Search Results - "Rath, Nigam"

Role of Substitution at Terminal Nitrogen of 2‑Oxo-1,2-dihydroquinoline-3-Carbaldehyde Thiosemicarbazones on the Coordination Behavior and Structure and Biological Properties of Their Palladium(II) Complexes by Ramachandran, Eswaran, Senthil Raja, Duraisamy, Rath, Nigam. P, Natarajan, Karuppannan

“…A series of four new palladium(II) complexes of 2-oxo-1,2-dihydroquinoline-3-carbaldehyde thiosemicarbazones with triphenylphosphine as coligand have been…”
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Oxidative C–C Bond Formation Reactivity of Organometallic Ni(II), Ni(III), and Ni(IV) Complexes by Watson, Michael B, Rath, Nigam P, Mirica, Liviu M

“…The use of the tridentate ligand 1,4,7-trimethyl-1,4,7-triazacyclononane (Me3tacn) and the cyclic alkyl/aryl C-donor ligand -CH2CMe2-o-C6H4- (cycloneophyl)…”
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Thermochromic and Photoresponsive Cyanometalate Fe/Co Squares: Toward Control of the Electron Transfer Temperature by Zhang, Yuan-Zhu, Ferko, Philip, Siretanu, Diana, Ababei, Rodica, Rath, Nigam P, Shaw, Michael J, Clérac, Rodolphe, Mathonière, Corine, Holmes, Stephen M

“…Two structurally related and photoresponsive cyanide-bridged Fe/Co square complexes, {Fe2Co2}, are reported:…”
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Isolated Organometallic Nickel(III) and Nickel(IV) Complexes Relevant to Carbon–Carbon Bond Formation Reactions by Schultz, Jason W, Fuchigami, Kei, Zheng, Bo, Rath, Nigam P, Mirica, Liviu M

“…Nickel-catalyzed cross-coupling reactions are experiencing a dramatic resurgence in recent years given their ability to employ a wider range of electrophiles…”
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Aerobic C-C and C-O bond formation reactions mediated by high-valent nickel species by Smith, Sofia M, Planas, Oriol, Gómez, Laura, Rath, Nigam P, Ribas, Xavi, Mirica, Liviu M

“…Nickel complexes have been widely employed as catalysts in C-C and C-heteroatom bond formation reactions. While Ni(0), Ni( i ), and Ni( ii ) intermediates are…”
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Copper(I) Complexes Containing PCP Ligand Catalyzed Hydrogenation of Carbon Dioxide to Formate under Ambient Conditions by Trivedi, Manoj, Kumar, Abhinav, Husain, Ahmad, Rath, Nigam P

“…The five new copper­(I) complexes [Cu2(μ-Cl)2(κ1-PCP t‑Bu)] (1), [Cu2(μ-Br)2(κ1-PCP t‑Bu)] (2), [Cu2(μ-I)2(κ1-PCP t‑Bu)] (3), [Cu2(μ-CN)2(κ1-PCP t‑Bu)] (4),…”
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Organometallic Nickel(III) Complexes Relevant to Cross-Coupling and Carbon–Heteroatom Bond Formation Reactions by Zheng, Bo, Tang, Fengzhi, Luo, Jia, Schultz, Jason W, Rath, Nigam P, Mirica, Liviu M

“…Nickel complexes have been widely employed as catalysts in C–C and C–heteroatom bond formation reactions. In addition to Ni(0) and Ni(II) intermediates,…”
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Carbene-Like Reactivity in an Iron Azametallacyclobutene Complex: Insights from Electronic Structure by Richards, Corey A., Rath, Nigam P., Neely, Jamie M.

