Search Results - "Reilly, Sean D."

Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR2)2]3 Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, iPr, H) by Gaunt, Andrew J, Reilly, Sean D, Enriquez, Alejandro E, Scott, Brian L, Ibers, James A, Sekar, Perumal, Ingram, Kieran I. M, Kaltsoyannis, Nikolas, Neu, Mary P

“…Treatment of M[N(SiMe3)2]3 (M = U, Pu (An); La, Ce (Ln)) with NH(EPPh2)2 and NH(EPiPr2)2 (E = S, Se), afforded the neutral complexes M[N(EPR2)2]3 (R = Ph,…”
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Synthesis and Coordination Chemistry of Phosphine Oxide Decorated Dibenzofuran Platforms by Rosario-Amorin, Daniel, Duesler, Eileen N, Paine, Robert T, Hay, Benjamin P, Delmau, Lætitia H, Reilly, Sean D, Gaunt, Andrew J, Scott, Brian L

“…A four-step synthesis for 4,6-bis­(diphenylphosphinoylmethyl)­dibenzofuran (4) from dibenzofuran and a two-step synthesis for…”
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Complexation of Pu(IV) with the Natural Siderophore Desferrioxamine B and the Redox Properties of Pu(IV)(siderophore) Complexes by Boukhalfa, Hakim, Reilly, Sean D, Neu, Mary P

“…The bioavailability and mobility of Pu species can be profoundly affected by siderophores and other oxygen-rich organic ligands. Pu(IV)(siderophore) complexes…”
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Plutonium(IV) Reduction by the Metal-Reducing Bacteria Geobacter metallireducens GS15 and Shewanella oneidensis MR1 by Boukhalfa, Hakim, Icopini, Gary A, Reilly, Sean D, Neu, Mary P

“…The bacterial reduction of actinides has been suggested as a possible remedial strategy for actinide-contaminated environments, and the bacterial reduction of…”
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Solubility of plutonium(VI) carbonate in saline solutions by Reilly, Sean D., Runde, Wolfgang, Neu, Mary P.

“…Among the plutonium oxidation states found to form in the environment, mobile plutonium(VI) can exist under oxidizing conditions and in waters with high…”
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Trace Actinide Signatures of a Bulk Neptunium Sample by Reilly, Sean D., Patton, Genna M., Murillo, Jesse, Oldham, Warren J., Miller, Jeffrey L., LaMont, Stephen P., Sanborn, Matthew E., May, Iain, Gaunt, Andrew J., Hanson, Susan K.

“…In nuclear forensic analyses, measurements of actinide elements in a sample can assist with identifying interdicted or unknown materials. While these…”
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Complexation of High-Valency Mid-Actinides by a Lipophilic Schiff Base Ligand: Synthesis, Structural Characterization, and Progress toward Selective Extraction by Bustillos, Christian G, Hawkins, Cory A, Copping, Roy, Reilly, Sean D, Scott, Brian L, May, Iain, Nilsson, Mikael

“…Separation of U, Np, and Pu from used nuclear fuel (UNF) would result in lower long-term radiotoxicity, alleviating constraints on the storage and handling of…”
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Plutonium(IV) complexation by diglycolamide ligands--coordination chemistry insight into TODGA-based actinide separations by Reilly, Sean D, Gaunt, Andrew J, Scott, Brian L, Modolo, Giuseppe, Iqbal, Mudassir, Verboom, Willem, Sarsfield, Mark J

“…Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that…”
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Experimental and theoretical comparison of actinide and lanthanide bonding in M[N(EPR(2))(2)](3) complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, iPr, H) by Gaunt, Andrew J, Reilly, Sean D, Enriquez, Alejandro E, Scott, Brian L, Ibers, James A, Sekar, Perumal, Ingram, Kieran I M, Kaltsoyannis, Nikolas, Neu, Mary P

“…Treatment of M[N(SiMe3)2]3 (M = U, Pu (An); La, Ce (Ln)) with NH(EPPh2)2 and NH(EPiPr2)2 (E = S, Se), afforded the neutral complexes M[N(EPR2)2]3 (R = Ph,…”
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Determination of plutonium in spent nuclear fuel using high resolution X-ray by McIntosh, Kathryn G., Reilly, Sean D., Havrilla, George J.

