Search Results - "Raptopoulou, C. P"
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Hydrogels containing water soluble conjugates of silver(I) ions with amino acids, metabolites or natural products for non infectious contact lenses
Published in Dalton transactions : an international journal of inorganic chemistry (12-10-2021)“…The poor handling and hygiene practices of contact lenses are the key reasons for their frequent contamination, and are responsible for developing ocular…”
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pH-Specific Hydrothermal Assembly of Binary and Ternary Pb(II)-(O,N-Carboxylic Acid) Metal Organic Framework Compounds: Correlation of Aqueous Solution Speciation with Variable Dimensionality Solid-State Lattice Architecture and Spectroscopic Signatures
Published in Inorganic chemistry (03-09-2012)“…Hydrothermal pH-specific reactivity in the binary/ternary systems of Pb(II) with the carboxylic acids N-hydroxyethyl-iminodiacetic acid (Heida),…”
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Heptanuclear Antiferromagnetic Fe(III)–d‑(-)-Quinato Assemblies with an S = 3/2 Ground StatepH-Specific Synthetic Chemistry, Spectroscopic, Structural, and Magnetic Susceptibility Studies
Published in Inorganic chemistry (16-12-2013)“…Iron is an essential metal ion with numerous roles in biological systems and advanced abiotic materials. d-(-)-Quinic acid is a cellular metal ion chelator,…”
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A Unique Dinuclear Mixed V(V) Oxo-peroxo Complex in the Structural Speciation of the Ternary V(V)-Peroxo-citrate System. Potential Mechanistic and Structural Insight into the Aqueous Synthetic Chemistry of Dinuclear V(V)-Citrate Species with H2O2
Published in Inorganic chemistry (21-11-2011)“…Diverse vanadium biological activities entail complex interactions with physiological target ligands in aqueous media and constitute the crux of the undertaken…”
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Vanadium(IV)−Citrate Complex Interconversions in Aqueous Solutions. A pH-Dependent Synthetic, Structural, Spectroscopic, and Magnetic Study
Published in Inorganic chemistry (05-11-2001)“…Citrate is abundantly encountered in biological fluids as a natural metal ion chelator. Vanadium participates in biological processes as a catalyst in the…”
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Manganese Citrate Chemistry: Syntheses, Spectroscopic Studies, and Structural Characterizations of Novel Mononuclear, Water-Soluble Manganese Citrate Complexes
Published in Inorganic chemistry (04-09-2000)“…The first two mononuclear manganese citrate complexes, (NH4)4[MnII(C6H5O7)2] (1) and (NH4)5[MnIII(C6H4O7)2]·2H2O (2) were synthesized in aqueous solutions near…”
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pH-Specific Structural Speciation of the Ternary V(V)–Peroxido–Betaine System: A Chemical Reactivity-Structure Correlation
Published in Inorganic chemistry (04-06-2012)“…Vanadium involvement in cellular processes requires deep understanding of the nature and properties of its soluble and bioavailable forms arising in aqueous…”
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Synthesis and Spectroscopic and Structural Studies of a New Cadmium(II)−Citrate Aqueous Complex. Potential Relevance to Cadmium(II)−Citrate Speciation and Links to Cadmium Toxicity
Published in Inorganic chemistry (21-04-2003)“…The presence of cadmium in the environment undoubtedly contributes to an increased risk of exposure and ultimate toxic influence on humans. In an effort to…”
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Aromatic Chelator-Specific Lattice Architecture and Dimensionality in Binary and Ternary Cu(II)-Organophosphonate Materials
Published in Inorganic chemistry (06-05-2013)“…Synthetic efforts linked to the design of defined lattice dimensionality and architecture materials in the binary/ternary systems of Cu(II) with butylene…”
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A New Dinuclear Ti(IV)−Peroxo−Citrate Complex from Aqueous Solutions. Synthetic, Structural, and Spectroscopic Studies in Relevance to Aqueous Titanium(IV)−Peroxo−Citrate Speciation