“…Herein we describe our investigation into the electronic structure of the first isolated monometallic iron azametallacyclobutene complex. Computational…”
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Aromatic Cyanoalkylation through Double C–H Activation Mediated by Ni(III) by Zhou, Wen, Zheng, Shuai, Schultz, Jason W, Rath, Nigam P, Mirica, Liviu M

“…Herein we report an atom- and step-economic aromatic cyanoalkylation reaction that employs nitriles as building blocks and proceeds through Csp2 –H and Csp3 –H…”
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Detection and Characterization of Mononuclear Pd(I) Complexes Supported by N2S2 and N4 Tetradentate Ligands by Luo, Jia, Tran, Giang N, Rath, Nigam P, Mirica, Liviu M

“…Palladium is a versatile transition metal used to catalyze a large number of chemical transformations, largely due to its ability to access various oxidation…”
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Iron-Catalyzed Alkyne Carboamination via an Isolable Iron Imide Complex by Richards, Corey A, Rath, Nigam P, Neely, Jamie M

“…Transition metal imide-mediated C–N bond formation is a powerful strategy for the introduction of nitrogen into organic compounds. We have discovered that the…”
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The Aerobic Oxidation of a Pd(II) Dimethyl Complex Leads to Selective Ethane Elimination from a Pd(III) Intermediate by Khusnutdinova, Julia R, Rath, Nigam P, Mirica, Liviu M

“…Oxidation of the PdII complex (N4)PdIIMe2 (N4 = N,N′-di-tert-butyl-2,11-diaza[3.3](2,6)pyridinophane) with O2 or ROOH (R = H, tert-butyl, cumyl) produces the…”
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Aromatic Methoxylation and Hydroxylation by Organometallic High-Valent Nickel Complexes by Zhou, Wen, Schultz, Jason W, Rath, Nigam P, Mirica, Liviu M

“…Herein we report the synthesis and reactivity of several organometallic NiIII complexes stabilized by a modified tetradentate pyridinophane ligand containing…”
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Improved Oxidative C–C Bond Formation Reactivity of High-Valent Pd Complexes Supported by a Pseudo-Tridentate Ligand by Schultz, Jason W, Rath, Nigam P, Mirica, Liviu M

“…There is a large interest in developing oxidative transformations catalyzed by palladium complexes that employ environmentally friendly and economical…”
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Axial Donor Effects on Oxidatively Induced Ethane Formation from Nickel–Dimethyl Complexes by Smith, Sofia M, Rath, Nigam P, Mirica, Liviu M

“…Tetradentate pyridinophane ligands have been shown to stabilize uncommon high-valent palladium and nickel organometallic complexes. Described herein are the…”
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Indolylthio Glycosides As Effective Building Blocks for Chemical Glycosylation by Shrestha, Ganesh, Panza, Matteo, Singh, Yashapal, Rath, Nigam P, Demchenko, Alexei V

“…The S-indolyl (SIn) anomeric moiety was investigated as a new leaving group that can be activated for chemical glycosylation under a variety of conditions…”
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Stable Mononuclear Organometallic Pd(III) Complexes and Their C−C Bond Formation Reactivity by Khusnutdinova, Julia R, Rath, Nigam P, Mirica, Liviu M

“…Organometallic Pd(III) complexes have been implicated as intermediates in a number of catalytic and stoichiometric transformations. While a few dinuclear…”
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Synthesis of Phostones via the Palladium-Catalyzed Ring Opening of Epoxy Vinyl Phosphonates by Gnawali, Giri Raj, Rath, Nigam P, Spilling, Christopher D

“…The reaction of epoxy aldehydes with tetraethyl methylenediphosphonate gave γ,δ-epoxy vinyl phosphonates. The palladium-catalyzed addition of primary alcohols…”
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Mononuclear Rhodium(II) and Iridium(II) Complexes Supported by Tetradentate Pyridinophane Ligands by Fuchigami, Kei, Rath, Nigam P, Mirica, Liviu M

“…The tetradentate ligands N,N′-dialkyl-2,11-diaza­[3,3]­(2,6)­pyridinophane (RN4, where R = Me or tBu) were employed to synthesize and fully characterize…”
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Detection of Pd(III) and Pd(IV) Intermediates during the Aerobic Oxidative C–C Bond Formation from a Pd(II) Dimethyl Complex by Tang, Fengzhi, Zhang, Ying, Rath, Nigam P, Mirica, Liviu M

“…The dimethyl PdII complex (MeN4)PdIIMe2 (MeN4 = N,N′-dimethyl-2,11-diaza[3,3](2,6)pyridinophane) is readily oxidized by dioxygen in the presence of protic…”
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