Search Results - "Rowen, Julien F."

Vibrational Circular Dichroism of a Chiral Triplet Nitrene Investigated Under Matrix‐Isolation Conditions in Parahydrogen by Beyer, Frederike, Grassin, Corentin, Rowen, Julien F., Sander, Wolfram, Merten, Christian

“…Vibrational circular dichroism (VCD) spectra of chiral high‐spin organic radicals are expected to show a strong intensity enhancement and are thought to be…”
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Isomer-Specific Heavy-Atom Tunneling in the Ring Expansion of Fluorenylazirines by Rowen, Julien F., Beyer, Frederike, Schleif, Tim, Sander, Wolfram

“…The photolysis of 2-azidofluorene in solid argon at 3 K results in the formation of 2-fluorenylnitrene. The nitrene undergoes subsequent rearrangements to two…”
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Elusive Arylalkylcarbenes in Solution and in Crystals: Facile 1,2‑R (R = H, Ph) Migrations of 1,2,2-Triphenylethylidene by Fajardo, Javier, Rowen, Julien F., Schleif, Tim, Jariwala, Palak, Garcia-Garibay, Miguel A.

“…Highly reactive arylalkylcarbenes generated in solution by photolysis of their aryldiazoalkane precursors tend to undergo competing inter- and intramolecular…”
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Heavy‐Atom Tunneling in Semibullvalenes: How Driving Force, Substituents, and Environment Influence the Tunneling Rates by Schleif, Tim, Tatchen, Jörg, Rowen, Julien F., Beyer, Frederike, Sanchez‐Garcia, Elsa, Sander, Wolfram

“…The Cope rearrangement of selectively deuterated isotopomers of 1,5‐dimethylsemibullvalene 2 a and 3,7‐dicyano‐1,5‐dimethylsemibullvalene 2 b were studied in…”
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Heavy‐Atom Tunneling in Semibullvalenes: How Driving Force, Substituents, and Environment Influence the Tunneling Rates by Schleif, Tim, Tatchen, Jörg, Rowen, Julien F., Beyer, Frederike, Sanchez‐Garcia, Elsa, Sander, Wolfram

“…Invited for the cover of this issue are the groups of Elsa Sanchez‐Garcia and Wolfram Sander at the Universität Duisburg‐Essen and the Ruhr‐Universität Bochum…”
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Front Cover: Heavy‐Atom Tunneling in Semibullvalenes: How Driving Force, Substituents, and Environment Influence the Tunneling Rates (Chem. Eur. J. 46/2020) by Schleif, Tim, Tatchen, Jörg, Rowen, Julien F., Beyer, Frederike, Sanchez‐Garcia, Elsa, Sander, Wolfram

“…The heavy‐atom tunneling in the Cope rearrangement of selectively deuterated semibullvalenes was extensively studied. The experimental results from matrix…”
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