Search Results - "Rosario, Scopelliti"

Nitrogen reduction and functionalization by a multimetallic uranium nitride complex by Falcone, Marta, Chatelain, Lucile, Scopelliti, Rosario, Živković, Ivica, Mazzanti, Marinella

“…A complex containing two uranium ions and three potassium ions, held together by a nitride group and a flexible molecular framework, can reduce and…”
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Isolation and characterization of diazoolefins by Varava, Paul, Dong, Zhaowen, Scopelliti, Rosario, Fadaei-Tirani, Farzaneh, Severin, Kay

“…Diazoolefins tend to be highly reactive compounds that rapidly lose dinitrogen. So far, most experimental evidence for diazoolefins is indirect, via trapping…”
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CO2 and CO/H2 Conversion to Methoxide by a Uranium(IV) Hydride by Falcone, Marta, Scopelliti, Rosario, Mazzanti, Marinella

“…Here we show that a scaffold combining siloxide ligands and a bridging oxide allows the synthesis and characterization of the stable dinuclear uranium­(IV)…”
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A smart low molecular weight gelator for the triple detection of copper (II), mercury (II), and cyanide ions in water resources by Mandegani, Fatemeh, Zali-Boeini, Hassan, Khayat, Zohreh, Scopelliti, Rosario

“…Novel supramolecular gelators based on quinoline-indolin-2-one structure were synthesized. These gelators formed stable organogels in a mixture of DMSO/H2O…”
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Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides by Federsel, Christopher, Boddien, Albert, Jackstell, Ralf, Jennerjahn, Reiko, Dyson, Paul J, Scopelliti, Rosario, Laurenczy, Gabor, Beller, Matthias

“…A will of iron: An active well‐defined iron complex (see structure; gray C, white H, yellow B, green F, brown Fe, pink P) catalyzes the title reaction (see…”
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Synthesis and Characterization of a Water Stable Uranyl(V) Complex by Faizova, Radmila, Scopelliti, Rosario, Chauvin, Anne-Sophie, Mazzanti, Marinella

“…We have identified a polydentate aminocarboxylate ligand that stabilizes uranyl­(V) in water. The mononuclear [UO2(dpaea)]­X, (dpaeaH2 =…”
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Synthesis, Reactivity, and Catalytic Application of a Nickel Pincer Hydride Complex by Breitenfeld, Jan, Scopelliti, Rosario, Hu, Xile

“…The nickel­(II) hydride complex [(MeN2N)­Ni-H] (2) was synthesized by the reaction of [(MeN2N)­Ni-OMe] (6) with Ph2SiH2 and was characterized by NMR and IR…”
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A molecular probe for the optical detection of biogenic amines by Lee, Boram, Scopelliti, Rosario, Severin, Kay

“…A coumarin derivative was employed for the detection of biogenic amines in buffered aqueous solution by UV-Vis or fluorescence spectroscopy. Incorporated in a…”
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Divergent Asymmetric Synthesis of Polycyclic Compounds via Vinyl Triazenes by Kossler, David, Perrin, Florian G., Suleymanov, Abdusalom A., Kiefer, Gregor, Scopelliti, Rosario, Severin, Kay, Cramer, Nicolai

“…Vinyl triazenes were obtained by enantioselective [2+2] cycloaddition reactions of bicyclic alkenes with 1‐alkynyl triazenes in the presence of a RuII catalyst…”
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Ligand and Metal Based Multielectron Redox Chemistry of Cobalt Supported by Tetradentate Schiff Bases by Andrez, Julie, Guidal, Valentin, Scopelliti, Rosario, Pécaut, Jacques, Gambarelli, Serge, Mazzanti, Marinella

“…We have investigated the influence of bound cations on the reduction of cobalt complexes of redox active ligands and explored the reactivity of reduced species…”
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Connection of Metallamacrocycles via Dynamic Covalent Chemistry: A Versatile Method for the Synthesis of Molecular Cages by Granzhan, Anton, Schouwey, Clément, Riis-Johannessen, Thomas, Scopelliti, Rosario, Severin, Kay

