Search Results - "Rieder, Curtis J"
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Cyclization of Cross-Conjugated Trienes: The Vinylogous Nazarov Reaction
Published in Journal of the American Chemical Society (10-06-2009)“…Cross-conjugated trienoates can be readily prepared from 1,4-pentadien-3-one precursors via a 2-step process: 1,2-addition of lithiated ethynyl ethyl ether…”
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Heteroaromatic Trapping of Tricyclic 2-Oxidocyclopentenyl Cations: A Surprisingly Efficient Example of Intermolecular Interrupted Nazarov Reaction
Published in Heterocycles (01-03-2010)Get full text
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An Unexpected Incident during the Manufacture of O‑(Diphenylphosphinyl)hydroxylamine
Published in Organic process research & development (15-10-2021)“…Scaling up processes to the manufacturing setting demands vigilance, even with controls implemented to mitigate potential thermal hazards. This was highlighted…”
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Olefination of α,α′-Divinyl Ketones through Catalytic Meyer−Schuster Rearrangement
Published in Journal of organic chemistry (07-01-2011)“…The direct olefination of 1,4-dien-3-ones remains a synthetic challenge. A two-step protocol, employing acetylide addition followed by catalytic Meyer−Schuster…”
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Formation of an Endoperoxide upon Chromium-Catalyzed Allylic Oxidation of a Triterpene by Oxygen
Published in Journal of organic chemistry (02-01-2015)“…The chromium-catalyzed allylic oxidation of triterpene 1 with O2 and N-hydroxyphthalimide (NHPI, 5 equiv) formed endoperoxide 2 in 76% yield at ambient…”
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Synthesis and Reactivity of 1,2-Dioxolanes from β,γ-Epoxy Ketones
Published in Organic letters (16-05-2014)“…Five-membered ring peroxides were prepared in one step in 31–86% yield from readily accessible β,γ-epoxy ketones and H2O2. The reaction proceeded via a…”
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Construction of aryl-substituted triquinanes through the interrupted Nazarov reaction
Published in Chemical communications (Cambridge, England) (01-01-2008)“…The first examples of intermolecular trapping of Nazarov cyclopentenyl cation intermediates by simple arenes to furnish alpha-arylcyclopentanones are described…”
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