Search Results - "Ronchin, Lucio"
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Advanced 3D printed mini-vascular network for self-healing concrete
Published in Materials & design (01-06-2023)“…[Display omitted] •3D printed d-TETs satisfied the requirements, i.e. impermeability, rupture and release of healing agents at intended crack width.•The…”
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A New Pd-Based Catalytic System for the Reductive Carbonylation of Nitrobenzene to Form N-(4-hydroxyphenyl)acetamide Selectively in One Pot
Published in Reactions (Basel, Switzerland) (01-12-2023)“…N-(4-hydroxyphenyl)acetamide (commonly named paracetamol or acetaminophen) is a target molecules for many industries that produce chemicals for pharmaceutical…”
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Enhanced Antibacterial Activity of Vancomycin Loaded on Functionalized Polyketones
Published in Polymers (01-07-2024)“…Today, polymeric drug delivery systems (DDS) appear as an interesting solution against bacterial resistance, having great advantages such as low toxicity,…”
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Experimental Investigation of a Novel Formulation of a Cyanoacrylate-Based Adhesive for Self-Healing Concrete Technologies
Published in Frontiers in built environment (07-06-2021)“…The selection of an appropriate healing agent is critical to the success of vascular and mini-vascular networks. In self-healing concrete technology,…”
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Trifluoroacetic acid promoted hydration of styrene catalyzed by sulfonic resins: Comparison of the reactivity of styrene, n-hexene and cyclohexene
Published in Applied catalysis. A, General (25-01-2019)“…Cyclohexene hydration in TFA catalyzed by sulfonic resins. [Display omitted] •Trifluoroacetic acid acts as promoter and catalyst in olefin…”
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Phosgene-free synthesis of 1,3-diphenylurea via catalyzed reductive carbonylation of nitrobenzene
Published in Pure and applied chemistry (06-01-2012)“…1,3-Diphenylurea (DPU) has been proposed as a synthetic intermediate for phosgene-free synthesis of methyl -phenylcarbamate and phenyl isocyanate, which are…”
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Acidity and reactivity of trifluoromethanesulfonic acid in liquid and solid acid catalysts
Published in Journal of molecular catalysis. A, Chemical (01-10-2001)“…The acidic properties of CF 3SO 3H/SiO 2 acid catalysts have been investigated by the protonation of weak bases (B) (B+H +⇌BH +) and the proton-transfer…”
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New insight on the mechanism of the catalytic hydrogenation of nitrobenzene to 4-aminophenol in CH3CN–H2O–CF3COOH as a reusable solvent system. Hydrogenation of nitrobenzene catalyzed by precious metals supported on carbon
Published in Applied catalysis. A, General (05-04-2014)“…•Pt/C catalyzed nitrobenzene hydrogenation to 4-aminophenol in a single liquid phase.•CF3COOH–H2O–CH3CN easily reusable solvent acid system.•Activity and…”
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Beckmann rearrangement of acetophenone oximes to the corresponding amides organo-catalyzed by trifluoroacetic acid for sustainable NSAIDs synthesis
Published in Applied catalysis. A, General (22-02-2014)“…•High yield of acetaminophen and acetanilide is obtained under mild conditions.•Easy Beckmann rearrangement, easy recovery of the reagents, no work-up…”
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New Sustainable Pd(II)/Fe(III) Catalytic System Very Efficient in the Hydromethoxycarbonylation of 1-octene
Published in Periodica polytechnica. Chemical engineering. (28-02-2024)“…In order to increase the catalytic activity of the Pd(II)-complexes in the alcoxycarbonylation of 1-olefins, the presence in solution of a strong Brönsted acid…”
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Influence of formic acid and water on the [Pd(OAc)2(dppp)] catalyzed ethene–carbon monoxide copolymerization carried out in aprotic organic solvents
Published in Applied catalysis. A, General (27-12-2012)“…[Display omitted] ► [Pd(OAc)2(dppp)] as catalyst for the ethene–CO copolymerization. ► Best results in 1,4-dioxane-H2O-HCOOH as reaction medium. ► Productivity…”
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One-pot oximation–Beckmann rearrangement of ketones and aldehydes to amides of industrial interest: Acetanilide, caprolactam and acetaminophen
Published in Catalysis communications (05-04-2014)“…High yielding one-pot oximation–Beckmann rearrangement of ketones to amides in ktrifluoroacetic acid has been conducted on several ketones and aldehydes. The…”
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Carbon monoxide–ethene alternating copolymerization catalyzed by [PdCl2(dppf)] in H2O–HCOOH [dppf=1,1′-bis(diphenylphosphino)ferrocene]
Published in Journal of molecular catalysis. A, Chemical (01-11-2012)“…[Display omitted] ► [PdCl2(dppf)] catalyzes the CO–ethene copolymerization in H2O–HCOOH as a solvent. ► At 90°C 45MPa (CO/E, 1/1) H2O 50%, yield:…”
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Kinetics and mechanistic study of the Bamberger rearrangement of N-phenylhydroxylamine to 4-aminophenol in acetonitrile-trifluoroacetic acid: A substrate acid complex as para selectivity driver
Published in Applied catalysis. A, General (25-04-2016)“…[Display omitted] •Bamberger rearrangement of phenylhydroxylamine (PHA) to 4-aminophenol in acetonitrile.•Trifluoroacetic acid (TFA) an easily reusable acid…”
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Influence of formic acid and water on the [Pd(OAc)2(dppp)] catalyzed etheneacarbon monoxide copolymerization carried out in aprotic organic solvents
Published in Applied catalysis. A, General (27-12-2012)“…The copolymerization of ethene with carbon monoxide catalyzed by [Pd(OAc)2(dppp)] in an aprotic solvent such as 1,4-dioxane or nitromethane is efficiently…”
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Self-catalyzed direct amidation of ketones: A sustainable procedure for acetaminophen synthesis
Published in Catalysis communications (05-09-2014)“…High yielding amination of ketones and benzaldehyde in acid-less conditions has been conducted on several ketones to achieve amides and nitriles. The…”
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Supported palladium metal as heterogeneous catalyst precursor for the methoxycarbonylation of cyclohexene
Published in Molecular catalysis (01-03-2020)“…[Display omitted] •Pd metal is used as catalyst precursor for the methoxycarbonylation of cyclohexene.•Pd/cations exchanging resin led to activity comparable…”
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Acid Catalyzed Direct-Amidation–Dehydrocyclization of 2-Hydroxy-acetophenones to Benzoxazoles by a One-Pot Sustainable Synthesis
Published in Catalysis letters (01-03-2015)“…A series of 2-methyl-benzoxazoles have been synthesized starting from 2-hydroxy-acetophenones via a one-pot three steps reaction. Hydroxylamonium salt has been…”
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