“…Characterization of Pu is an essential aspect of safeguards operations at nuclear fuel reprocessing facilities. A novel analysis technique called hiRX (high…”
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Structural and Spectroscopic Characterization of Plutonyl(VI) Nitrate under Acidic Conditions by Gaunt, Andrew J, May, Iain, Neu, Mary P, Reilly, Sean D, Scott, Brian L

“…The plutonyl(VI) dinitrate complex [PuO2(NO3)2(H2O)2]·H2O (1) has been structurally characterized by single-crystal X-ray diffraction and spectroscopically…”
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Dissolution of Plutonium(IV) Hydroxide by Desferrioxamine Siderophores and Simple Organic Chelators by Ruggiero, Christy E, Matonic, John H, Reilly, Sean D, Neu, Mary P

“…Plutonium is thought to exist mostly as low soluble plutonium(IV) species in the environment and, therefore, has low potential of becoming mobile. Due to their…”
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Unexpected Actinyl Cation-Directed Structural Variation in Neptunyl(VI) A‑Type Tri-lacunary Heteropolyoxotungstate Complexes by Berg, John M, Gaunt, Andrew J, May, Iain, Pugmire, Alison L, Reilly, Sean D, Scott, Brian L, Wilkerson, Marianne P

“…A-type tri-lacunary heteropolyoxotungstate anions (e.g., [PW9O34]9–, [AsW9O34]9–, [SiW9O34]10–, and [GeW9O34]10–) are multidentate oxygen donor ligands that…”
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A Linear trans-Bis(imido) Neptunium(V) Actinyl Analog: NpV(NDipp)2( t Bu2bipy)2Cl (Dipp = 2,6‑ i Pr2C6H3) by Brown, Jessie L, Batista, Enrique R, Boncella, James M, Gaunt, Andrew J, Reilly, Sean D, Scott, Brian L, Tomson, Neil C

“…The discovery that imido analogs of actinyl dioxo cations can be extended beyond uranium into the transuranic elements is presented. Synthesis of the Np­(V)…”
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Pu(VI) Hydrolysis:  Further Evidence for a Dimeric Plutonyl Hydroxide and Contrasts with U(VI) Chemistry by Reilly, Sean D, Neu, Mary P

“…A significant fraction of plutonium that is soluble in environmental waters and other aqueous solutions can be present as complexes of plutonyl, PuO2 2+. Few…”
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Iron(III) Coordination Properties of a Pyoverdin Siderophore Produced by Pseudomonas putida ATCC 33015 by Boukhalfa, Hakim, Reilly, Sean D, Michalczyk, Ryszard, Iyer, Srinivas, Neu, Mary P

“…The iron complexation of a fluorescent green pyoverdin siderophore produced by the environmental bacterium Pseudomonas putida was characterized by solution…”
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Structural characterization of Pu[N(SiMe(3))(2)](3), a synthetically useful nonaqueous plutonium(III) precursor by Gaunt, Andrew J, Enriquez, Alejandro E, Reilly, Sean D, Scott, Brian L, Neu, Mary P

“…A rare, and synthetically versatile, nonaqueous plutonium complex, Pu[N(SiMe3)2]3 (1), has been structurally characterized by single-crystal X-ray diffraction…”
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The Reaction Chemistry of Plutonyl(VI) Chloride Complexes with Triphenyl Phosphineoxide and Triphenyl Phosphinimine by Berthon, Claude, Boubals, Nathalie, Charushnikova, Iraida A, Collison, David, Cornet, Stéphanie M, Den Auwer, Christophe, Gaunt, Andrew J, Kaltsoyannis, Nikolas, May, Iain, Petit, Sebastien, Redmond, Michael P, Reilly, Sean D, Scott, Brian L

“…The reaction between Ph3PO dissolved in acetone and “PuO2Cl2” in dilute HCl resulted in the formation of [PuO2Cl2(Ph3PO)2]. Crystallographic characterization…”
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Low-Valent Molecular Plutonium Halide Complexes by Gaunt, Andrew J, Reilly, Sean D, Enriquez, Alejandro E, Hayton, Trevor W, Boncella, James M, Scott, Brian L, Neu, Mary P

“…Treatment of plutonium metal with 1.5 equiv of bromine in tetrahydrofuran (thf) led to isolation of PuBr3(thf)4 (1), which is a new versatile synthon for…”
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[N(n‑Bu)4]2[Pu(NO3)6] and [N(n‑Bu)4]2[PuCl6]: Starting Materials To Facilitate Nonaqueous Plutonium(IV) Chemistry by Reilly, Sean D, Scott, Brian L, Gaunt, Andrew J

“…The reaction of plutonium(IV) in aqueous nitric acid with tetra-n-butylammonium nitrate leads to the immediate precipitation of [N(n-Bu)4]2[Pu(NO3)6] (1) in…”
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