Search Results - "Rapenne , Gwénaël"
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1
Molecular Gears: From Solution to Surfaces
Published in Chemistry : a European journal (19-08-2021)“…This review highlights the major efforts devoted to the development of molecular gears over the past 40 years, from pioneering covalent bis‐triptycyl systems…”
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2
Procrystalline Self-Assembly of Desymmetrized Pentaphenylcyclopentadiene
Published in The journal of physical chemistry letters (01-08-2024)“…The interplay between the molecular shape and the intermolecular interaction plays a decisive role in self-assembled structures. Recently, inherent randomness…”
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3
Hierarchical Emergence and Dynamic Control of Chirality in a Photoresponsive Dinuclear Complex
Published in The journal of physical chemistry letters (03-05-2018)“…Chiroptical photoswitches are of interest from a viewpoint of applications in advanced information technologies. We report dynamic on–off photoswitching of…”
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4
Scorpionate Hydrotris(indazolyl)borate Ligands as Tripodal Platforms for Surface-Mounted Molecular Gears and Motors
Published in European journal of inorganic chemistry (01-06-2016)“…This microreview describes the use of scorpionate hydrotris(indazolyl)borate ligands to build structurally rigid bifunctional surface‐mounted molecular gears…”
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5
Synthesis and Dynamic Behavior of Ce(IV) Double-Decker Complexes of Sterically Hindered Phthalocyanines
Published in Molecules (Basel, Switzerland) (17-02-2024)“…Phthalocyanines and their double-decker complexes are interesting in designing rotative molecular machines, which are crucial for the development of molecular…”
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6
Divergent Synthesis of Molecular Winch Prototypes
Published in Chemistry : a European journal (22-11-2021)“…We report the synthesis of conceptually new prototypes of molecular winches with the ultimate aim to investigate the work performed by a single ruthenium‐based…”
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7
Extended Tripodal Hydrotris(indazol‐1‐yl)borate Ligands as Ruthenium‐Supported Cogwheels for On‐Surface Gearing Motions
Published in Chemistry : a European journal (03-04-2023)“…This paper reports the synthesis of ruthenium‐based molecular gear prototypes composed of a brominated or non‐brominated pentaphenylcyclopentadienyl ligand as…”
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8
Energy Storage upon Photochromic 6‑π Photocyclization and Efficient On-Demand Heat Release with Oxidation Stimuli
Published in The journal of physical chemistry letters (25-11-2021)“…Photochromic molecules display reversible isomerization reactions between two isomers accompanied by an exchange between heat and chemical potential. A…”
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9
Mechanics of Molecule-Gears with Six Long Teeth
Published in Journal of physical chemistry. C (15-10-2020)“…On a Pb(111) surface in its superconducting state, the construction of a train of two and three hexa-tert-butylbiphenylbenzene molecule-gears (HB-BPB) is…”
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10
Transmitting Stepwise Rotation among Three Molecule-Gear on the Au(111) Surface
Published in The journal of physical chemistry letters (20-08-2020)“…The realization of a train of molecule-gears working under the tip of a scanning tunneling microscope (STM) requires a stable anchor of each molecule to the…”
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11
Biomimetic and Technomimetic Single Molecular Machines
Published in Chemistry letters (05-04-2019)“…This highlight review describes our contribution to the field of biomimetic and technomimetic molecular machines specially designed to be studied as single…”
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12
A chiral molecular propeller designed for unidirectional rotations on a surface
Published in Nature communications (20-08-2019)“…Synthetic molecular machines designed to operate on materials surfaces can convert energy into motion and they may be useful to incorporate into solid state…”
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13
Desymmetrised pentaporphyrinic gears mounted on metallo-organic anchors
Published in Chemical science (Cambridge) (18-02-2021)“…Mastering intermolecular gearing is crucial for the emergence of complex functional nanoscale machineries. However, achieving correlated motion within trains…”
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14
Molecular Rotor Functionalized with a Photoresponsive Brake
Published in Inorganic chemistry (15-03-2021)“…A molecular motor that has been previously shown to rotate when fueled by electrons through a scanning tunneling microscope tip has been functionalized with a…”
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15
Expedient Synthesis of Thioether‐Functionalized Hydrotris(indazolyl)borate as an Anchoring Platform for Rotary Molecular Machines
Published in European journal of organic chemistry (16-09-2018)“…Major improvements in the synthesis of surface‐mounted rotary molecular machines based on ruthenium(II) complexes are reported. The development of a one‐pot…”
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16
Dual Photochemical Bond Cleavage for a Diarylethene-Based Phototrigger Containing both Methanolic and Acetic Sources
Published in Journal of organic chemistry (18-11-2016)“…In this paper, we present a novel concept for “smarter” photolabile organic compounds combining not one but two caged functions. As proof of principle, this…”
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17
Scanning Tunneling Microscope Tip-Induced Formation of a Supramolecular Network of Terarylene Molecules on Cu(111)
Published in Journal of physical chemistry. C (16-11-2017)“…Bottom-up approaches allow for molecular-level control of engineering new nanostructures. For next-generation molecular circuits, machines, and phase-change…”
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18
Star‐Shaped Ruthenium Complexes as Prototypes of Molecular Gears
Published in Chemistry : a European journal (18-12-2019)“…The design and synthesis of two families of molecular‐gear prototypes is reported, with the aim of assembling them into trains of gears on a surface and…”
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19
Terarylenes as Photoactivatable Hydride Donors
Published in Journal of organic chemistry (16-11-2018)“…Terarylene frameworks containing benzothiazole as a photoprecursor of hydride donors are presented. We here report on two new scaffolds along with their…”
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20
Dipolar Nanocars Based on a Porphyrin Backbone
Published in Chemistry : a European journal (16-09-2020)“…The design and synthesis of a new family of nanocars is reported. To control their motion, we integrated a dipole which can be tuned thanks to strategic donor…”
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