Search Results - "Retamosa, María de Gracia"
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1
Recent Development in Palladium-Catalyzed Domino Reactions: Access to Materials and Biologically Important Carbo- and Heterocycles
Published in Organometallics (13-05-2019)“…The chemistry of palladium complexes has no limits. Many domino processes (even multicomponent) are continuously appearing in the literature. Carbocyclic and…”
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2
Densely Substituted l‑Proline Esters as Catalysts for Asymmetric Michael Additions of Ketones to Nitroalkenes
Published in Journal of organic chemistry (05-06-2015)“…Homochiral methyl 4-aminopyrrolidine-2-carboxylates are readily obtained by means of asymmetric (3 + 2) cycloadditions between azomethine ylides and…”
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3
Pyridine‐Hydrazone Ligands in Asymmetric Palladium‐Catalyzed 1,4‐ and 1,6‐Additions of Arylboronic Acids to Cyclic (Di)enones
Published in Advanced synthesis & catalysis (11-01-2019)“…Catalysts generated by combinations of Pd(TFA)2 and enantiomerically pure pyridine‐hydrazone ligands have been applied to the 1,4‐addition of arylboronic acids…”
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4
Synthesis of Prolines by Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylides and Alkenes Catalyzed by Chiral Phosphoramidite-Silver(I) Complexes
Published in European Journal of Organic Chemistry (01-11-2009)“…The endo‐diastereo‐ and enantioselective 1,3‐dipolar cycloaddition of azomethine ylides and electrophilic alkenes is efficiently catalysed by chiral…”
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5
Asymmetric Remote Aldol Cyclization Reaction to Synthesize Trifluoromethylated Heterospirocyclic Frameworks
Published in Journal of organic chemistry (20-09-2024)“…The highly enantioselective organocatalytic synthesis of dihydropyran spirocyclic compounds bearing di- and trifluoromethyl groups by aldol cyclization…”
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6
Stereoselective Synthesis of Densely Substituted Pyrrolidines via a [3 + 2] Cycloaddition Reaction between Chiral N-tert-Butanesulfinylazadienes and Azomethine Ylides
Published in Organic letters (17-11-2023)“…The N-tert-butanesulfinylimine group behaves as a suitable electron-withdrawing group in 1-azadienes, allowing the diastereoselective synthesis of densely…”
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7
Synthesis of Bicyclic Hemiacetals Catalyzed by Unnatural Densely Substituted γ‑Dipeptides
Published in Journal of organic chemistry (04-11-2022)“…The asymmetric synthesis of bicyclic highly substituted tetrahydropyrans is described. The reaction is catalyzed by unnatural γ-dipeptides based on densely…”
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8
Remote Asymmetric Bisvinylogous [4+2] Cycloaddition Reaction to Synthesize Spirocyclic Frameworks
Published in Advanced synthesis & catalysis (13-10-2023)“…The highly enantioselective organocatalytic synthesis of spirocyclic compounds by Diels‐Alder reactions via trienamine using cyclic 2,5‐dienones as…”
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9
Phosphine Catalyzed Michael-Type Additions: The Synthesis of Glutamic Acid Derivatives from Arylidene- α -amino Esters
Published in Molecules (Basel, Switzerland) (01-01-2024)“…The reaction of arylidene-α-amino esters with electrophilic alkenes to yield Michael-type addition compounds is optimized using several phosphines as…”
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10
Asymmetric Organocatalytic Synthesis of Fluorinated β‐Hydroxy Diazenes
Published in European journal of organic chemistry (10-01-2019)“…The nucleophilic addition of formaldehyde tert‐butyl hydrazone to fluoromethyl ketones provides a valuable tool for the synthesis of highly functionalized…”
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11
Hydrazones as Singular Reagents in Asymmetric Organocatalysis
Published in Chemistry : a European journal (12-09-2016)“…This Minireview summarizes strategies and developments regarding the use of hydrazones as reagents in asymmetric organocatalysis, their distinct roles in…”
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12
Dual chiral silver catalyst in the synthetic approach to the core of hepatitis C virus inhibitor GSK 625433 using enantioselective 1,3-dipolar cycloaddition of azomethine ylides and electrophilic alkenes
Published in Tetrahedron: asymmetry (15-10-2017)“…[Display omitted] The asymmetric 1,3-dipolar cycloaddition of an imino ester 5 with tert-butyl acrylate is catalyzed by a dual chiral silver(I) complex formed…”
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13
A Three‐Component Enantioselective Cyclization Reaction Catalyzed by an Unnatural Amino Acid Derivative
Published in Angewandte Chemie International Edition (15-01-2018)“…A new diastereo‐ and enantioselective three‐component cyclization reaction is described. The reaction takes place between a ketone, a carboxylic acid, and a…”
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14
Bifunctional Squaramide Organocatalysts for the Asymmetric Addition of Formaldehyde tert‐Butylhydrazone to Simple Aldehydes
Published in Chemistry : a European journal (07-05-2018)“…The nucleophilic addition of formaldehyde tert‐butylhydrazone to simple aldehydes (a formal hetero‐carbonyl–ene reaction) can be performed with good reactivity…”
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15
Preparation of a ruthenium complex covalently bonded to multilayer graphene and its evaluation as a photocatalyst
Published in Nanoscale advances (12-03-2024)“…Multilayer graphene ( MLG ), obtained by mild sonication of graphite in NMP, was functionalised via 1,3-dipolar cycloaddition with azomethine ylides generated…”
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16
Biological properties and conformational studies of amphiphilic Pd(II) and Ni(II) complexes bearing functionalized aroylaminocarbo- N -thioylpyrrolinate units
Published in Beilstein journal of organic chemistry (02-12-2021)“…A series of novel palladium(II) and nickel(II) complexes of multifunctionalized aroylaminocarbo- -thioylpyrrolinates were synthesized and characterized by…”
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17
A Three‐Component Enantioselective Cyclization Reaction Catalyzed by an Unnatural Amino Acid Derivative
Published in Angewandte Chemie (15-01-2018)“…A new diastereo‐ and enantioselective three‐component cyclization reaction is described. The reaction takes place between a ketone, a carboxylic acid, and a…”
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18
Additive and Emergent Catalytic Properties of Dimeric Unnatural Amino Acid Derivatives: Aldol and Conjugate Additions
Published in Chemistry : a European journal (11-11-2021)“…Different densely substituted L‐ and D‐proline esters were prepared by asymmetric (3+2) cycloaddition reactions catalyzed by conveniently selected EhuPhos…”
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19
Widening the antimicrobial spectrum of esters of bicyclic amines: In vitro effect on gram-positive Streptococcus pneumoniae and gram-negative non-typeable Haemophilus influenzae biofilms
Published in Biochimica et biophysica acta. General subjects (01-01-2019)“…Antibiotic resistance is a global current threat of increasing importance. Moreover, biofilms represent a medical challenge since the inherent antibiotic…”
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20
Remote Substituent Effects on the Stereoselectivity and Organocatalytic Activity of Densely Substituted Unnatural Proline Esters in Aldol Reactions
Published in European journal of organic chemistry (01-04-2015)“…The organocatalytic activities of highly substituted proline esters obtained through asymmetric [3+2] cycloadditions of azomethine ylides derived from glycine…”
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