Search Results - "Reek, Joost N. H."

Transition metal catalysis in confined spaces by Leenders, Stefan H A M, Gramage-Doria, Rafael, de Bruin, Bas, Reek, Joost N H

“…Transition metal catalysis plays an important role in both industry and in academia where selectivity, activity and stability are crucial parameters to…”
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Supramolecular strategies in artificial photosynthesis by Keijer, Tom, Bouwens, Tessel, Hessels, Joeri, Reek, Joost N. H

“…Artificial photosynthesis is a major scientific endeavor aimed at converting solar power into a chemical fuel as a viable approach to sustainable energy…”
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Ligand Template Strategies for Catalyst Encapsulation by Jongkind, Lukas J, Caumes, Xavier, Hartendorp, Arnout P. T, Reek, Joost N. H

“…Conspectus Binding of molecules in molecular cages based on self-assembled concave building blocks has been of great interest to scientists for decades. The…”
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Enantioselective Hydroformylation by a Rh-Catalyst Entrapped in a Supramolecular Metallocage by García-Simón, Cristina, Gramage-Doria, Rafael, Raoufmoghaddam, Saeed, Parella, Teodor, Costas, Miquel, Ribas, Xavi, Reek, Joost N. H

“…Regio- and enantioselective hydroformylation of styrenes is attained upon embedding a chiral Rh complex in a nonchiral supramolecular cage formed from…”
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Just Add Water: Modulating the Structure-Derived Acidity of Catalytic Hexameric Resorcinarene Capsules by Poole, David A, Mathew, Simon, Reek, Joost N. H

“…The hexameric undecyl-resorcin[4]­arene capsule ( C11 R 6 ) features eight discrete structural water molecules located at the vertices of its cubic…”
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Supramolecular control of selectivity in transition-metal catalysis through substrate preorganization by Dydio, Pawe, Reek, Joost N. H

“…Supramolecular chemistry exploits multiple weak intermolecular interactions to assemble nano-sized molecular architectures, providing new possibilities for…”
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Reactivity within a confined self-assembled nanospace by Koblenz, Tehila S, Wassenaar, Jeroen, Reek, Joost N H

“…Confined nanospaces in which reactions can take place, have been created by various approaches such as molecular capsules, zeolites and micelles. In this…”
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Supramolecular Control on Chemo- and Regioselectivity via Encapsulation of (NHC)-Au Catalyst within a Hexameric Self-Assembled Host by Cavarzan, Alessandra, Scarso, Alessandro, Sgarbossa, Paolo, Strukul, Giorgio, Reek, Joost N. H

“…The encapsulation of a Au(I) catalyst within a self-assembled, hydrogen bonded, hexameric capsule dramatically changes its catalytic activity, leading to…”
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How to Control the Rate of Heterogeneous Electron Transfer across the Rim of M6L12 and M12L24 Nanospheres by Zaffaroni, Riccardo, Bobylev, Eduard O, Plessius, Raoul, van der Vlugt, Jarl Ivar, Reek, Joost N. H

“…Catalysis in confined spaces, such as those provided by supramolecular cages, is quickly gaining momentum. It allows for second coordination sphere strategies…”
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Mononuclear Water Oxidation Catalysts by Hetterscheid, Dennis G. H., Reek, Joost N. H.

“…Recently, several mononuclear water oxidation catalysts have been reported, a breakthrough considering the dogma that at least two metal sites were required to…”
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Precise Supramolecular Control of Selectivity in the Rh-Catalyzed Hydroformylation of Terminal and Internal Alkenes by Dydio, Paweł, Detz, Remko J, Reek, Joost N. H

“…In this study, we report a series of DIMPhos ligands L1–L3, bidentate phosphorus ligands equipped with an integral anion binding site (the DIM pocket)…”
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Self-Assembly of a Confined Rhodium Catalyst for Asymmetric Hydroformylation of Unfunctionalized Internal Alkenes by Gadzikwa, Tendai, Bellini, Rosalba, Dekker, Henk L, Reek, Joost N. H

“…A chiral supramolecular ligand has been assembled and applied to the rhodium-catalyzed asymmetric hydroformylation of unfunctionalized internal alkenes…”
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Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers by Khoenkhoen, Nitesh, de Bruin, Bas, Reek, Joost N. H., Dzik, Wojciech I.

“…This review presents a comprehensive overview of the reactions of N2 within the coordination sphere of transition metals of groups 6 to 9. Many of these metals…”
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Ruthenium PNN(O) Complexes: Cooperative Reactivity and Application as Catalysts for Acceptorless Dehydrogenative Coupling Reactions by de Boer, Sandra Y, Korstanje, Ties J, La Rooij, Stefan R, Kox, Rogier, Reek, Joost N. H, van der Vlugt, Jarl Ivar

“…The novel tridentate PNNOH pincer ligand L H features a reactive 2-hydroxypyridine functionality as well as a bipyridyl-methylphosphine skeleton for meridional…”
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Base-Free Production of H2 by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex by Oldenhof, Sander, de Bruin, Bas, Lutz, Martin, Siegler, Maxime A., Patureau, Frederic W., van der Vlugt, Jarl Ivar, Reek, Joost N. H.

“…Erase the base: An iridium complex based on a cooperative ligand that functions as an internal base is reported. This complex can rapidly and cleanly…”
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Encapsulated Cobalt-Porphyrin as a Catalyst for Size-Selective Radical-type Cyclopropanation Reactions by Otte, Matthias, Kuijpers, Petrus F., Troeppner, Oliver, Ivanović-Burmazović, Ivana, Reek, Joost N. H., de Bruin, Bas

“…A cobalt–porphyrin catalyst encapsulated in a cubic M8L6 cage allows cyclopropanation reactions in aqueous media. The caged‐catalyst shows enhanced activities…”
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A Switchable Gold Catalyst by Encapsulation in a Self-Assembled Cage by Jans, Anne C. H., Gómez-Suárez, Adrián, Nolan, Steven P., Reek, Joost N. H.

“…Dinuclear gold complexes have the ability to interact with one or more substrates in a dual‐activation mode, leading to different reactivity and selectivity…”
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Gold(I) Catalysis at Extreme Concentrations Inside Self-Assembled Nanospheres by Gramage-Doria, Rafael, Hessels, Joeri, Leenders, Stefan H. A. M., Tröppner, Oliver, Dürr, Maximilian, Ivanović-Burmazović, Ivana, Reek, Joost N. H.

“…Homogeneous transition‐metal catalysis is a crucial technology for the sustainable preparation of valuable chemicals. The catalyst concentration is usually…”
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Direct Probing of Photoinduced Electron Transfer in a Self-Assembled Biomimetic [2Fe2S]-Hydrogenase Complex Using Ultrafast Vibrational Spectroscopy by Li, Ping, Amirjalayer, Saeed, Hartl, František, Lutz, Martin, Bruin, Bas de, Becker, René, Woutersen, Sander, Reek, Joost N. H

“…A pyridyl-functionalized diiron dithiolate complex, [μ-(4-pyCH2–NMI-S2)­Fe2(CO)6] (3, py = pyridine (ligand), NMI = naphthalene monoimide) was synthesized and…”
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Redox-Active Ligand-Induced Homolytic Bond Activation by Broere, Daniël L. J., Metz, Lotte L., de Bruin, Bas, Reek, Joost N. H., Siegler, Maxime A., van der Vlugt, Jarl Ivar

“…Coordination of the novel redox‐active phosphine‐appended aminophenol pincer ligand (PNOH2) to PdII generates a paramagnetic complex with a persistent…”
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