the synthesis of planar chiral phosphines. Its rigid structure and unusual electronic properties have led…”
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Synthesis of a Boronic Acid Anhydride Based Ligand and Its Application in Beryllium Coordination by Buchner, Magnus R., Müller, Matthias, Raymond, Onyekachi, Severinsen, Rebecca J., Nixon, David J., Henderson, William, Brothers, Penelope J., Rowlands, Gareth J., Plieger, Paul G.

“…The synthesis of a boronic acid anhydride‐based ligand containing one three‐ and one four‐coordinated boron atom is presented. This ligand was successfully…”
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Breaking paracyclophane: the unexpected formation of non-symmetric disubstituted nitro[2.2]metaparacyclophanes by Patel, Suraj, Dais, Tyson N, Plieger, Paul G, Rowlands, Gareth J

“…Substituted [2.2]metaparacyclophanes are amongst the least studied of the simple cyclophanes. This is undoubtedly the result of the lengthy syntheses of these…”
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Radicals in organic synthesis: part 2 by Rowlands, Gareth J.

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Radicals in organic synthesis. Part 1 by Rowlands, Gareth J.

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Synthesis and characterization of Co(II) and Mn(II) [M3L3] triangles by Dais, Tyson N., Brown, Michael J., Coles, Martyn P., Laur, François, Price, Jason R., Rowlands, Gareth J., Plieger, Paul G.

“…We report an improved method to make the ligand N,N′ -(pyrazine-2,5-diylbis(methanylylidene))bis(2-(pyridin-2-yl)ethanamine) ( L ) and the subsequent…”
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Correlated Transcriptional Responses Provide Insights into the Synergy Mechanisms of the Furazolidone, Vancomycin, and Sodium Deoxycholate Triple Combination in Escherichia coli by Olivera, Catrina, Cox, Murray P, Rowlands, Gareth J, Rakonjac, Jasna

“…Effective therapeutic options are urgently needed to tackle antibiotic resistance. Furazolidone (FZ), vancomycin (VAN), and sodium deoxycholate (DOC) show…”
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Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives by Rowlands, Gareth J, Seacome, Richard J

“…This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the…”
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The Synthesis of Pyridyl[2.2]paracyclophanes by Palladium‐Catalyzed Cross‐Coupling of Pyridine Sulfinates by Mungalpara, Maulik N., Plieger, Paul G., Rowlands, Gareth J.

“…Substituted planar chiral pyridyl[2.2]paracyclophanes were prepared by the palladium‐catalyzed desulfinative cross‐coupling of bromo[2.2]paracyclophanes and…”
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Coordination cages in catalysis by Severinsen, Rebecca J., Rowlands, Gareth J., Plieger, Paul G.

“…Catalysis is an important process across multiple disciplines, and there are still many challenges to be met. Enzymes, “nature’s catalysts”, display impressive…”
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Synthesis and Basicity Studies of Quinolino[7,8‑h]quinoline Derivatives by Rowlands, Gareth J, Severinsen, Rebecca J, Buchanan, Jenna K, Shaffer, Karl J, Jameson, Heather T, Thennakoon, Nishani, Leito, Ivo, Lõkov, Märt, Kütt, Agnes, Vianello, Robert, Despotović, Ines, Radić, Nena, Plieger, Paul G

“…Quinolino­[7,8-h]­quinoline is a superbasic compound, with a pK aH in acetonitrile greater than that of 1,8-bis­(dimethylaminonaphthalene) (DMAN), although its…”
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Facile synthesis of planar chiral N-oxides and their use in Lewis base catalysis by Fulton, J Robin, Glover, Jean E, Kamara, Lamin, Rowlands, Gareth J

“…A rapid and versatile method for the preparation of planar chiral [2.2]paracyclophane-derived pyridines and pyridine N-oxides is reported. The potential…”
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The enantiospecific synthesis of (+)-monomorine I using a 5-endo-trig cyclisation strategy by Berry, Malcolm B, Craig, Donald, Jones, Philip S, Rowlands, Gareth J

“…We have developed a general strategy for the synthesis of 2,5-syn disubstituted pyrrolidines that is based on the multi-faceted reactivity of the sulfone…”
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Planar Chiral Triazole-Based Phosphanes Derived from [2.2]Paracyclophane and Their Activity in Suzuki Coupling Reactions by Glover, Jean E., Martin, David J., Plieger, Paul G., Rowlands, Gareth J.

“…In this communication we report the short synthesis of a variety of planar chiral triazole‐based phosphanes. These molecules have been readily prepared from…”
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The Proton Sponge Effect: Substitution of Quino[7,8-h]quinoline and the First Structurally Characterised Derivatives by Shaffer, Karl J., Parr, Daniel C., Wenzel, Marco, Rowlands, Gareth J., Plieger, Paul G.

“…A new route to unsymmetrical derivatives of quino[7,8‐h]quinoline was developed. Substitutions at the 2,11‐, 4,9‐ and 6,7‐positions of quino[7,8‐h]quinoline…”
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The Synthesis of Pyridylparacyclophanes by Palladium‐Catalyzed Cross‐Coupling of Pyridine Sulfinates by Mungalpara, Maulik N, Plieger, Paul G, Rowlands, Gareth J

“…Substituted planar chiral pyridyl[2.2]paracyclophanes were prepared by the palladium‐catalyzed desulfinative cross‐coupling of bromo[2.2]paracyclophanes and…”
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Ambifunctional cooperative catalysts by Rowlands, Gareth J.

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The synthesis of a [2.2]paracyclophane-derived secondary phosphine oxide and a study of its reactivity by Mungalpara, Maulik N., Wang, Jingjing, Coles, Martyn P., Plieger, Paul G., Rowlands, Gareth J.

“…A planar chiral secondary phosphine oxide based on [2.2]paracyclophane was synthesized and its chemistry investigated; it was shown to be a competent…”
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