Search Results - "Raus, Vladimír"
-
1
Cu(0)-RDRP of 2-hydroxyethyl methacrylate in a non-polar solvent enables rapid synthesis of high-molecular weight homopolymers and direct access to amphiphilic copolymers
Published in Reactive & functional polymers (01-02-2023)“…2-Hydroxyethyl methacrylate (HEMA) is an important functional monomer affording (co)polymers with numerous applications in different fields. Nevertheless, we…”
Get full text
Journal Article -
2
Well-Defined Linear and Grafted Poly(2-isopropenyl-2-oxazoline)s Prepared via Copper-Mediated Reversible-Deactivation Radical Polymerization Methods
Published in Macromolecules (24-03-2020)“…2-Isopropenyl-2-oxazoline (IPOx) is an important double functional monomer with multiple potential applications. However, until now, the attempts at…”
Get full text
Journal Article -
3
Intermolecular Interactions in N,N -Dimethylacetamide without and with LiCl Studied by Infrared Spectroscopy and Quantum Chemical Model Calculations
Published in The journal of physical chemistry. B (27-09-2018)“…The mixture of LiCl and N , N -dimethylacetamide (DMAc) is an important laboratory-scale solvent for cellulose. However, the mechanism of cellulose dissolution…”
Get full text
Journal Article -
4
ATRP of POSS Monomers Revisited: Toward High-Molecular Weight Methacrylate–POSS (Co)Polymers
Published in Macromolecules (11-11-2014)“…For the first time, ATRP was successfully employed for homopolymerization of a commercial methacrylate-functionalized polyhedral oligomeric silsesquioxane…”
Get full text
Journal Article -
5
Straightforward synthesis of complex polymeric architectures with ultra-high chain density
Published in Chemical science (Cambridge) (14-08-2024)“…Synthesis of complex polymeric architectures (CPAs) reversible-deactivation radical polymerization (RDRP) currently relies on the rather inefficient attachment…”
Get full text
Journal Article -
6
Structural Transitions of 1‑Butyl-3-methylimidazolium Chloride/Water Mixtures Studied by Raman and FTIR Spectroscopy and WAXS
Published in Crystal growth & design (06-04-2016)“…Ionic liquid 1-butyl-3-methylimidazolium chloride (bmimCl) and its water mixtures were subjected to the temperature of −25 °C for various periods of time and…”
Get full text
Journal Article -
7
Impact of Cellulose Dissolution on 1‑Butyl-3-Methylimidazolium Chloride Crystallization Studied by Raman Spectroscopy, Wide-Angle X‑ray Scattering, and Solid-State NMR
Published in Crystal growth & design (04-03-2020)“…Ionic liquid 1-butyl-3-methylimidazolium chloride (bmimCl) is a widely applied solvent for cellulose. In this work, we studied the crystallization behavior of…”
Get full text
Journal Article -
8
Postmodification with Polycations Enhances Key Properties of Alginate-Based Multicomponent Microcapsules
Published in Biomacromolecules (08-07-2024)“…Postmodification of alginate-based microspheres with polyelectrolytes (PEs) is commonly used in the cell encapsulation field to control microsphere stability…”
Get full text
Journal Article -
9
Non-covalent interactions of imidazolium-based ionic liquids with model pyrrolidones revealed by FTIR spectroscopy and quantum chemical model calculations
Published in Journal of molecular liquids (15-08-2020)“…Certain ionic liquids (ILs), such as 1-butyl-3-methylimidazolium chloride (bmimCl) and 1-ethyl-3-methylimidazolium acetate (emimAc), are potent cellulose…”
Get full text
Journal Article -
10
Non-covalent interactions in bmimCl/co-solvent mixtures: A FTIR spectroscopy and computational study
Published in Journal of molecular liquids (01-07-2019)“…Ionic liquids such as 1-butyl-3-methylimidazolium chloride (bmimCl) are efficient solvents for cellulose, but high viscosity of the resulting solutions hampers…”
Get full text
Journal Article -
11
Sulfonated polystyrenes: pH and Mg2+-insensitive amphiphilic copolymers for detergent-free membrane protein isolation
Published in European polymer journal (17-10-2023)“…[Display omitted] •A library of sulfonated polystyrenes differing in MW and polarity was synthesized.•Polymers effective in solubilizing model cell membranes…”
Get full text
Journal Article -
12
Copper Wire–Catalyzed RDRP in Nonpolar Media as a Route to Ultrahigh Molecular Weight Organic–Inorganic Hybrid Polymers
Published in Macromolecular chemistry and physics (01-07-2018)“…Controlled synthesis of high‐molecular weight (MW) organic–inorganic hybrid polymers based on polyhedral oligomeric silsesquioxane (POSS) monomers has…”
Get full text
Journal Article -
13
Tailoring Butyl Methacrylate/Methacrylic Acid Copolymers for the Solubilization of Membrane Proteins: The Influence of Composition and Molecular Weight
Published in Macromolecular bioscience (01-10-2022)“…Low‐molecular weight (MW) amphiphilic copolymers have been recently introduced as a powerful tool for the detergent‐free isolation of cell membrane proteins…”
Get full text
Journal Article -
14
SHARP hydrogel for the treatment of inflammatory bowel disease
Published in International journal of pharmaceutics (05-02-2022)“…[Display omitted] Inflammatory bowel disease (IBD) is a relapsing and remitting inflammatory disease affecting millions of people worldwide. The active phase…”
Get full text
Journal Article -
15
Polyhedral oligomeric butyl stannoxane cages (Sn-POSS) as oxidation-activated linear repairing units or crosslinking nano-building blocks, depending on structure of the polymer matrix
Published in Polymer degradation and stability (01-08-2017)“…The chemically active heavier POSS homolog, the n-butylstannoxane dodacamer cage, shows unusual stabilizing properties during an oxidizing treatment of…”
Get full text
Journal Article -
16
Diminishing the catalyst concentration in the Cu(0)‐RDRP and ATRP synthesis of well‐defined low‐molecular weight poly(glycidyl methacrylate)
Published in Journal of polymer science (2020) (01-07-2023)“…Low‐molecular weight (MW) solvent‐borne functional (meth)acrylic polymers find an important use in coating resins. However, when preparing such polymers…”
Get full text
Journal Article -
17
A systematic study of tert‐butylacrylamide‐methyl acrylate‐acrylic acid radical solution terpolymerization
Published in Canadian journal of chemical engineering (01-09-2023)“…Multi‐functional polymers used for personal care products can be synthesized by radical polymerization of acrylic acid (AA) in alcohol/water solutions with…”
Get full text
Journal Article -
18
Incorporation and chemical effect of Sn-POSS cages in poly(ethyl methacrylate)
Published in European polymer journal (01-07-2015)“…[Display omitted] •Two Sn-POSS cages were incorporated into a poly(ethyl methacrylate) matrix.•The cages are able to reconnect interrupted matrix chains during…”
Get full text
Journal Article -
19
Structural changes in alginate-based microspheres exposed to in vivo environment as revealed by confocal Raman microscopy
Published in Scientific reports (26-01-2018)“…A next-generation cure for type 1 diabetes relies on immunoprotection of insulin-producing cells, which can be achieved by their encapsulation in microspheres…”
Get full text
Journal Article -
20
Synthesis of defined polyhedral oligosilsesquioxane-containing diblock and triblock methacrylate copolymers by atom transfer radical polymerization
Published in Journal of applied polymer science (15-06-2013)“…Defined diblock and triblock copolymers composed of methyl methacrylate‐co‐glycidyl methacrylate block and…”
Get full text
Journal Article