Search Results - "Roland, Sébastien"
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Physico-chemical characterization of the blooming of Irganox 1076® antioxidant onto the surface of a silane-crosslinked polyethylene
Published in Polymer degradation and stability (01-01-2020)“…This study aims at investigating the blooming of Irganox 1076® onto the surface of a silane-crosslinked polyethylene. Preliminary studies on the commercial…”
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Thermal ageing of a silane-crosslinked polyethylene stabilised with an excess of Irganox 1076
Published in Polymer degradation and stability (01-07-2021)“…•Thermal ageing in air at 87°C, 110°C and 130°C of a Si-XLPE stabilised with an excess of phenolic antioxidant•Chemical consumption and physical loss by…”
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Thermal ageing of a silane-crosslinked polyethylene stabilised with a thiodipropionate antioxidant
Published in Polymer degradation and stability (01-11-2020)“…The thermal ageing of a silane-crosslinked polyethylene stabilised with 1 wt% of distearyl thiodipropionate (Irganox PS802) was studied in air at three…”
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Physico-chemical analysis of a silane-grafted polyethylene stabilised with an excess of Irganox 1076®. Proposal of a microstructural model
Published in Polymer degradation and stability (01-01-2021)“…•Solubility threshold of Irganox 1076® in Si-g-LLDPE around 0.9 wt% at 25°C•Above this critical value, exudation and blooming of antioxidant crystals at the…”
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Multi scale aging assessment of low-voltage cables subjected to radio-chemical aging: Towards an electrical diagnostic technique
Published in Polymer testing (01-11-2021)“…In this article, the aging behavior of nuclear-grade low voltage cables, characterized by different geometries and insulation compositions, is investigated…”
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A new analytical model for predicting the radio-thermal oxidation kinetics and the lifetime of electric cable insulation in nuclear power plants. application to silane cross-linked polyethylene
Published in Polymer degradation and stability (01-03-2021)“…•A new analytical kinetic model is proposed for the radio-thermal oxidation of Si-XLPE•Its reliability is successfully checked from the concentrations of…”
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Beware of the Flory parameter to characterize polymer-polymer interactions: A critical reexamination of the experimental literature
Published in European polymer journal (01-11-2016)“…[Display omitted] Methods for obtaining Flory parameter (χ) values for polymer blends or blocks are critically examined, for three simple systems…”
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Consequences of Radiothermal Ageing on the Crystalline Morphology of Additive-Free Silane-Crosslinked Polyethylene
Published in Polymers (18-07-2022)“…The radiothermal ageing of silane-crosslinked low-density PE (Si-XLPE) films was studied in the air under three different γ dose rates (8.5, 77.8, and 400…”
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Radiochemical Ageing of ATH Filled Silane‐Crosslinked Polyethylene
Published in Macromolecular symposia. (01-10-2022)“…This study focuses on the degradation of a silane cross‐linked polyethylene (Si‐XLPE) matrix filled with three different aluminum tri‐hydrate (ATH) contents:…”
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Numerical study of the relationship between the spherulitic microstructure and isothermal crystallization kinetics. Part I. 2-D analyses
Published in Polymer (Guilford) (28-09-2019)“…In this paper, we proposed a numerical model to study the kinetic properties and the spherulite microstructure of a semi-crystalline polymer under isothermal…”
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Multiscale framework for estimation of elastic properties of Poly ethylene terephthalate from the crystallization temperature
Published in Mechanics of materials (01-06-2023)“…A 2D multiscale numerical strategy is presented in this paper. It allows to generate a representative elementary volume (REV) with a spherulitic microstructure…”
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Towards a Kinetic Modeling of the Changes in the Electrical Properties of Cable Insulation during Radio-Thermal Ageing in Nuclear Power Plants. Application to Silane-Crosslinked Polyethylene
Published in Polymers (16-12-2021)“…The radio-thermal ageing of silane-crosslinked polyethylene (Si-XLPE) was studied in air under different γ dose rates (6.0, 8.5, 77.8, and 400 Gy·h ) at…”
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Coupling various in-situ methods to reveal the peculiar semi-crystalline morphology of melt-processed fluorinated copolymers
Published in Polymer (Guilford) (24-07-2024)“…Poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-co-TrFE)) copolymer and poly(vinylidene fluoride-ter-trifluoroethylene-ter-chlorotrifluoroethylene)…”
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Evolution of mechanical properties of aged poly(ether ketone ketone) explained by a microstructural approach
Published in Polymer degradation and stability (01-01-2021)“…•Branching/crosslinking is the prominent degradation process for PEKK.•Saito & Charlesby theories predict the crosslink number as a function of…”
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Morphology Evolution in Slowly Dip-Coated Supramolecular PS-b-P4VP Thin Films
Published in Macromolecules (10-07-2012)“…Block copolymer films obtained by dip-coating have been much less studied than those obtained by spin-coating, although it is an important industrial process…”
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Nanostructuration effect on the mechanical properties of PMMA toughened by a triblock acrylate copolymer using multilayer coextrusion
Published in Polymer (Guilford) (01-08-2018)“…Multilayer coextrusion was used to obtain nanolayered films of self-assembled commercial triblock copolymer poly(methyl methacrylate-b-butyl acrylate-b-methyl…”
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Double dynamic hydrogels formed by wormlike surfactant micelles and cross-linked polymer
Published in Journal of colloid and interface science (01-04-2022)“…[Display omitted] Interpenetrating networks consisting of a polymer network with dynamic cross-links and a supramolecular network allow obtaining hydrogels…”
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Preparation and characterization of poly(ethylene terephthalate) films coated by chitosan and vermiculite nanoclay
Published in Carbohydrate polymers (01-12-2018)“…•Poly(ethylene terephthalate) (PET) 130 μm thick films have been successfully coated with 1–3 μm thick of homogeneous layers of chitosan or…”
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A New Kinetic Modeling Approach for Predicting the Lifetime of ATH-Filled Silane Cross-Linked Polyethylene in a Nuclear Environment
Published in Polymers (06-04-2022)“…This study focuses on the degradation of a silane cross-linked polyethylene (Si-XLPE) matrix filled with three different contents of aluminum tri-hydrate…”
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Unraveling the morphological diversity of P(VDF-ter-TrFE-ter-CTFE) semi-crystalline terpolymers via combined AFM and SAXS experiments
Published in Polymer testing (01-03-2023)“…In this article, the diverse morphologies observed after annealing or crystallization from the melt in P(VDF-ter-TrFE-ter-CTFE) terpolymers with varying CTFE…”
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