Search Results - "Rodríguez‐Molina, Braulio"
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Global Performance Indices for Dynamic Crystals as Organic Thermal Actuators
Published in Advanced materials (Weinheim) (01-05-2020)“…Crystal adaptronics is an emergent materials science discipline at the intersection of solid‐state chemistry and mechanical engineering that explores the…”
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2
Rotation of a Bulky Triptycene in the Solid State: Toward Engineered Nanoscale Artificial Molecular Machines
Published in Journal of the American Chemical Society (25-06-2014)“…We report the design and dynamics of a solid-state molecular rotor with a large triptycene rotator. With a cross-section and surface area that are 2 and 3…”
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3
Hydrogen‐Bonded Crystalline Molecular Machines with Ultrafast Rotation and Displacive Phase Transitions
Published in Chemistry : a European journal (10-09-2020)“…Two new crystalline rotors 1 and 2 assembled through N−H⋅⋅⋅N hydrogen bonds by using halogenated carbazole as stators and 1,4‐diaza[2.2.2]bicyclooctane (DABCO)…”
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4
Amphidynamic Crystals of a Steroidal Bicyclo[2.2.2]octane Rotor: A High Symmetry Group That Rotates Faster than Smaller Methyl and Methoxy Groups
Published in Journal of the American Chemical Society (17-07-2013)“…The synthesis, crystallization, single crystal X-ray structure, and solid state dynamics of molecular rotor 3 provided with a high symmetry order and…”
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5
Gold-Catalyzed Ascorbic Acid-Induced Arylative Carbocyclization of Alkynes with Aryldiazonium Tetrafluoroborates
Published in ACS catalysis (06-08-2021)“…We describe, herein, arylative carbocyclization of alkynes catalyzed by gold. In this process, Au(I) is oxidized to Au(III) with aryldiazonium…”
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6
Synthesis of Dimeric Steroid Trioxabispiroacetals Scaffolds by Gold(I)‐Catalyzed Hydroalkoxylation–Hydration of Diynediols
Published in European journal of organic chemistry (15-08-2019)“…Five novel dimers in which the steroid cores are bridged by a 6,5,6‐trioxabispiroacetal moiety were synthesized by gold(I)‐catalyzed…”
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7
Dinuclear Organotin Building Blocks and their Conversion into a Tetranuclear Macrocycle Containing Sn−O−Sn Linkages
Published in European journal of inorganic chemistry (14-06-2021)“…Six dinuclear organotin building blocks of general composition RR′R′′SnCH2Si(CH3)2−biphenyl−Si(CH3)2CH2SnR′′R′R, in which the tin atoms are separated by a…”
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8
Asymmetric Dual‐State Emitters Featuring Thiazole Acceptors
Published in European journal of organic chemistry (20-09-2022)“…This work describes a new approach to construct highly conjugated molecules with asymmetric donor‐acceptor‐donor’ architectures (D−A−D’). Five new emissive…”
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Aggregation-Induced Emission Enhancement and Solid-State Photoswitching of Crystalline Carbazole N‑Salicylidene Anilines
Published in ACS omega (10-09-2024)“…The development of fluorescent stimuli-responsive organic materials has attracted substantial interest due to their increasing optoelectronic applications…”
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10
Engineered Photochromism in Crystalline Salicylidene Anilines by Facilitating Rotation to Reach the Colored trans-Keto Form
Published in Crystal growth & design (02-07-2014)“…The photochromism of crystalline salicylidene anilines regularly occurs by a volume-conserving bicycle pedal motion that transposes the relative position of…”
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11
Synthesis and Solid-State Characterization of Self-Assembled Macrocyclic Molecular Rotors of Bis(dithiocarbamate) Ligands with Diorganotin(IV)
Published in Organometallics (13-01-2014)“…Two bis(dithiocarbamate) (bdtc) metallamacrocyclic compounds, 1 and 2, and the deuterated analogues 1-d 8 and 1-d 20 were readily prepared through…”
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12
Toward Crystalline Molecular Rotors with Linearly Conjugated Diethynyl-Phenylene Rotators and Pentiptycene Stators
Published in Journal of organic chemistry (07-09-2012)“…A strategy for the construction of crystalline molecular rotors involves the assemblage of chemical structures that emulate the elements of macroscopic rotary…”
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13
Dual-State Emission (DSE) in Organic Fluorophores: Design and Applications
Published in Chemistry of materials (28-09-2021)“…Organic luminescent materials have attracted significant attention in the past few years due to their fascinating photophysical properties. Implementing these…”
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14
Throwing in a Monkey Wrench to Test and Determine Geared Motion in the Dynamics of a Crystalline One-Dimensional (1D) Columnar Rotor Array
Published in Journal of the American Chemical Society (13-02-2019)“…Crystals of molecular rotor 1 with a central 1,4-phenylene rotator linked to two molecules of the steroid mestranol were prepared with 1%, 5%, 20%, and up to…”
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15
Influence of Internal Molecular Motions in the Photothermal Conversion Effect of Charge-Transfer Cocrystals
Published in Chemistry of materials (12-12-2023)“…Herein, we report two new charge-transfer organic cocrystals, CP-TCNQ and CP-TFBQ. The two cocrystals exhibit broad absorption, good thermal stability, and low…”
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16
Diol Struts Stabilize the Structure of a 3D Hydrogen-Bonded Framework with Large Cavities: Inclusion of Solvated Nile Red in the Solid State
Published in Crystal growth & design (19-06-2024)“…Three-dimensional hydrogen-bonded frameworks (3D HBFs) based on organotin macrocycles were obtained by self-assembly of 2,5-pyridinedicarboxylic acid and…”
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Molecular Cage Assembly by Sn−O−Sn Bridging of Di‐, Tri‐ and Tetranuclear Organotin Tectons: Extending the Spacing in Double Ladder Structures
Published in Chemistry : a European journal (25-08-2021)“…Hydrolysis reactions of di‐ and trinuclear organotin halides yielded large novel cage compounds containing Sn−O−Sn bridges. The molecular structures of two…”
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18
Self-Assembly of Fluorinated Boronic Esters and 4,4′-Bipyridine into 2:1 N→B Adducts and Inclusion of Aromatic Guest Molecules in the Solid State: Application for the Separation of o,m,p‑Xylene
Published in Crystal growth & design (02-05-2018)“…A series of 2:1 fluorinated arylboronic ester adducts with 4,4′-bipyridine sustained by N→B dative bonds have been synthesized. The degree of fluorination in…”
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19
Self-Assembly of an Amphiphilic Bile Acid Dimer: A Combined Experimental and Theoretical Study of Its Medium-Responsive Fluorescence
Published in Journal of organic chemistry (04-03-2022)“…This work describes the synthesis and aggregation behavior of a dimeric bile acid derivative in which two steroid cores are bridged by a…”
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20
Indolocarbazole as a Platform for Concatenated Crystalline Rotors
Published in Crystal growth & design (06-09-2023)“…Herein, we describe a series of molecular rotors formed by cocrystallizing three indolo[3,2-b]carbazole (ICZ) derivatives with butyl and cyclohexyl…”
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