Search Results - "Real, José A"

Thermo-, piezo-, photo- and chemo-switchable spin crossover iron(II)-metallocyanate based coordination polymers by Muñoz, M. Carmen, Real, José A.

“…Iron(II) metallocyanate-based coordination polymers feature structural diversity, supramolecular isomerism, interpenetrating frameworks, structure flexibility,…”
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Bidirectional Chemo-Switching of Spin State in a Microporous Framework by Ohba, Masaaki, Yoneda, Ko, Agustí, Gloria, Muñoz, M. Carmen, Gaspar, Ana B, Real, José A, Yamasaki, Mikio, Ando, Hideo, Nakao, Yoshihide, Sakaki, Shigeyoshi, Kitagawa, Susumu

“…The ins and outs of spin: Using the microporous coordination polymer {Fe(pz)[Pt(CN)₄]} (1, pz=pyrazine), incorporating spin-crossover subunits, two-directional…”
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Precise Control and Consecutive Modulation of Spin Transition Temperature Using Chemical Migration in Porous Coordination Polymers by Ohtani, Ryo, Yoneda, Ko, Furukawa, Shuhei, Horike, Nao, Kitagawa, Susumu, Gaspar, Ana B, Muñoz, M. Carmen, Real, José A, Ohba, Masaaki

“…Precise control of spin transition temperature (T c) is one of the most important challenges in molecular magnetism. A Hofmann-type porous coordination polymer…”
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Discrimination between two memory channels by molecular alloying in a doubly bistable spin crossover material by Valverde-Muñoz, Francisco Javier, Seredyuk, Maksym, Meneses-Sánchez, Manuel, Muñoz, M Carmen, Bartual-Murgui, Carlos, Real, José A

“…A multistable spin crossover (SCO) molecular alloy system [Fe M ( Bu-im) (tren)](P As F ) (M = Zn , Ni ; ( Bu-im) (tren) = tris(…”
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A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound by Rodríguez-Velamazán, J. Alberto, González, Miguel A, Real, José A, Castro, Miguel, Muñoz, M. Carmen, Gaspar, Ana B, Ohtani, Ryo, Ohba, Masaaki, Yoneda, Ko, Hijikata, Yuh, Yanai, Nobuhiro, Mizuno, Motohiro, Ando, Hideo, Kitagawa, Susumu

“…A quasielastic neutron scattering and solid-state 2H NMR spectroscopy study of the polymeric spin-crossover compound {Fe(pyrazine)[Pt(CN)4]} shows that the…”
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Competing Phases Involving Spin-State and Ligand Structural Orderings in a Multistable Two-Dimensional Spin Crossover Coordination Polymer by Zhang, Daopeng, Trzop, Elzbieta, Valverde-Muñoz, Francisco J, Piñeiro-López, Lucía, Muñoz, M. Carmen, Collet, Eric, Real, José A

“…Competition between spin-crossover and structural ligand ordering is identified as responsible for multistability and generation of six different phases in a…”
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Spin-Crossover Nanocrystals with Magnetic, Optical, and Structural Bistability Near Room Temperature by Boldog, Ishtvan, Gaspar, Ana B, Martínez, Víctor, Pardo-Ibañez, Pablo, Ksenofontov, Vadim, Bhattacharjee, Ashis, Gütlich, Philipp, Real, José A

“…Nanocrystals of the three‐dimensional, spin‐crossover, porous coordination framework [Fe(pz)Pt(CN)4]⋅n H2O (pz=pyrazine; n≤2.5) have been synthesized from…”
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Reversible Chemisorption of Sulfur Dioxide in a Spin Crossover Porous Coordination Polymer by Arcís-Castillo, Zulema, Muñoz-Lara, Francisco J., Muñoz, M. Carmen, Aravena, Daniel, Gaspar, Ana B., Sánchez-Royo, Juan F., Ruiz, Eliseo, Ohba, Masaaki, Matsuda, Ryotaro, Kitagawa, Susumu, Real, José A.

“…The chemisorption of sulfur dioxide (SO2) on the Hofmann-like spin crossover porous coordination polymer (SCO-PCP) {Fe(pz)[Pt(CN)4]} has been investigated at…”
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Exploiting Pressure To Induce a “Guest-Blocked” Spin Transition in a Framework Material by Sciortino, Natasha F., Ragon, Florence, Zenere, Katrina A., Southon, Peter D., Halder, Gregory J., Chapman, Karena W., Piñeiro-López, Lucía, Real, José A., Kepert, Cameron J., Neville, Suzanne M.

“…A new functionalized 1,2,4-triazole ligand, 4-[(E)-2-(5-methyl-2-thienyl)­vinyl]-1,2,4-triazole (thiome), was prepared to assess the broad applicability of…”
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Single‐Crystal X‐Ray Diffraction Study of Pressure and Temperature‐Induced Spin Trapping in a Bistable Iron(II) Hofmann Framework by Turner, Gemma F., Campbell, Fallyn, Moggach, Stephen A., Parsons, Simon, Goeta, Andrés E., Muñoz, M. Carmen, Real, José A.

