Search Results - "Rodgers, Ryan P."
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Advances in Asphaltene Petroleomics. Part 1: Asphaltenes Are Composed of Abundant Island and Archipelago Structural Motifs
Published in Energy & fuels (21-12-2017)“…For decades, discussion of asphaltene structure focused primarily on molecular weight. Now that it is widely accepted that asphaltene monomers are between ∼250…”
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Petroleomics: Chemistry of the underworld
Published in Proceedings of the National Academy of Sciences - PNAS (25-11-2008)“…Each different molecular elemental composition--e.g., CcHhNnOoSs--has a different exact mass. With sufficiently high mass resolving power (m/Δm₅₀% [almost…”
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21 Tesla FT-ICR Mass Spectrometer for Ultrahigh-Resolution Analysis of Complex Organic Mixtures
Published in Analytical chemistry (Washington) (06-02-2018)“…We describe complex organic mixture analysis by 21 tesla (T) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Ultrahigh mass-resolving…”
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Petroleomics: The Next Grand Challenge for Chemical Analysis
Published in Accounts of chemical research (01-01-2004)“…Ultrahigh-resolution Fourier transform ion cyclotron resonance mass spectrometry has recently revealed that petroleum crude oil contains heteroatom-containing…”
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Heavy Petroleum Composition. 5. Compositional and Structural Continuum of Petroleum Revealed
Published in Energy & fuels (21-03-2013)“…Twenty-five years ago, Boduszynski et al. conducted a comprehensive study of heavy oil composition and concluded that crude oil composition increases gradually…”
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Molecular-Level Characterization of Asphaltenes Isolated from Distillation Cuts
Published in Energy & fuels (21-03-2019)“…Asphaltenes challenge nearly all analytical techniques because of their immense polydispersity in molecular composition and structure. This operationally…”
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Identification of Vanadyl Porphyrins in a Heavy Crude Oil and Raw Asphaltene by Atmospheric Pressure Photoionization Fourier Transform Ion Cyclotron Resonance (FT-ICR) Mass Spectrometry
Published in Energy & fuels (16-04-2009)“…Vanadyl porphyrins are detected and characterized by their double-bond equivalents (DBE = number of rings plus double bonds) and carbon number in an…”
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Petroleomics: advanced molecular probe for petroleum heavy ends
Published in Journal of mass spectrometry. (01-04-2011)“…To look into complex mixtures of petroleum heavy ends at the molecular level, ultra high‐resolution mass spectrometry, i.e. resolving power > 50 000, is needed…”
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Functional Isomers in Petroleum Emulsion Interfacial Material Revealed by Ion Mobility Mass Spectrometry and Collision-Induced Dissociation
Published in Energy & fuels (19-01-2017)“…Petroleum emulsion interfacial material (species that reside in the water/oil interface) are believed to be responsible for stabilizing emulsions in petroleum;…”
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Heavy Petroleum Composition. 1. Exhaustive Compositional Analysis of Athabasca Bitumen HVGO Distillates by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry: A Definitive Test of the Boduszynski Model
Published in Energy & fuels (20-05-2010)“…Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) allows detailed characterization of complex petroleum samples at the level of elemental…”
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Stepwise Structural Characterization of Asphaltenes during Deep Hydroconversion Processes Determined by Atmospheric Pressure Photoionization (APPI) Fourier Transform Ion Cyclotron Resonance (FT-ICR) Mass Spectrometry
Published in Energy & fuels (15-04-2010)“…The compositional analysis (speciation) of heavy oil products is a key step to improve our understanding of hydrotreatment processes and reaction mechanisms…”
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Atmospheric Pressure Photoionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry for Complex Mixture Analysis
Published in Analytical chemistry (Washington) (15-08-2006)“…We have coupled atmospheric pressure photoionization (APPI) to a home-built 9.4-T Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer…”
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Unprecedented Ultrahigh Resolution FT-ICR Mass Spectrometry and Parts-Per-Billion Mass Accuracy Enable Direct Characterization of Nickel and Vanadyl Porphyrins in Petroleum from Natural Seeps
Published in Energy & fuels (17-04-2014)“…The most abundant and problematic metal compounds in crude oil exist as organic complexes of vanadium and nickel in porphyrin structures derived from…”
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Isomeric Separation and Structural Characterization of Acids in Petroleum by Ion Mobility Mass Spectrometry
Published in Energy & fuels (18-06-2015)“…Although naphthenic acids are minor constituents in petroleum, their characterization is crucial because they are geochemically important tracers and play a…”
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Oil Spill Source Identification by Principal Component Analysis of Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectra
Published in Analytical chemistry (Washington) (01-10-2013)“…One fundamental challenge with either acute or chronic oil spills is to identify the source, especially in highly polluted areas, near natural oil seeps, when…”
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Two- and Three-Dimensional van Krevelen Diagrams: A Graphical Analysis Complementary to the Kendrick Mass Plot for Sorting Elemental Compositions of Complex Organic Mixtures Based on Ultrahigh-Resolution Broadband Fourier Transform Ion Cyclotron Resonance Mass Measurements
Published in Analytical chemistry (Washington) (01-05-2004)“…Ultrahigh-resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry has resolved and identified the elemental compositions…”
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Resolution of 11 000 Compositionally Distinct Components in a Single Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrum of Crude Oil
Published in Analytical chemistry (Washington) (15-08-2002)“…Mass spectrometry is well-suited for complex mixture analysis, because unlike other types of spectroscopy, the number of mass spectral peaks per analyte is of…”
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Mass Spectral Analysis of Asphaltenes. I. Compositional Differences between Pressure-Drop and Solvent-Drop Asphaltenes Determined by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry
Published in Energy & fuels (20-09-2006)“…Asphaltenes are typically defined by their solubility in benzene and insolubility in pentane or heptane. They are believed to exist in petroleum crude oil as a…”
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Atmospheric Pressure Laser-Induced Acoustic Desorption Chemical Ionization Mass Spectrometry for Analysis of Saturated Hydrocarbons
Published in Analytical chemistry (Washington) (21-08-2012)“…We present atmospheric pressure laser-induced acoustic desorption chemical ionization (AP/LIAD-CI) with O2 carrier/reagent gas as a powerful new approach for…”
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Speciation of Nitrogen Containing Aromatics by Atmospheric Pressure Photoionization or Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry
Published in Journal of the American Society for Mass Spectrometry (01-07-2007)“…We determine the elemental compositions of aromatic nitrogen model compounds as well as a petroleum sample by atmospheric pressure photoionization (APPI) and…”
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