Search Results - "Rodriguez, José A"
-
1
Low Temperature Activation of Methane on Metal-Oxides and Complex Interfaces: Insights from Surface Science
Published in Accounts of chemical research (18-08-2020)“…Conspectus The abundance of cheap, natural gas has transformed the energy landscape, whereby revealing new possibilities for sustainable chemical technologies…”
Get full text
Journal Article -
2
Activation and Conversion of Methane to Syngas over ZrO2/Cu(111) Catalysts near Room Temperature
Published in Journal of the American Chemical Society (05-04-2023)“…Enzymatic systems achieve the catalytic conversion of methane at room temperature under mild conditions. In this study, varying thermodynamic and kinetic…”
Get full text
Journal Article -
3
Hydrogenation of CO2 to Methanol: Importance of Metal–Oxide and Metal–Carbide Interfaces in the Activation of CO2
Published in ACS catalysis (06-11-2015)“…The high thermochemical stability of CO2 makes it very difficult to achieve the catalytic conversion of the molecule into alcohols or other hydrocarbon…”
Get full text
Journal Article -
4
Hydrogenation of CO2 to Methanol on a Auδ+–In2O3–x Catalyst
Published in ACS catalysis (02-10-2020)“…CO2 hydrogenation to methanol has attracted increasing attention with the development of renewable hydrogen. A big challenge is to identify catalysts able to…”
Get full text
Journal Article -
5
Bandgap- and Local Field-Dependent Photoactivity of Ag/Black Phosphorus Nanohybrids
Published in ACS catalysis (02-12-2016)“…Black phosphorus (BP) is the most exciting post-graphene layered nanomaterial that serendipitously bridges the 2D materials gap between semimetallic graphene…”
Get full text
Journal Article -
6
Highly Active Ceria-Supported Ru Catalyst for the Dry Reforming of Methane: In Situ Identification of Ruδ+–Ce3+ Interactions for Enhanced Conversion
Published in ACS catalysis (05-04-2019)“…The metal–oxide interaction changes the surface electronic states of catalysts deployed for chemical conversion, yet details of its influence on the catalytic…”
Get full text
Journal Article -
7
Highly Active Au/δ-MoC and Cu/δ-MoC Catalysts for the Conversion of CO2: The Metal/C Ratio as a Key Factor Defining Activity, Selectivity, and Stability
Published in Journal of the American Chemical Society (06-07-2016)“…The ever growing increase of CO2 concentration in the atmosphere is one of the main causes of global warming. Thus, CO2 activation and conversion toward…”
Get full text
Journal Article -
8
Selective Methane Oxidation to Methanol on ZnO/Cu2O/Cu(111) Catalysts: Multiple Site-Dependent Behaviors
Published in Journal of the American Chemical Society (17-11-2021)“…Because of the abundance of natural gas in our planet, a major goal is to achieve a direct methane-to-methanol conversion at medium to low temperatures using…”
Get full text
Journal Article -
9
Surface-Structure Sensitivity of CeO2 Nanocrystals in Photocatalysis and Enhancing the Reactivity with Nanogold
Published in ACS catalysis (01-07-2015)“…Structure–function correlations are a central theme in heterogeneous (photo)catalysis. In this study, using aberration-corrected scanning transmission…”
Get full text
Journal Article -
10
Theoretical Prediction and Experimental Verification of IrO x Supported on Titanium Nitride for Acidic Oxygen Evolution Reaction
Published in Journal of the American Chemical Society (19-06-2024)“…Reducing iridium (Ir) catalyst loading for acidic oxygen evolution reaction (OER) is a critical strategy for large-scale hydrogen production via proton…”
Get full text
Journal Article -
11
AP-XPS Study of the Reaction of O2 and CO2 with Zn–Au(111) Surface Alloys: Activation of O–O/C–O Bonds and the Formation of ZnO
Published in Journal of physical chemistry. C (13-08-2024)“…Synchrotron-based ambient-pressure X-ray photoelectron spectroscopy (AP-XPS) was used to study the dissociation of O2 and CO2 on Zn–Au(111) alloys, which…”
Get full text
Journal Article -
12
Catalysts for Hydrogen Evolution from the [NiFe] Hydrogenase to the Ni2P(001) Surface: The Importance of Ensemble Effect
Published in Journal of the American Chemical Society (26-10-2005)“…Density functional theory (DFT) was employed to investigate the behavior of a series of catalysts used in the hydrogen evolution reaction (HER, 2H+ + 2e- →…”
Get full text
Journal Article -
13
Water-Gas-Shift Reaction on Molybdenum Carbide Surfaces: Essential Role of the Oxycarbide
Published in The journal of physical chemistry. B (05-10-2006)“…Density functional theory (DFT) was employed to investigate the behavior of Mo carbides in the water-gas-shift reaction (WGS, CO + H2O → H2 +CO2). The kinetics…”
Get full text
Journal Article -
14
Inverse Oxide/Metal Catalysts in Fundamental Studies and Practical Applications: A Perspective of Recent Developments
Published in The journal of physical chemistry letters (07-07-2016)“…Inverse oxide/metal catalysts have shown to be excellent systems for studying the role of the oxide and oxide–metal interface in catalytic reactions. These…”
Get full text
Journal Article -
15
Effects of Zr Doping into Ceria for the Dry Reforming of Methane over Ni/CeZrO2 Catalysts: In Situ Studies with XRD, XAFS, and AP-XPS
Published in ACS catalysis (06-03-2020)“…The methane activation and methane dry reforming reactions were studied and compared over 4 wt % Ni/CeO2 and 4 wt % Ni/CeZrO2 (containing 20 wt % Zr)…”
Get full text
Journal Article -
16
Inverse oxide/metal catalysts: A versatile approach for activity tests and mechanistic studies
Published in Surface science (15-02-2010)“…There is a general desire to improve the configuration of industrial catalysts to take advantage of the intrinsic properties of metal oxides. In recent years,…”
Get full text
Journal Article -
17
Theoretical Studies of the Adsorption of CO and C on Ni(111) and Ni/CeO2(111): Evidence of a Strong Metal–Support Interaction
Published in Journal of physical chemistry. C (25-04-2013)“…The catalytic CO methanation reaction on Ni/CeO2(111) systems is known to depend on Ni coverage: at medium and large coverages, Ni/CeO2(111) surfaces are able…”
Get full text
Journal Article -
18
Redox Properties of TiO2 Thin Films Grown on Mesoporous Silica by Atomic Layer Deposition
Published in The journal of physical chemistry letters (25-05-2023)“…The redox properties of titania films grown by ALD on SBA-15, a silica-based mesoporous material, were characterized as a function of thickness (that is, the…”
Get full text
Journal Article -
19
Morphology Dependent Reactivity of CsOx Nanostructures on Au(111): Binding and Hydrogenation of CO2 to HCOOH
Published in ACS nano (28-11-2023)“…Cesium oxide (CsOx) nanostructures grown on Au(111) behave as active centers for the CO2 binding and hydrogenation reactions. The morphology and reactivity of…”
Get full text
Journal Article -
20
CO Oxidation on Gold-Supported Iron Oxides: New Insights into Strong Oxide–Metal Interactions
Published in Journal of physical chemistry. C (23-07-2015)“…Very active FeO x –Au catalysts for CO oxidation are obtained after depositing nanoparticles of FeO, Fe3O4, and Fe2O3 on a Au(111) substrate. Neither FeO nor…”
Get full text
Journal Article