Search Results - "Reddy, Alla Siva"
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Ethanol as a Hydrogenating Agent: Palladium‐Catalyzed Stereoselective Hydrogenation of Ynamides To Give Enamides
Published in Angewandte Chemie International Edition (06-06-2017)“…Ethanol is shown to act as a hydrogenating agent for ynamides under palladium catalysis. This behavior is different from the normally expected reaction of…”
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2
Palladium-Catalyzed Tandem-Cyclization of Functionalized Ynamides: An Approach to Benzosultams
Published in Advanced synthesis & catalysis (19-05-2016)“…A palladium‐catalyzed tandem‐cyclization of functionalized ynamides to afford a wide range of hetero‐substituted benzosultams (1,2‐benzothiazine 1,1‐dioxides)…”
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3
Palladium-catalyzed regioselective synthesis of benzosultams from functionalized ynamides and benzotriazoles/tetrazoles
Published in Tetrahedron (11-05-2017)“…Palladium-catalyzed highly regioselective synthesis of benzotriazole appended benzosultams by the tandem-cyclization of functionalized ynamides with…”
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4
Reactivity of ynamides with AlCl3 and ICl: Ready access to (E)-α-chloroenamides and (E/Z)-α-chloro-β-iodo-enamides
Published in Journal of chemical sciences (Bangalore, India) (2021)“…AlCl 3 acts as a chlorinating agent for ynamides in the presence of stoichiometric amount of water in the environmentally benign solvent dimethylcarbonate,…”
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5
Advances in chemoselective and/or stereoselective semihydrogenation of alkynes
Published in Tetrahedron letters (31-01-2018)“…[Display omitted] •Catalytic semihydrogenation of alkynes is a direct and simple route to alkenes.•Both chemoselectivity and stereoselectivity are critical to…”
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Divergent Reactivity of Phosphorylated and Related Allenes: [4 + 2] Cycloaddition with 3,6-Diphenyltetrazine, Self-Addition Leading to Dimers and [Pd]-Complex Formation
Published in Journal of organic chemistry (04-11-2022)“…Phosphorus-based naphthalenes are formed by self-dimerization-cum-cyclization of α-aryl allenylphosphonates or allenylphosphine oxides using catalytic…”
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7
Use of Elemental Sulfur or Selenium in a Novel One-Pot Copper-Catalyzed Tandem Cyclization of Functionalized Ynamides Leading to Benzosultams
Published in Organic letters (19-06-2015)“…A novel and efficient [Cu]-catalyzed one-pot regio- and stereospecific synthesis of benzo[1,4,2]dithiazine 1,1-dioxides and benzo[1,4,2]thiaselenazine…”
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8
Computer-aided drug design to generate a unique antibiotic family
Published in Nature communications (27-09-2024)“…The World Health Organization has identified antibiotic resistance as one of the three greatest threats to human health. The need for antibiotics is a pressing…”
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9
Transition Metal-Free Cascade Cyclization of Epoxy-Ynamides: To Go for 1,3-Oxazines or 1,4-Oxazines?
Published in Organic letters (04-11-2016)“…An approach to both 1,3- and 1,4-oxazines is developed by the cascade cyclization of epoxy ynamides under transition metal-free conditions. Thus, while…”
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10
New reactions of allenes, alkynes, ynamides, enynones and isothiocyanates
Published in Journal of chemical sciences (Bangalore, India) (01-07-2018)“…This perspective article is related to transformations (both catalytic and non-catalytic) involving allenes, alkynes/enynones/ynamides and isothiocyanates…”
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11
Reactions of alkynes- copper-catalyzed cyclization of functionalized alkynes with elemental sulfur/selenium to form oxathiines/oxaselenines
Published in Journal of organometallic chemistry (01-07-2019)“…In this article, a part of the work related to the reactivity of alkynes from our group will be highlighted. These include (i) [Pd]-catalyzed double arylation…”
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12
Ethanol as a Hydrogenating Agent: Palladium‐Catalyzed Stereoselective Hydrogenation of Ynamides To Give Enamides
Published in Angewandte Chemie (06-06-2017)“…Ethanol is shown to act as a hydrogenating agent for ynamides under palladium catalysis. This behavior is different from the normally expected reaction of…”
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