Search Results - "Ramu, M"
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Buchwald–Hartwig Amination of Nitroarenes
Published in Angewandte Chemie International Edition (16-10-2017)“…The Buchwald–Hartwig amination of nitroarenes was achieved for the first time by using palladium catalysts bearing dialkyl(biaryl)phosphine ligands. These…”
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2
Reductive Denitration of Nitroarenes
Published in Organic letters (16-03-2018)“…The Pd-catalyzed reductive denitration of nitroarenes has been achieved via a direct cleavage of the C–NO2 bonds. The catalytic conditions reported exhibit a…”
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3
The Suzuki–Miyaura Coupling of Nitroarenes
Published in Journal of the American Chemical Society (19-07-2017)“…Synthesis of biaryls via the Suzuki–Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies…”
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4
Pd(II)-Catalyzed Primary-C(sp3)–H Acyloxylation at Room Temperature
Published in Organic letters (20-07-2012)“…With the aid of a novel S-methyl-S-2-pyridyl-sulfoximine (MPyS) directing group (DG), the unactivated primary β-C(sp3)–H bond of MPyS-N-amides oxidizes at room…”
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5
Investigation on para‐aramid fiber‐reinforced poly‐ether ketone‐ketone high‐performance composite for ballistic application
Published in Polymer composites (10-06-2024)“…This investigation highlights the performance of high‐performance polymeric composite for ballistic application. Therefore, reinforcement of para‐aramid fiber…”
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6
Photoinduced Alkyl/Aryl Radical Cascade for the Synthesis of Quaternary CF3‑Containing Oxindoles and Indoline Alkaloids
Published in Journal of organic chemistry (05-05-2023)“…Metal- and additive-free, photoinduced decarboxylative radical alkylation–cyclization of CF3-acrylamides with alkyl redox-active esters provided the…”
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7
Sulfoximine Directed Intermolecular o‑C–H Amidation of Arenes with Sulfonyl Azides
Published in Organic letters (05-04-2013)“…The Ru(II)-catalyzed intermolecular o-C–H amidation of arenes in N-benzoylated sulfoximine with sulfonyl azides is demonstrated. The reaction proceeds with…”
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8
Sulfoximine-Directed Ruthenium-Catalyzed ortho-C–H Alkenylation of (Hetero)Arenes: Synthesis of EP3 Receptor Antagonist Analogue
Published in Journal of organic chemistry (03-07-2014)“…The reusable sulfoximine directing-group-assisted Ru(II)-catalyzed chemo- and regioselective ortho-C–H alkenylation of arenes and heteroarenes with…”
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9
Photoinduced Alkyl/Aryl Radical Cascade for the Synthesis of Quaternary CF 3 -Containing Oxindoles and Indoline Alkaloids
Published in Journal of organic chemistry (05-05-2023)“…Metal- and additive-free, photoinduced decarboxylative radical alkylation-cyclization of CF -acrylamides with alkyl redox-active esters provided the…”
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10
Sulfoximines: A Reusable Directing Group for Chemo- and Regioselective ortho CH Oxidation of Arenes
Published in Chemistry : a European journal (27-04-2012)“…Sulfoximines direct: A new protocol for the chemo‐ and regioselective ortho CH acetoxylation of arenes in N‐benzoylated sulfoximines is reported. The…”
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11
Pd(II)-Catalyzed ortho-C–H Oxidation of Arylacetic Acid Derivatives: Synthesis of Benzofuranones
Published in Organic letters (07-02-2014)“…Pd(II)-catalyzed ortho-C–H acetoxylation of arylacetic acid derivatives is demonstrated with the aid of a novel S-methyl-S-2-pyridylsulfoximine (MPyS)…”
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12
Ultimate Spin Currents in Commercial Chemical Vapor Deposited Graphene
Published in ACS nano (27-10-2020)“…Establishing ultimate spin current efficiency in graphene over industry-standard substrates can facilitate research and development exploration of spin current…”
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13
Cu(I)/N,N-Imine Ligand Catalyzed C(sp3)–C(sp) Coupling of Alkyl Bromides with Alkynes: Scope and Mechanistic Investigation
Published in Organic letters (28-07-2023)“…We have developed an efficient Cu/N,N-bidentate imine ligand catalytic system for C(sp3)–C(sp) coupling to obtain internal alkynes, di/trisubstituted allenes…”
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14
Sulfoximine Assisted Pd(II)-Catalyzed Bromination and Chlorination of Primary β‑C(sp3)–H Bond
Published in Organic letters (17-10-2014)“…S-Methyl-S-2-pyridyl-sulfoximine (MPyS) directed bromination and chlorination of the 1°-β-C(sp3)–H bond of MPyS-N-amides is realized under the influence of…”
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15
Ru(II)-catalyzed intermolecular ortho-C-H amidation of aromatic ketones with sulfonyl azides
Published in Chemical communications (Cambridge, England) (07-06-2013)“…Ru(II)-catalyzed intermolecular ortho-C-H amidation of weakly coordinating aromatic ketones with sulfonyl azides is reported. The developed reaction protocol…”
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16
Ruthenium-Catalyzed ortho-C–H Mono- and Di-imidation of Arenes with N‑Tosyloxyphthalimide
Published in Organic letters (17-04-2015)“…The Ru(II)-catalyzed imidation of the o-C–H bond in arenes with N-tosyloxyphthalimide is realized with the assistance of a methyl phenylsulfoximine (MPS)…”
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17
High current limits in chemical vapor deposited graphene spintronic devices
Published in Nano research (01-04-2023)“…Understanding the stability and current-carrying capacity of graphene spintronic devices is key to their applications in graphene channel-based spin current…”
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18
Pd-Catalyzed Cascade Heck/C(sp3)–H Activation for Spirocyclopropyl Oxindoles
Published in Organic letters (21-06-2024)“…We have demonstrated a Pd(0)-catalyzed Heck/C(sp3)–H activation cascade for the synthesis of spirocyclopropyl oxindoles in high yields from easily accessible…”
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19
Organocatalytic strategy for hydrophenolation of gem-difluoroalkenes
Published in Tetrahedron (09-08-2019)“…Gem-difluoroalkenes are an easily accessed fluorinated functional group, and a useful intermediate for elaborating into more complex fluorinated compounds…”
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20
Reusable and Removable Directing Groups for C(sp2)−H Bond Functionalization of Arenes
Published in Asian journal of organic chemistry (01-09-2015)“…This review highlights the importance of removable and reusable directing groups in C−H activation. The functionalization of unactivated sp2 C−H bonds assisted…”
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