Search Results - "Ratanasak, Manussada"
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Asymmetric Dehydrative Cyclization of Allyl Alcohol to Cyclic Ether Using Chiral Brønsted Acid/CpRu(II) Hybrid Catalysts: A DFT Study of the Origin of Enantioselectivity
Published in Journal of organic chemistry (07-10-2022)“…To elucidate the reaction mechanism and the origin of the enantioselectivity of the asymmetric dehydrative cyclization of allyl alcohol to cyclic ether…”
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Roles of malonate donor on activity and stereoselectivity of Ziegler–Natta catalyzed propylene polymerization
Published in Journal of organometallic chemistry (01-01-2015)“…The role of malonate compounds as electron donors in the propylene polymerization using Ziegler–Natta (ZN) catalyst were investigated. Adsorption modes of a…”
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Theoretical Study on the C–H Activation of Methane by Liquid Metal Indium: Catalytic Activity of Small Indium Clusters
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (17-10-2019)“…The mechanism of C–H activation of methane by liquid indium, which is the first step of the dehydrogenative conversion of methane to higher hydrocarbons, was…”
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Chemoselective Transesterification of Methyl (Meth)acrylates Catalyzed by Sodium(I) or Magnesium(II) Aryloxides
Published in ACS catalysis (01-01-2021)“…A highly chemoselective transesterification of methyl (meth)acrylates catalyzed by sterically demanding 2,6-di-tert-butyl-4-methylphenol-derived NaOAr or…”
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Roles of Salicylate Donors in Enhancement of Productivity and Isotacticity of Ziegler-Natta Catalyzed Propylene Polymerization
Published in Polymers (10-04-2020)“…Roles of internal salicylate donors (SID) in enhancing activity and stereoselectivity of Ziegler-Natta catalyzed propylene (PP) polymerization were examined…”
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Towards the design of new electron donors for Ziegler–Natta catalyzed propylene polymerization using QSPR modeling
Published in Polymer (Guilford) (01-01-2015)“…Electron donors enhance the productivity and isotacticity of products of the Ziegler–Natta catalyzed propylene polymerization. Using the fact that adsorption…”
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Quaternary Alkyl Ammonium Salt-Catalyzed Transformation of Glycidol to Glycidyl Esters by Transesterification of Methyl Esters
Published in ACS catalysis (02-02-2018)“…Catalytic transformation of glycidol while maintaining its epoxide moiety intact is challenging because the terminal epoxide that interacts with the hydroxyl…”
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A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts
Published in Communications chemistry (27-09-2021)“…Chemists have designed strategies that trigger the conformational isomerization of molecules in response to external stimuli, which can be further applied to…”
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Aluminum porphyrins with quaternary ammonium halides as catalysts for copolymerization of cyclohexene oxide and CO2: metal–ligand cooperative catalysis
Published in Chemical science (Cambridge) (14-06-2020)“…Bifunctional AlIII porphyrins with quaternary ammonium halides, 2-Cl and 2-Br, worked as excellent catalysts for the copolymerization of cyclohexene oxide…”
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Theoretical investigation of sustainable CO2 electroreduction to high-value products utilizing N-doped/BN-modified Triphenylene-Graphdiyne catalysts
Published in Fuel (Guildford) (01-01-2025)“…[Display omitted] •A theoretical investigation presents pristine triphenylene-graphdiyne (tpGDY), BN-modified and nitrogen-doped derivatives as…”
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One‐Step Esterification of Phosphoric, Phosphonic and Phosphinic Acids with Organosilicates: Phosphorus Chemical Recycling of Sewage Waste
Published in Angewandte Chemie International Edition (14-11-2024)“…Global concerns regarding the depletion and strategic importance of phosphorus resources have increased demand for the recovery and recycling. However,…”
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Mechanism of BPh3‐Catalyzed N‐Methylation of Amines with CO2 and Phenylsilane: Cooperative Activation of Hydrosilane
Published in Chemistry : a European journal (18-10-2022)“…BPh3 catalyzes the N‐methylation of secondary amines and the C‐methylenation (methylene‐bridge formation between aromatic rings) of N,N‐dimethylanilines or…”
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Cover Feature: Mechanism of BPh3‐Catalyzed N‐Methylation of Amines with CO2 and Phenylsilane: Cooperative Activation of Hydrosilane (Chem. Eur. J. 58/2022)
Published in Chemistry : a European journal (18-10-2022)“…BPh3 and PhSiH3, represented as the stars Hikoboshi and Orihime, constitute a powerful catalytic system for deoxygenative CO2 conversions. According to a…”
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Mechanism of BPh 3 ‐Catalyzed N‐Methylation of Amines with CO 2 and Phenylsilane: Cooperative Activation of Hydrosilane
Published in Chemistry : a European journal (18-10-2022)“…BPh 3 catalyzes the N‐methylation of secondary amines and the C‐methylenation (methylene‐bridge formation between aromatic rings) of N , N ‐dimethylanilines or…”
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Bulky magnesium() and sodium() bisphenoxide catalysts for chemoselective transesterification of methyl (meth)acrylates
Published in Chemical science (Cambridge) (18-01-2023)“…Given the industrial importance of (meth)acrylate esters, various groups have devoted considerable effort to investigating their chemoselective…”
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DFT insight into metals and ligands substitution effects on reactivity of phenoxy-imine catalysts for ethylene polymerization
Published in Journal of molecular graphics & modelling (01-12-2023)“…The reaction mechanism of ethylene (ET) polymerization catalyzed by the phenoxy-imine (FI) ligands using DFT calculations was studied. Among five possible…”
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Exploring the Reaction Mechanism of Heterobimetallic Nickel‐Alkali Catalysts for Ethylene Polymerization: Secondary‐Metal‐Ligand Cooperative Catalysis
Published in ChemCatChem (07-07-2022)“…In this work, we explored the reaction mechanism of heterobimetallic nickel phenoxyphosphine polyethylene glycol (Ni‐PEG) with alkali metals (M+=Li+, Na+, K+,…”
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Mechanism of the Asymmetric Dehydrative Allylative Cyclization of Alcohols to Cyclic Ethers Catalyzed by a CpRu Complex of the Chiral Picolinic Acid-Type Ligand, Cl-Naph-PyCOOH: Is a π-Allyl Intermediate Present?
Published in Bulletin of the Chemical Society of Japan (15-02-2021)“…[Ru(II)Cp((R)-Cl-Naph-PyCOOH)]PF6 ((R)-1) catalyzes the dehydrative cyclization of (E)-hept-2-ene-1,7-diol (2) to 2-vinyltetrahydro-2H-pyran (3) with a 97:3…”
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Effects of shape, size, and pyrene doping on electronic properties of graphene nanoflakes
Published in Journal of molecular modeling (01-12-2017)“…Effects of size, shape, and pyrene doping on electronic properties of graphene nanoflakes (GNFs) were theoretically investigated using density functional…”
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