Search Results - "Renzi, Augusto De"
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Reactivity of cis-{PtII(Ar)(alkyne)} Fragments (Ar = aryl): A Domino-Formation of Indenes
Published in Organometallics (24-03-2008)“…The reactivity of cis-{PtII(Ar)(2-butyne)} fragments in cationic complexes is described. Coordination of the unsaturated ligand is observed at low temperature…”
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On factors influencing insertion of allylic substrates in Pd–Caryl bonds
Published in Inorganica Chimica Acta (01-04-2009)Get full text
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Synthesis, Structural Characterization, and Reactions of [PdPhCl(2,9-Me2-1,10-phenanthroline)] with Olefins
Published in Organometallics (01-11-1995)Get full text
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On factors influencing insertion of allylic substrates in Pd–C aryl bonds
Published in Inorganica Chimica Acta (20-04-2009)“…Arylation of allylic substrates has been performed in stoichiometric conditions by the use of neutral or cationic aryl/palladium species. The initially formed…”
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C–C coupling of aryl groups and allyl derivatives on Pt(II)-phenanthroline fragments: crystal and molecular structure of the tbp [(η 1,η 2-2-allyl,5-methyl-phenyl)iodo(1,10-phenanthroline)platinum(II)] complex containing the N–N ligand in axial-equatorial coordination mode
Published in Journal of organometallic chemistry (15-04-2005)“…Allyl compounds CH 2 CHCH 2Fn bearing electron-withdrawing functional (Fn) groups mainly react with cationic {Pt(aryl)(1,10-phenanthroline)} + fragments…”
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Five- vs. four-coordination in platinum(II)-olefin complexes with bidentate nitrogen ligands
Published in Inorganic chemistry (01-06-1985)Get full text
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Cis-(hydrido)hydrocarbylplatinum(IV) complexes as intermediates in the Pt IIC bond breaking
Published in Journal of organometallic chemistry (22-02-1995)“…Platinum(IV) complexes containing a cis-hydridohydrocarbyl arrangement have been obtained selectively on reaction of halotrimethylsilanes with…”
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Cationic platinum(II) - or palladium(II)-carbyl complexes and unsaturated substrates: a facile way to C-C bond formation
Published in Journal of organometallic chemistry (17-05-1995)“…Alkenes, alkynes, 1,2- and 1,3-dienes react with [MR(N-N)(MeCN)] + (M = Pt or Pd; R = hydrocarbyl group; NN = bidentate nitrogen ligand) to give R-substituted…”
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Pt(IV) derivatives formed by oxidative addition of organic halides to [Pt(CH 3) 2( N, N-chelate)] substrates: geometric isomers at equilibrium
Published in Journal of organometallic chemistry (15-01-2000)“…The geometrical isomerism at equilibrium of Pt(IV) derivatives of general formula [Pt(CH 3) 2(R)X(NN)] (NN=2,9-dimethyl-1,10-phenanthroline or…”
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Transition metals and carbohydrates: the methyl-4,6- O-benzylidene-2,3-diazo-2,3-dideoxy-α- d-mannopyranoside skeleton as building block for new chiral nitrogen chelates
Published in Carbohydrate research (22-03-2001)“…This paper describes a straightforward strategy for the synthesis of new nitrogen chelates by employing the chirality of readily available sugars. Thus,…”
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The cis-[lcub]PdII(Me)(alkene)[rcub] fragment: stabilization and reactivity
Published in Inorganica Chimica Acta (01-05-1997)Get full text
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The cis-[lcub]Pd II(Me)(alkene)[rcub] fragment: stabilization and reactivity
Published in Inorganica Chimica Acta (1997)“…The reaction of trimethyloxonium tetrafluoroborate, Me 3OBF 4, with [Pd(dmf)( N, N-chelate)] precursors ( N, N-mchelate=1,10-phenanthroline (phen) or 2,9-Me…”
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Cis-(hydrido)hydrocarbylplatinum(IV) complexes as intermediates in the PtIIC bond breaking
Published in Journal of organometallic chemistry (01-02-1995)Get full text
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Reaction products of CO with square-planar platinum(II)-( N, N-chelate) complexes: synthesis and reactivity
Published in Journal of organometallic chemistry (03-05-1996)“…Carbon monoxide adds to [PtCl(R)(N-N)] (R=hydrocarbyl group; N-N = chelating N, N-ligand) to afford neutral five-coordinate [PtCl(R)(CO)(N-N)] or cationic…”
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Carbon-carbon bond formation in cationic aryl-olefin-platinum(II) complexes
Published in Organometallics (01-11-1992)Get full text
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