Search Results - "Reed, Douglas A"
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High-performance organic pseudocapacitors via molecular contortion
Published in Nature materials (01-08-2021)“…Pseudocapacitors harness unique charge-storage mechanisms to enable high-capacity, rapidly cycling devices. Here we describe an organic system composed of…”
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M2(m‑dobdc) (M = Mn, Fe, Co, Ni) Metal–Organic Frameworks as Highly Selective, High-Capacity Adsorbents for Olefin/Paraffin Separations
Published in Journal of the American Chemical Society (01-11-2017)“…The metal–organic frameworks M2(m-dobdc) (M = Mn, Fe, Co, Ni; m-dobdc4– = 4,6-dioxido-1,3-benzenedicarboxylate) were evaluated as adsorbents for separating…”
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3
A spin transition mechanism for cooperative adsorption in metal–organic frameworks
Published in Nature (London) (05-10-2017)“…Metal–organic frameworks that undergo a cooperative spin transition at neighbouring metal centres upon coordination to CO exhibit large CO separation…”
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4
Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal–Organic Frameworks
Published in Journal of the American Chemical Society (07-03-2018)“…Purification of the C8 alkylaromatics o-xylene, m-xylene, p-xylene, and ethylbenzene remains among the most challenging industrial separations, due to the…”
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5
Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework
Published in Nature communications (18-06-2020)“…The design of stable adsorbents capable of selectively capturing dioxygen with a high reversible capacity is a crucial goal in functional materials…”
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6
Biomimetic O2 adsorption in an iron metal–organic framework for air separation
Published in Chemical science (Cambridge) (10-01-2020)“…Bio-inspired motifs for gas binding and small molecule activation can be used to design more selective adsorbents for gas separation applications. Here, we…”
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7
Cooperative adsorption of carbon disulfide in diamine-appended metal–organic frameworks
Published in Nature communications (03-12-2018)“…Over one million tons of CS 2 are produced annually, and emissions of this volatile and toxic liquid, known to generate acid rain, remain poorly controlled. As…”
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8
Leveraging ordered voids in microporous perovskites for intercalation and post-synthetic modification
Published in Chemical science (Cambridge) (16-10-2024)“…We report the use of porous organic layers in two-dimensional hybrid organic-inorganic perovskites (HOIPs) to facilitate permanent small molecule intercalation…”
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9
Selective nitrogen adsorption via backbonding in a metal–organic framework with exposed vanadium sites
Published in Nature materials (01-05-2020)“…Industrial processes prominently feature π-acidic gases, and an adsorbent capable of selectively interacting with these molecules could enable important…”
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10
Olsalazine-Based Metal–Organic Frameworks as Biocompatible Platforms for H2 Adsorption and Drug Delivery
Published in Journal of the American Chemical Society (17-08-2016)“…The drug olsalazine (H4olz) was employed as a ligand to synthesize a new series of mesoporous metal–organic frameworks that are expanded analogues of the…”
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11
Barriers to Bariatric Surgery: a Mixed Methods Study Investigating Obstacles Between Clinic Contact and Surgery
Published in Obesity surgery (01-09-2023)“…Purpose Populations most affected by obesity are not reflected in the patients who undergo bariatric surgery. Gaps in the referral system have been studied,…”
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12
Negative cooperativity upon hydrogen bond-stabilized O 2 adsorption in a redox-active metal-organic framework
Published in Nature communications (18-06-2020)“…The design of stable adsorbents capable of selectively capturing dioxygen with a high reversible capacity is a crucial goal in functional materials…”
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13
Single-Electron Currents in Designer Single-Cluster Devices
Published in Journal of the American Chemical Society (02-09-2020)“…Atomically precise clusters can be used to create single-electron devices wherein a single redox-active cluster is connected to two macroscopic electrodes via…”
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14
Design of a Metal–Organic Framework with Enhanced Back Bonding for Separation of N2 and CH4
Published in Journal of the American Chemical Society (15-01-2014)“…Gas separations with porous materials are economically important and provide a unique challenge to fundamental materials design, as adsorbent properties can be…”
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15
Site-Selective Surface Modification of 2D Superatomic Re6Se8
Published in Journal of the American Chemical Society (12-01-2022)“…Coating two-dimensional (2D) materials with molecules bearing tunable properties imparts their surfaces with functionalities for applications in sensing,…”
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16
Controlling Ligand Coordination Spheres and Cluster Fusion in Superatoms
Published in Journal of the American Chemical Society (12-01-2022)“…We show that reaction pathways from a single superatom motif can be controlled through subtle electronic modification of the outer ligand spheres. Chevrel-type…”
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17
Hierarchical Coherent Phonons in a Superatomic Semiconductor
Published in Advanced materials (Weinheim) (01-09-2019)“…The coupling of phonons to electrons and other phonons plays a defining role in material properties, such as charge and energy transport, light emission, and…”
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18
Site-Selective Surface Modification of 2D Superatomic Re 6 Se 8
Published in Journal of the American Chemical Society (12-01-2022)“…Coating two-dimensional (2D) materials with molecules bearing tunable properties imparts their surfaces with functionalities for applications in sensing,…”
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19
Reversible CO Scavenging via Adsorbate-Dependent Spin State Transitions in an Iron(II)–Triazolate Metal–Organic Framework
Published in Journal of the American Chemical Society (04-05-2016)“…A new metal–organic framework, Fe-BTTri (Fe3[(Fe4Cl)3(BTTri)8]2·18CH3OH, H3BTTri =1,3,5-tris(1H-1,2,3-triazol-5-yl)benzene)), is found to be highly selective…”
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20
M 2 (m-dobdc) (M = Mn, Fe, Co, Ni) Metal-Organic Frameworks as Highly Selective, High-Capacity Adsorbents for Olefin/Paraffin Separations
Published in Journal of the American Chemical Society (01-11-2017)“…The metal-organic frameworks M (m-dobdc) (M = Mn, Fe, Co, Ni; m-dobdc = 4,6-dioxido-1,3-benzenedicarboxylate) were evaluated as adsorbents for separating…”
Get full text
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