Search Results - "Rosemann, Nils W"
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A highly efficient directional molecular white-light emitter driven by a continuous-wave laser diode
Published in Science (American Association for the Advancement of Science) (10-06-2016)“…Tailored light sources have greatly advanced technological and scientific progress by optimizing the emission spectrum or color and the emission…”
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Tracing the Full Bimolecular Photocycle of Iron(III)–Carbene Light Harvesters in Electron-Donating Solvents
Published in Journal of the American Chemical Society (13-05-2020)“…Photoinduced bimolecular charge transfer processes involving the iron(III) N-heterocyclic carbene (FeNHC) photosensitizer [Fe(phtmeimb)2]+ (phtmeimb =…”
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3
Cluster‐Glass for Low‐Cost White‐Light Emission
Published in Advanced materials (Weinheim) (01-08-2022)“…The development of efficient and high‐brilliance white‐light sources is an essential contribution to innovative emission technologies. Materials exhibiting…”
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Photophysics and Photochemistry of Iron Carbene Complexes for Solar Energy Conversion and Photocatalysis
Published in Catalysts (01-03-2020)“…Earth-abundant first row transition metal complexes are important for the development of large-scale photocatalytic and solar energy conversion applications…”
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White‐Light Generation through Nonlinear Optical Response of 1,3,5,7‐Tetraphenyladamantane: Amorphous versus Crystalline States
Published in Advanced optical materials (19-06-2018)“…The vast optical nonlinearity of 1,3,5,7‐tetraphenyladamantane (AdPh4) enables efficient frequency conversion. The observed spectrum depends heavily on the…”
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Resonant X-ray photo-oxidation of light-harvesting iron (II/III) N-heterocyclic carbene complexes
Published in Scientific reports (12-11-2021)“…Two photoactive iron N -heterocyclic carbene complexes [ Fe II ( btz ) 2 ( bpy ) ] 2 + and [ Fe III ( btz ) 3 ] 3 + , where btz is…”
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Luminescence and reactivity of a charge-transfer excited iron complex with nanosecond lifetime
Published in Science (American Association for the Advancement of Science) (18-01-2019)“…Iron's abundance and rich coordination chemistry are potentially appealing features for photochemical applications. However, the photoexcitable charge-transfer…”
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Organotetrel Chalcogenide Clusters: Between Strong Second-Harmonic and White-Light Continuum Generation
Published in Journal of the American Chemical Society (21-12-2016)“…Highly directional white-light generation was recently reported for the organotin sulfide cluster [(StySn)4S6] (Sty = p-styryl). This effect was tentatively…”
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9
Tetrazole and Oxadiazole Derivatives as Thermally Activated Delayed Fluorescence Emitters
Published in Chemistry : a European journal (11-10-2024)“…Organic light‐emitting diodes (OLEDs) are promising lighting solutions for sustainability and energy efficiency. Incorporating thermally activated delayed…”
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10
Microsecond Photoluminescence and Photoreactivity of a Metal-Centered Excited State in a Hexacarbene–Co(III) Complex
Published in Journal of the American Chemical Society (27-01-2021)“…The photofunctionality of the cobalt–hexacarbene complex [Co(III)(PhB(MeIm)3)2]+ (PhB(MeIm)3 = tris(3-methylimidazolin-2-ylidene)(phenyl)borate) has…”
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Photofunctionality of iron(III) N-heterocyclic carbenes and related d transition metal complexes
Published in Coordination chemistry reviews (01-01-2021)Get full text
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12
Strain-Induced Structural Rearrangement Towards a White-Light-Emitting Adamantane-Type Cluster Dimer
Published in Angewandte Chemie International Edition (22-10-2024)“…Group 14/16 adamantane-type hybrid clusters of the type [(RT)4E6] (T = group 14 element, E = group 16 element, R = organic group) have been reported to emit…”
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A Stable Homoleptic Organometallic Iron(IV) Complex
Published in Chemistry : a European journal (06-10-2020)“…A homoleptic organometallic FeIV complex that is stable in both solution and in the solid state at ambient conditions has been synthesized and isolated as…”
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Adamantane-type clusters: compounds with a ubiquitous architecture but a wide variety of compositions and unexpected materials properties
Published in Chemical science (Cambridge) (26-06-2024)“…The research into adamantane-type compounds has gained momentum in recent years, yielding remarkable new applications for this class of materials. In…”
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Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)–NHC Complexes with Long-Lived 2LMCT Excited States
Published in Inorganic chemistry (07-11-2022)“…Fe(III) complexes with N-heterocyclic carbene (NHC) ligands belong to the rare examples of Earth-abundant transition metal complexes with long-lived…”
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Competing dynamics of intramolecular deactivation and bimolecular charge transfer processes in luminescent Fe() N-heterocyclic carbene complexes
Published in Chemical science (Cambridge) (29-03-2023)“…Steady state and ultrafast spectroscopy on [Fe III (phtmeimb) 2 ]PF 6 (phtmeimb = phenyl(tris(3-methylimidazol-2-ylidene))borate) was performed over a broad…”
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Dye-sensitized solar cells based on Fe N-heterocyclic carbene photosensitizers with improved rod-like push-pull functionality
Published in Chemical science (Cambridge) (15-12-2021)“…A new generation of octahedral iron( ii )-N-heterocyclic carbene (NHC) complexes, employing different tridentate C^N^C ligands, has been designed and…”
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Site-Selective Orbital Interactions in an Ultrathin Iron-Carbene Photosensitizer Film
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (27-02-2020)“…We present the first experimental study of the frontier orbitals in an ultrathin film of the novel hexa-carbene photosensitizer [Fe(btz)3]3+, where btz is…”
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How Rigidity and Conjugation of Bidentate Ligands Affect the Geometry and Photophysics of Iron N‑Heterocyclic Complexes: A Comparative Study
Published in Inorganic chemistry (11-03-2024)“…Two iron complexes featuring the bidentate, nonconjugated N-heterocyclic carbene (NHC) 1,1′-methylenebis(3-methylimidazol-2-ylidene) (mbmi) ligand, where the…”
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Tin Sulfide Clusters with Polyheteroatomic Ligands: Syntheses, Structures, and Photoluminescence Properties
Published in European journal of inorganic chemistry (01-12-2016)“…2‐Hydrazinobenzothiazole and 2‐furaldehyde diethyl acetal were connected to complementarily functionalized tin sulfide clusters, with coupling of an acetal to…”
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