Search Results - "Robinson, Randall E"

Long-Range Electronic Coupling of MM Quadruple Bonds (M = Mo or W) via a 2,6-Azulenedicarboxylate Bridge by Barybin, Mikhail V, Chisholm, Malcolm H, Dalal, Naresh S, Holovics, Thomas H, Patmore, Nathan J, Robinson, Randall E, Zipse, David J

“…The preparation of 2,6-azulenedicarboxylic acid (I) from its diester, 2-CO2 t Bu-6-CO2-C10H6 (II), is reported together with the crystal and molecular…”
Get full text

Five Possible Isocyanoazulenes and Electron-Rich Complexes Thereof:  A Quantitative Organometallic Approach for Probing Electronic Inhomogeneity of the Azulenic Framework by Robinson, Randall E, Holovics, Thomas C, Deplazes, Stephan F, Powell, Douglas R, Lushington, Gerald H, Thompson, Ward H, Barybin, Mikhail V

“…Efficient syntheses of all five possible isocyanoazulenes, the four isomeric archetypal compounds CN1Az, CN2Az, CN4Az, and CN6Az, as well as the…”
Get full text

The 2,6-Diisocyanoazulene Motif:  Synthesis and Efficient Mono- and Heterobimetallic Complexation with Controlled Orientation of the Azulenic Dipole by Holovics, Thomas C, Robinson, Randall E, Weintrob, Edward C, Toriyama, Masaharu, Lushington, Gerald H, Barybin, Mikhail V

“…Synthesis of the remarkably air- and thermally stable 2,6-diisocyano-1,3-diethoxycarbonylazulene linker from 2-amino-1,3-diethoxycarbonylazulene in 57%…”
Get full text

Interaction of Mono- and Diisocyanoazulenes with Gold Surfaces:  First Examples of Self-Assembled Monolayer Films Involving Azulenic Scaffolds by DuBose, David L, Robinson, Randall E, Holovics, Thomas C, Moody, David R, Weintrob, Edward C, Berrie, Cindy L, Barybin, Mikhail V

“…The formation and properties of a new class of self-assembled monolayers (SAM) of aryl isocyanides and diisocyanides based on the nonbenzenoid azulenic…”
Get full text

Ring-Closing Metathesis Strategies to Cyclic Sulfamide Peptidomimetics by Dougherty, Joseph M, Probst, Donald A, Robinson, Randall E, Moore, Joel D, Klein, Thomas A, Snelgrove, Kelley A, Hanson, Paul R

“…Ring-closing metathesis (RCM) strategies toward the synthesis of a number of constrained sulfamides are discussed. This approach exploits the inherent…”
Get full text

First Isocyanoazulene and Its Homoleptic Complexes by Robinson, Randall E, Holovics, Thomas C, Deplazes, Stephan F, Lushington, Gerald H, Powell, Douglas R, Barybin, Mikhail V

“…An efficient synthesis of remarkably stable 6-isocyanoazulene (CN6Az), the first nonbenzenoid organic isocyanide, is described. Its superb π-accepting…”
Get full text

Chlorination of bicyclo[1.1.1]pentane derivatives by Robinson, Randall E, Michl, Josef

Get full text

Cyclic sulfonamides via the ring-closing metathesis reaction by Hanson, Paul R., Probst, Donald A., Robinson, Randall E., Yau, Mei

“…The first examples of ring-closing metathesis (RCM) reactions on allyl- and vinylsulfonamide templates 1 and 2 catalyzed by the Grubbs ruthenium alkylidene 3…”
Get full text

Reactions of reduced cyclophanes: Electrophilic bromination — A double homoconjugate addition by Robinson, Randall E., Myers, Drew Y.

“…As part of a reawakening of interest in the chemistry of [2.2]paracyclophane derivatives a program to exploit the complexity of partially reduced cyclophanes…”
Get full text