“…A modular approach for the synthesis of cage structures is described. Reactions of [(arene)RuCl2]2 [arene = p-cymene, 1,3,5-C6H3Me3, 1,3,5-C6H3(i-Pr)3] with…”
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Isolation of a Star-Shaped Uranium(V/VI) Cluster from the Anaerobic Photochemical Reduction of Uranyl(VI) by Chatelain, Lucile, White, Sarah, Scopelliti, Rosario, Mazzanti, Marinella

“…Actinide oxo clusters are an important class of compounds due to their impact on actinide migration in the environment. The photolytic reduction of uranyl(VI)…”
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Nickel-Catalyzed Direct Alkylation of Terminal Alkynes at Room Temperature: A Hemilabile Pincer Ligand Enhances Catalytic Activity by Pérez García, Pablo M, Ren, Peng, Scopelliti, Rosario, Hu, Xile

“…Direct coupling of alkyl halides with terminal alkynes provides an efficient and streamlined access to alkyl-substituted alkynes, which are important synthetic…”
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A Five-Coordinate Iron Center in the Active Site of [Fe]-Hydrogenase: Hints from a Model Study by Chen, Dafa, Scopelliti, Rosario, Hu, Xile

“…What's your number? The synthesis, structure, and reactivity of a five‐coordinate model complex of [Fe]‐hydrogenase are described. The work suggests that the…”
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One-Pot Synthesis of Trisubstituted Triazenes from Grignard Reagents and Organic Azides by Suleymanov, Abdusalom A, Scopelliti, Rosario, Fadaei Tirani, Farzaneh, Severin, Kay

“…A simple and versatile method for the preparation of linear, trisubstituted triazenes is reported. The procedure is based on the reaction of Grignard reagents…”
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A molecularly engineered hole-transporting material for efficient perovskite solar cells by Saliba, Michael, Orlandi, Simonetta, Matsui, Taisuke, Aghazada, Sadig, Cavazzini, Marco, Correa-Baena, Juan-Pablo, Gao, Peng, Scopelliti, Rosario, Mosconi, Edoardo, Dahmen, Klaus-Hermann, De Angelis, Filippo, Abate, Antonio, Hagfeldt, Anders, Pozzi, Gianluca, Graetzel, Michael, Nazeeruddin, Mohammad Khaja

“…Solution-processable perovskite solar cells have recently achieved certified power conversion efficiencies of over 20%, challenging the long-standing…”
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Ethynylbenziodazolones (EBZ) as Electrophilic Alkynylation Reagents for the Highly Enantioselective Copper‐Catalyzed Oxyalkynylation of Diazo Compounds by Hari, Durga Prasad, Schouwey, Lionel, Barber, Verity, Scopelliti, Rosario, Fadaei‐Tirani, Farzaneh, Waser, Jerome

“…Ethynylbenziodoxol(on)e (EBX) cyclic hypervalent iodine reagents are now established reagents for the alkynylation of radicals and nucleophiles, yet they…”
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Influence of Symmetry on the Luminescence and Radiative Lifetime of Nine-Coordinate Europium Complexes by Shavaleev, Nail M, Eliseeva, Svetlana V, Scopelliti, Rosario, Bünzli, Jean-Claude G

“…Homoleptic mononuclear nine-coordinate lanthanum­(III) and europium­(III) tris-complexes [Ln­(N∧N∧O)3]·nH2O with two tridentate N-benzylbenzimidazole…”
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Multicomponent Assembly of Macrocycles and Polymers by Coordination of Pyridyl Ligands to 1,4-Bis(benzodioxaborole)benzene by Icli, Burcak, Solari, Euro, Kilbas, Benan, Scopelliti, Rosario, Severin, Kay

“…Multicomponent reactions between 1,4‐benzenediboronic acid, catechol, and different pyridyl ligands are reported. The condensation of 1,4‐benzenediboronic acid…”
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Ligand Aspect Ratio as a Decisive Factor for the Self-Assembly of Coordination Cages by Jansze, Suzanne M, Cecot, Giacomo, Wise, Matthew D, Zhurov, Konstantin O, Ronson, Tanya K, Castilla, Ana M, Finelli, Alba, Pattison, Philip, Solari, Euro, Scopelliti, Rosario, Zelinskii, Genrikh E, Vologzhanina, Anna V, Voloshin, Yan Z, Nitschke, Jonathan R, Severin, Kay

“…It is possible to control the geometry and the composition of metallasupramolecular assemblies via the aspect ratio of their ligands. This point is…”
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