Search Results - "Rosenthal, Amos J."

Isolation of a C5-Deprotonated Imidazolium, a Crystalline "Abnormal" N-Heterocyclic Carbene by Aldeco-Perez, Eugenia, Rosenthal, Amos J., Donnadieu, Bruno, Parameswaran, Pattiyil, Frenking, Gernot, Bertrand, Guy

“…The discovery two decades ago of metal-free stable carbenes, especially imidazol-2-ylidenes [N-heterocyclic carbenes (NHCs)], has led to numerous breakthroughs…”
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A Phosphine-Coordinated Boron-Centered Gomberg-Type Radical by Rosenthal, Amos J., Devillard, Marc, Miqueu, Karinne, Bouhadir, Ghenwa, Bourissou, Didier

“…The P‐coordinated boryl radical [Ph2P(naphthyl)BMes]. (Mes=mesityl) was prepared by (electro)chemical reduction of the corresponding borenium salt or…”
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Facile Synthesis of Phosphaamidines and Phosphaamidinates using Nitrilium Ions as an Imine Synthon by van Dijk, Tom, Burck, Sebastian, Rong, Mark K., Rosenthal, Amos J., Nieger, Martin, Slootweg, J. Chris, Lammertsma, Koop

“…Readily accessible nitrilium triflates are convenient imine building blocks for the expedient synthesis of a novel class of 1,3‐P,N ligands as demonstrated for…”
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A Diolefin Diamide Rhodium(I) Complex and Its One-Electron Oxidation Resulting in a Two-Center, Three-Electron Rh-N Bond by Rosenthal, Amos J., Vogt, Matthias, de Bruin, Bas, Grützmacher, Hansjörg

“…A tetracoordinated diolefin diamide rhodium(I) complex 6 with the two amido and olefin groups in mutual trans‐position and a butterfly structure has been…”
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A Phosphine-Coordinated Boron-Centered Gomberg-Type Radical by Rosenthal, Amos J., Devillard, Marc, Miqueu, Karinne, Bouhadir, Ghenwa, Bourissou, Didier

“…The P‐coordinated boryl radical [Ph2P(naphthyl)BMes]. (Mes=mesityl) was prepared by (electro)chemical reduction of the corresponding borenium salt or…”
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B‑Centered Reactivity of Persistent P‑Stabilized Boryl Radicals by Rosenthal, Amos J, Mallet-Ladeira, Sonia, Bouhadir, Ghenwa, Sosa-Carrizo, Eric-Daiann, Miqueu, Karinne, Bourissou, Didier

“…A new P-stabilized boryl radical [iPr2P­(naph)­BMes]• 2a was obtained by reduction of the corresponding phosphino-bromoborane 1a with Na­(Hg). The persistent…”
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Facile Synthesis of Phosphaamidines and Phosphaamidinates using Nitrilium Ions as an Imine Synthon by van Dijk, Tom, Burck, Sebastian, Rong, Mark K., Rosenthal, Amos J., Nieger, Martin, Slootweg, J. Chris, Lammertsma, Koop

“…Readily accessible nitrilium triflates are convenient imine building blocks for the expedient synthesis of a novel class of 1,3‐P,N ligands as demonstrated for…”
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Synthesis and Coordination Chemistry of Iminophosphanes by van Dijk, Tom, Burck, Sebastian, Rosenthal, Amos J., Nieger, Martin, Ehlers, Andreas W., Slootweg, J. Chris, Lammertsma, Koop

“…Iminophosphanes are a new group of 1,3‐P,N‐ligands, readily obtainable from secondary phosphanes and nitrilium ions, having a tunable N‐donor site by means of…”
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η2-Coordination of a Phosphaalkyne to an Amino Olefin Nickel Complex and Regioselective Catalyzed Cyclooligomerization to Dewar 1,3,5-Triphosphabenzene by Trincado, Mónica, Rosenthal, Amos J., Vogt, Matthias, Grützmacher, Hansjörg

“…We report herein an efficient synthesis of a Dewar‐triphosphabenzene derived from [2+2+2] cycloaddition of three phosphaalkyne molecules promoted by an amino…”
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Diastereoselective Formation of Complexed Methylenediphosphiranes by Jansen, Helen, Rosenthal, Amos J, Slootweg, J. Chris, Ehlers, Andreas W, Lutz, Martin, Spek, Anthony L, Lammertsma, Koop

“…Stable syn-substituted methylenediphosphirane complexes are obtained from the reaction of transient, electrophilic phosphinidenes [R−PW(CO)5] (R = Me, Ph),…”
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[eta]2-Coordination of a Phosphaalkyne to an Amino Olefin Nickel Complex and Regioselective Catalyzed Cyclooligomerization to Dewar 1,3,5-Triphosphabenzene by Trincado, Mónica, Rosenthal, Amos J, Vogt, Matthias, Grutzmacher, Hansjörg

“…We report herein an efficient synthesis of a Dewar-triphosphabenzene derived from [2+2+2] cycloaddition of three phosphaalkyne molecules promoted by an amino…”
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η 2 ‐Coordination of a Phosphaalkyne to an Amino Olefin Nickel Complex and Regioselective Catalyzed Cyclooligomerization to Dewar 1,3,5‐Triphosphabenzene by Trincado, Mónica, Rosenthal, Amos J., Vogt, Matthias, Grützmacher, Hansjörg

“…Abstract We report herein an efficient synthesis of a Dewar‐triphosphabenzene derived from [2+2+2] cycloaddition of three phosphaalkyne molecules promoted by…”
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eta super(2)-Coordination of a Phosphaalkyne to an Amino Olefin Nickel Complex and Regioselective Catalyzed Cyclooligomerization to Dewar 1,3,5-Triphosphabenzene by Trincado, Monica, Rosenthal, Amos J, Vogt, Matthias, Gruetzmacher, Hansjorg

“…We report herein an efficient synthesis of a Dewar-triphosphabenzene derived from [2+2+2] cycloaddition of three phosphaalkyne molecules promoted by an amino…”
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