“…High‐pressure single‐crystal X‐ray diffraction has been used to trap both the low‐spin (LS) and high‐spin (HS) states of the iron(II) Hofmann spin crossover…”
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Synthesis of Nanocrystals and Particle Size Effects Studies on the Thermally Induced Spin Transition of the Model Spin Crossover Compound [Fe(phen)2(NCS)2] by Valverde-Muñoz, Francisco Javier, Gaspar, Ana B, Shylin, Sergii I, Ksenofontov, Vadim, Real, José A

“…Surfactant-free nanocrystals of the model spin-crossover compound [Fe­(phen)2(NCS)2] (phen: 1,10-phenanthroline) have been synthesized applying the reverse…”
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Effect of Guest Molecules on Spin Transition Temperature in Loaded Hofmann‐Like Clathrates with Improved Porosity by Piñeiro‐López, Lucía, Seredyuk, Maksym, Muñoz, M. Carmen, Real, José A.

“…The synthesis, crystal structure, magnetic and calorimetric studies of a new clathrate compound of the Hofmann‐type spin crossover (SCO) metal‐organic…”
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Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal-Organic Frameworks by Romero-Morcillo, Tania, De la Pinta, Noelia, Callejo, Lorena M., Piñeiro-López, Lucía, Muñoz, M. Carmen, Madariaga, Gotzon, Ferrer, Sacramento, Breczewski, Tomasz, Cortés, Roberto, Real, José A.

“…[Fe(tvp)2(NCS)2] (1) (tvp=trans‐(4,4′‐vinylenedipyridine)) consists of two independent perpendicular stacks of mutually interpenetrated two‐dimensional grids…”
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Communication between iron(II) building blocks in cooperative spin transition phenomena by Real, José A, Gaspar, Ana B, Niel, Virginie, Muñoz, M.Carmen

“…In the present article we discuss the cooperative nature of the spin crossover phenomenon in iron(II) complexes, providing a perspective of the state of the…”
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Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex by Piñeiro-López, Lucía, Ortega-Villar, Norma, Muñoz, M. Carmen, Molnár, Gábor, Cirera, Jordi, Moreno-Esparza, Rafael, Ugalde-Saldívar, Víctor M., Bousseksou, Azzedine, Ruiz, Eliseo, Real, José A.

“…The highly stable nitrosyl iron(II) mononuclear complex [Fe(bztpen)(NO)](PF6)2 (bztpen=N‐benzyl‐N,N′,N′‐tris(2‐pyridylmethyl)ethylenediamine) displays an…”
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The Effect of Pressure on the Cooperative Spin Transition in the 2D Coordination Polymer {Fe(phpy)2[Ni(CN)4]} by Gaspar, Ana B., Levchenko, Georgiy, Terekhov, Sergey, Bukin, Gennadiy, Valverde-Muñoz, Javier, Muñoz-Lara, Francisco J., Seredyuk, Maksym, Real, José A.

“…The effect of pressure on the spin‐transition properties of the 2D coordination polymer {Fe(phpy)2[Ni(CN)4]} is reported. The study has been carried out by…”
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Electrical Conductivity and Spin Crossover:  A New Achievement with a Metal Bis Dithiolene Complex by Faulmann, Christophe, Jacob, Kane, Dorbes, Stéphane, Lampert, Stéphane, Malfant, Isabelle, Doublet, Marie-Liesse, Valade, Lydie, Real, José A

“…Three new compounds based on the cationic complex [FeIII(3-R-salEen)2]+ (salEen stands for N-(2-ethylamino)ethyl)-salicylaldimine, R = H, CH3O) with the…”
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Switchable Spin-Crossover Hofmann-Type 3D Coordination Polymers Based on Tri- and Tetratopic Ligands by Valverde-Muñoz, Francisco Javier, Muñoz, M. Carmen, Ferrer, Sacramento, Bartual-Murgui, Carlos, Real, José A

“…FeII spin-crossover (SCO) coordination polymers of the Hofmann type have become an archetypal class of responsive materials. Almost invariably, the…”
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Thermal-, Pressure- and Light-Induced Spin-Crossover Behaviour in the Two-Dimensional Hofmann-Like Coordination Polymer [Fe(3-Clpy)2Pd(CN)4] by Martínez, Víctor, Arcís Castillo, Zulema, Muñoz, M. Carmen, Gaspar, Ana B., Etrillard, C., Létard, Jean-François, Terekhov, Sergey A., Bukin, Gennadiy V., Levchenko, Georgiy, Real, José A.

“…The thermal spin‐crossover behaviour, photoexcitation and subsequent relaxation, as well as the pressure‐induced spin‐crossover behaviour at 298 K are…”
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Spin-Crossover Behavior in Cyanide-Bridged Iron(II)−Copper(I) Bimetallic 1−3D Metal−Organic Frameworks by Agustí, Gloria, Muñoz, M. Carmen, Gaspar, Ana B, Real, José A

“…The synthesis and characterization of a series of 1−3D cyanide-bridged iron(II)−copper(I) bimetallic coordination polymers formulated as {Fe(3-Xpy)2[Cu(3-Xpy)…”
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