Published in Inorganic chemistry (28-07-2003)“…The wide use of titanium in applied materials has prompted pertinent studies targeting the requisite chemistry of that metal's biological interactions. In…”
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Correlations of Synthetic, Spectroscopic, Structural, and Speciation Studies in the Biologically Relevant Cobalt(II)−Citrate System: The Tale of the First Aqueous Dinuclear Cobalt(II)−Citrate Complex
Published in Inorganic chemistry (13-01-2003)“…Synthetic efforts targeting soluble species of Co(II) with the low molecular mass physiological ligand citric acid led to the isolation of the first dinuclear…”
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pH-Specific Synthesis and Spectroscopic, Structural, and Magnetic Studies of a Chromium(III)−Citrate Species. Aqueous Solution Speciation of the Binary Chromium(III)−Citrate System
Published in Inorganic chemistry (16-04-2007)“…In an attempt to understand the aqueous interactions of Cr(III) with the low-molecular-mass physiological ligand citric acid, the pH-specific synthesis in the…”
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Mononuclear Titanium(IV)−Citrate Complexes from Aqueous Solutions: pH-Specific Synthesis and Structural and Spectroscopic Studies in Relevance to Aqueous Titanium(IV)−Citrate Speciation
Published in Inorganic chemistry (18-04-2005)“…Titanium is a metal frequently employed in a plethora of materials supporting medical applications. In an effort to comprehend the involvement of titanium in…”
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Synthesis, pH-Dependent Structural Characterization, and Solution Behavior of Aqueous Aluminum and Gallium Citrate Complexes
Published in Inorganic chemistry (09-04-2001)“…Reactions of Al(III) and Ga(III) with citric acid in aqueous solutions, yielded the complexes (NH4)5{M(C6H4O7)2}·2H2O (M(III) = Al (1), Ga (2)) at alkaline pH,…”
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Hydrothermal Synthesis and Characterization of 2D M(II)-Quinate (M = Co,Zn) Metal−Organic Lattice Assemblies: Solid-State Solution Structure Correlation in M(II)-Hydroxycarboxylate Systems
Published in Inorganic chemistry (20-12-2010)“…Co(II) and Zn(II) ions exhibit variable reactivity toward O-containing ligands in aqueous media, affording isolable materials with distinct solid-state lattice…”
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pH-Specific Synthesis of a Dinuclear Vanadium(V)−Peroxo−Citrate Complex in Aqueous Solutions: pH-Dependent Linkage, Spectroscopic and Structural Correlations with Other Aqueous Vanadium(V)−Peroxo−Citrate and Non-Peroxo Species
Published in Inorganic chemistry (03-05-2004)“…Aqueous reactions of V2O5 or VCl3 in the presence of the physiological citric acid and hydrogen peroxide, in a pH specific fashion, afforded a new…”
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Synthesis and Structural and Spectroscopic Characterization of a Complex between Co(II) and Imino-bis(methylphosphonic acid): Gaining Insight into Biologically Relevant Metal−Ion Phosphonate Interactions or Looking at a New Co(II)−Organophosphonate Material?
Published in Inorganic chemistry (01-07-2002)“…Cobalt is an essential metal ion involved in key biomolecules, regulating processes in human physiology. As a metal ion, Co(II) assumes forms, which are…”
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pH-Dependent Investigations of Vanadium(V)−Peroxo−Malate Complexes from Aqueous Solutions. In Search of Biologically Relevant Vanadium(V)−Peroxo Species
Published in Inorganic chemistry (16-07-2001)“…The established biochemical potential of vanadium has spurred considerable research interest in our lab, with specific focus on pertinent synthetic studies of…”
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Comparative Study of Structure−Properties Relationship for Novel β-Halogenated Lanthanide Porphyrins and Their Nickel and Free Bases Precursors, as a Function of Number and Nature of Halogens Atoms
Published in Inorganic chemistry (20-05-2002)“…The synthetic route of partially β-halogenated via a “metal-assisted” reaction and perhalogenated terbium complexes is described. This protocol allows the…”
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