Search Results - "Reynolds, Jacob G"
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Salt Solubilities in Aqueous Solutions of NaNO3, NaNO2, NaCl, and NaOH: A Hofmeister-like Series for Understanding Alkaline Nuclear Waste
Published in ACS omega (30-11-2018)“…Nonelectrolyte solubility in electrolyte solutions follow the Hofmeister series, but the applicability of the series to salt solubility has been less…”
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A method to apply Zavitsas' aqueous electrolyte model to multicomponent solutions and its equivalence to Zdanovskii's rule
Published in AIChE journal (01-02-2022)“…Zavitsas developed an aqueous electrolyte thermodynamic model and applied it to single electrolyte solutions previously. Here, a method to apply the model to…”
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Resolving intermediates during the growth of aluminum deuteroxide (Hydroxide) polymorphs in high chemical potential solutions
Published in Communications chemistry (04-09-2024)“…Aluminum hydroxide polymorphs are of widespread importance yet their kinetics of nucleation and growth remain beyond the reach of current models. Here we…”
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A Review of Sodium Fluoride Solubility in Water
Published in Journal of chemical and engineering data (08-06-2017)“…The solubility of NaF in water is important to a number of industries, but there is a limited review of the large amount of solubility data scattered…”
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A Review of Sodium Nitrite Solubility in Water and Physical Properties of the Saturated Solutions
Published in Journal of chemical and engineering data (12-08-2021)“…The solubility of sodium nitrite (NaNO2) in water is important to many industries, including those of heat pumps, oil extraction, and the management of…”
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Large cemented gibbsite agglomerates in alkaline nuclear waste at the Hanford site and the impacts to remediation
Published in Journal of hazardous materials (15-02-2020)“…[Display omitted] •7-cm diameter gibbsite particles grew over 40+ years in alkaline waste.•These particles inhibited retrieval because they do not fit in…”
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Strontium/strontium‐90 removal from chelate‐bearing Hanford tank waste using crystalline silicotitanate
Published in Environmental progress & sustainable energy (01-05-2022)“…A study was conducted to evaluate if crystalline silicotitanate (CST) could be used to remove 90Sr from highly chelated tank waste in support of tank waste…”
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Ab Initio Molecular Dynamics Reveal Spectroscopic Siblings and Ion Pairing as New Challenges for Elucidating Prenucleation Aluminum Speciation
Published in The journal of physical chemistry. B (26-07-2018)“…The characterization of prenucleation species is essential to understand crystallization mechanisms across many chemical systems and often involves the use of…”
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Gibbsite Solubility in Hanford Nuclear Waste Approached from above and below Saturation
Published in Industrial & engineering chemistry research (18-05-2016)“…Liquid Hanford nuclear wastes are highly concentrated caustic aqueous electrolyte solutions. They contain elevated dissolved aluminum concentrations compared…”
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apparent solubility of aluminum (III) in Hanford high-level waste
Published in Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering (01-12-2012)“…The solubility of aluminum in Hanford nuclear waste impacts on the processability of the waste by a number of proposed treatment options. For many years,…”
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Multinuclear PFGSTE NMR description of 39K, 23Na, 7Li, and 1H specific activation energies governing diffusion in alkali nitrite solutions
Published in Journal of magnetic resonance (1997) (01-07-2024)“…[Display omitted] •Established feasibility of 39K PFGSTE NMR in concentrated potassium nitrite solutions despite unfavorable NMR properties•Identified viable…”
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12
Multinuclear PFGSTE NMR description of 39 K, 23 Na, 7 Li, and 1 H specific activation energies governing diffusion in alkali nitrite solutions
Published in Journal of magnetic resonance (1997) (01-07-2024)“…While pulsed field gradient stimulated echo nuclear magnetic resonance (PFGSTE NMR) spectroscopy has found widespread use in the quantification of…”
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A sulfate and darapskite solubility model with Pitzer interaction coefficients for aqueous solutions containing NaNO2, NaNO3, and NaOH
Published in The Journal of chemical thermodynamics (01-10-2016)“…•Molal-based Pitzer model coefficients developed.•Sulfate-anion interaction parameters are temperature independent.•Gibbs energies and enthalpies of darapskite…”
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A Pitzer Interaction Model for the NaNO3–NaNO2–NaOH–H2O System from 0 to 100 °C
Published in Industrial & engineering chemistry research (25-03-2015)“…The solubility relations and water activities in NaNO3, NaNO2, and NaOH solutions are used in many applications, including the management of alkaline…”
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Conversion of Coarse Gibbsite Remaining in Hanford Nuclear Waste Tank Heels to Solid Sodium Aluminate [NaAl(OH)4·1.5H2O]
Published in Industrial & engineering chemistry research (10-09-2014)“…The Hanford Site near Richland, WA, has 177 high-level nuclear waste tanks containing 56 million gallons of waste derived from nuclear fuel reprocessing. The…”
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16
Development of a carbonate crust on alkaline nuclear waste sludge at the Hanford site
Published in Journal of hazardous materials (15-01-2018)“…[Display omitted] •A hard crust which inhibited nuclear waste remediation efforts was examined.•Formation of carbonates from CO2 absorption was shown to have…”
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The importance of ion interactions on electrolyte solution viscosities determined by comparing concentrated sodium carbonate and nitrate solutions
Published in Journal of molecular liquids (15-08-2019)“…Sodium carbonate is a common electrolyte in high pH aqueous solution, and its contribution to the viscosity of those electrolytes solutions is of practical…”
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Sodium strontium phosphate nonahydrate (NaSrPO4·9H2O) found in Hanford nuclear waste
Published in Journal of radioanalytical and nuclear chemistry (01-10-2020)“…The Hanford site, near Richland, WA, in the U.S.A., has legacy radioactive waste left over from plutonium production. Strontium-90 and its short-lived daughter…”
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Salt Solubilities in Aqueous Solutions of NaNO 3 , NaNO 2 , NaCl, and NaOH: A Hofmeister-like Series for Understanding Alkaline Nuclear Waste
Published in ACS omega (30-11-2018)“…Nonelectrolyte solubility in electrolyte solutions follow the Hofmeister series, but the applicability of the series to salt solubility has been less…”
Get full text
Journal Article -
20
The relative viscosity of NaNO3 and NaNO2 aqueous solutions
Published in Journal of molecular liquids (15-08-2018)“…In aqueous solution, both nitrate and nitrite are planar, monovalent, and have the same elements but different sizes and charge densities. Comparing the…”
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