Search Results - "Randoll, Sören"
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Stereospecific Octahedral Group 4 Bis(phenolate) Ether Complexes for Olefin Polymerization
Published in Journal of the American Chemical Society (28-04-2010)“…Octahedral group 4 bisphenolate ether complexes, activated by methylaluminoxane, are highly active and stereospecific α-olefin polymerization catalysts. X-ray…”
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Imidazolin-2-iminato Complexes of Rare Earth Metals with Very Short Metal−Nitrogen Bonds: Experimental and Theoretical Studies
Published in Inorganic chemistry (15-06-2009)“…The reactions of 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-imine (ImDippNH, 1-H) with trimethylsilylmethyl lithium (LiCH2SiMe3) and anhydrous rare earth metal…”
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3
Quinine-Derived Imidazolidin-2-imine Ligands: Synthesis, Coordination Chemistry, and Application in Catalytic Transfer Hydrogenation
Published in ZAAC - Journal of Inorganic and General Chemistry (01-04-2010)“…Two new optically active bidentate N,N‐ligands, DMIQCI (3a) and DMIQCD (3b), containing a quinuclidine core and an imidazolidin‐2‐imine unit, were synthesized…”
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4
Secondary Interactions in Phosphane‐Functionalized Group 4 Cycloheptatrienyl–Cyclopentadienyl Sandwich Complexes
Published in Chemistry : a European journal (01-01-2009)“…Twice as reactive: The coordination chemistry of phosphane‐functionalized Zr and Hf cycloheptatrienyl–cyclopentadienyl complexes gives rise to unusual…”
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5
Cooperative Binding of Phosphate Anion and a Neutral Nitrogen Donor to Alkaline-Earth Metal Ions. Investigation of Group 2 Metal−Organophosphate Interaction in the Absence and Presence of 1,10-Phenanthroline
Published in Inorganic chemistry (07-07-2008)“…Alkaline-earth metal phosphates containing nitrogen-donor ligands have been prepared by the reaction of alkaline-earth metal acetates M(OAc)2·xH2O (M = Mg, Ca,…”
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6
Synthesis and Reactivity of Silicon- and Germanium-Bridged ansa-Cycloheptatrienyl−Cyclopentadienyl Titanium Complexes
Published in Organometallics (15-01-2007)“…A new type of ansa-cycloheptatrienyl−cyclopentadienyl complex with germanium as a bridging atom has been synthesized. Using the established route for the…”
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7
Syntheses and structures of mononuclear lutetium imido complexes with very short Lu-N bonds
Published in Chemical communications (Cambridge, England) (01-01-2007)“…The reaction of 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-imine (ImDippNH) with trimethylsilylmethyllithium and anhydrous lutetium trichloride affords the…”
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8
Synthesis and Reactivity of 16-Electron Cycloheptatrienyl-Molybdenum(0) Complexes with Bis(imidazolin-2-imine) Ligands
Published in Organometallics (25-02-2008)“…The reaction of the ligands 1,2-bis(1,3-diisopropyl-4,5-dimethylimidazolin-2-imino)ethane (BL iPr) and 1,2-bis(1,3,4,5-tetramethylimidazolin-2-imino)ethane…”
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9
Structural and theoretical investigation of 2-iminoimidazolines--carbene analogues of iminophosphoranes
Published in Organic & biomolecular chemistry (01-01-2007)“…The preparation of 2-iminoimidazolines - has been accomplished by the Staudinger reaction of the carbenes 1,3-di-tert-butylimidazolin-2-ylidene (),…”
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10
Chromium Complexes with Me2Si-Bridged Cyclopentadienyl-imidazolin-2-imine Ligands: Synthesis, Structure, and Use in Ethylene Polymerization Catalysis
Published in Organometallics (14-07-2008)“…Imidazolin-2-imino-functionalized tetramethylcyclopentadienes 3-H have been prepared in high yields by the reaction of 2 equiv of…”
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11
Imidazolin-2-iminato titanium complexes: synthesis, structure and use in ethylene polymerization catalysis
Published in Dalton transactions : an international journal of inorganic chemistry (21-01-2006)“…The Staudinger reaction of the imidazolin-2-ylidenes, 1,3-di-tert-butylimidazolin-2-ylidene (1a), 1,3-diisopropylimidazolin-2-ylidene (1b),…”
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Bis(η-cyclo-hepta-trien-yl)tri-μ-hydrido-dimolybdenum(0,I)
Published in Acta crystallographica. Section E, Structure reports online (17-12-2008)“…In the title compound, [Mo(2)(η(7)-C(7)H(7))(2)(μ-H)(3)], which displays crystallographic mirror symmetry, two (η(7)-C(7)H(7))Mo units are linked along the…”
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14
Adduct formation of [(η 7-C 7H 7)Zr(η 5-C 5H 5)] with phosphines and N-heterocyclic carbenes: An experimental and theoretical study
Published in Inorganica Chimica Acta (01-12-2006)“…The reaction of the sandwich compound [(η 7-C 7H 7)Zr(η 5-C 5H 5)] with the Lewis bases PMe 3 and [:C{N(Me)C(Me)} 2] have been investigated in the solid state…”
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15
Stereoselective allyl transfer to chiral α-methoxycarbaldehydes: A model study related to the C-9/C-15 fragment of geldanamycin
Published in Bioorganic & medicinal chemistry (15-09-2006)“…The enantiomerically pure α-methoxycarbaldehyde 3 was prepared from l-leucine in five steps and 31% overall yield. The aldehyde was subjected to a…”
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Stereoselective and regioselective propylene polymerization with group 4 bisphenolate ether complexes
Published in Journal of polymer science. Part A, Polymer chemistry (01-07-2012)“…Octahedral group 4 bisphenolate ether complexes, activated by methylaluminoxane, were tested in propylene polymerization in the presence and absence of diethyl…”
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Synthesis and Reactivity of 16-Electron Pentamethylcyclopentadienyl-Ruthenium(II) Complexes with Bis(imidazolin-2-imine) Ligands
Published in European Journal of Inorganic Chemistry (01-08-2007)“…The 1,2‐bis(imidazolin‐2‐imino)ethane ligands BLMe and BLiPr were prepared, in which the ability of the imidazolium moiety to effectively stabilize a positive…”
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