Search Results - "Ramirez de Arellano, Carmen"
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Experimental and theoretical insights in the alkene-arene intramolecular π-stacking interaction
Published in Beilstein journal of organic chemistry (28-07-2016)“…Chiral acrylic esters derived from biomass were developed as models to have a better insight in the aryl-vinyl π-stacking interactions. Quantum chemical…”
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Two Complementary Approaches to Silicon-Supported Soluble [FeFe]-Hydrogenase Mimics
Published in Organometallics (28-11-2022)“…Two series of silicon-supported [(μ-SCH2)2NRFe2(CO)6] (R = p-OHC6H4, 3, and (CH2)2OH, 4a, and (CH2)5OH, 4b) hydrogenase mimics, as well as…”
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Phosphite Bearing [(μ-ADT)RFe2(CO)6] (ADT = Azadithiolate) Moieties: A Tool for the Building of Multimetallic [FeFe]-Hydrogenase Mimics
Published in Organometallics (27-02-2023)“…A new phosphite ligand having three [(μ-ADT)RFe2(CO)6] (R= p-HOC6H4) moieties (2) has been prepared in good yield by the reaction of complex [(μ-ADT)RFe2(CO)6]…”
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Straightforward Synthesis of α‑Chloromethylketimines Catalyzed by Gold(I). A Clean Way to Building Blocks
Published in Journal of organic chemistry (04-03-2022)“…α-Chloromethylketimines have been obtained through a gold-catalyzed hydroamination of aromatic and aliphatic 1-chloroalkynes with aromatic amines by using…”
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5
A new family of "clicked" estradiol-based low-molecular-weight gelators having highly symmetry-dependent gelation ability
Published in Chemical communications (Cambridge, England) (07-10-2011)“…Reported herein is the discovery of a novel family of "clicked" estradiol-based LMWGs whose gelation ability highly depends on the gelator symmetry. These…”
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Selective “One-Pot” Synthesis of Functionalized Cyclopentenones
Published in Journal of organic chemistry (20-07-2012)“…Double addition (1,2–1,4) of vinyl magnesium bromide to squaric acid derivatives allows the preparation of polyoxygenated cyclopentenones (8) in a “one-pot”…”
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[3.3]Ferrocenophanes with Guanidine Bridging Units as Multisignalling Receptor Molecules for Selective Recognition of Anions, Cations, and Amino Acids
Published in Chemistry : a European journal (01-01-2007)“…The synthesis, electrochemical, and optical properties of a new [3.3]ferrocenophane framework in which two ferrocene subunits, with similar electronic…”
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Synthesis of Oxaspiranic Compounds through [3 + 2] Annulation of Cyclopropenones and Donor–Acceptor Cyclopropanes
Published in Journal of organic chemistry (16-01-2015)“…The Sc(OTf)3-catalyzed [3 + 2]-annulation reaction between cyclopropenones and donor–acceptor cyclopropanes is described. The process leads directly to the…”
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9
Competitive Gold-Activation Modes in Terminal Alkynes: An Experimental and Mechanistic Study
Published in Chemistry : a European journal (13-01-2014)“…The competition between π‐ and dual σ,π‐gold‐activation modes is revealed in the gold(I)‐catalyzed heterocyclization of 1‐(o‐ethynylaryl)urea. A noticeable…”
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10
Ion Pair Recognition Receptor Based on an Unsymmetrically 1,1′-Disubstituted Ferrocene–Triazole Derivative
Published in Journal of organic chemistry (16-11-2012)“…The ferrocene–triazole derivative 4, available from 1,1′-bis(diazido)ferrocene by sequential functionalization through click-type chemistry and the Staudinger…”
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Clicking Azides and Alkynes with Poly(pyrazolyl)borate-Copper(I) Catalysts: An Experimental and Computational Study
Published in Catalysts (01-08-2019)“…The synthesis of 1,4-disubstituted-1,2,3-triazoles under a copper(I)-catalyzed azide−alkyne cycloaddition (CuAAC) regime was accomplished in high yields and a…”
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Remote Control by π‑Conjugation of the Emissive Properties of Fischer Carbene-BODIPY Dyads
Published in Inorganic chemistry (21-03-2016)“…The synthesis, structure, and complete characterization of mono- and bimetallic dyads joining Fischer carbene complexes and BODIPY chromophores are reported…”
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NHC-Stabilized Gold(I) Complexes: Suitable Catalysts for 6-exo-dig Heterocyclization of 1-(o-Ethynylaryl)ureas
Published in Organic letters (07-05-2010)“…3-substituted 1-(o-ethynylaryl)ureas 1 selectively undergo either 6-exo-dig or 5-endo-dig cyclization (to give 4-methylene-3,4-quinazolin-2-ones 2 or indoles…”
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[(Pyridylcarbonyl)pyridyl]triazolopyridines, Useful Ligands for the Construction of Polynuclear Coordination Compounds - Synthesis, Crystal Structure and Magnetic Properties of a Novel Tetranuclear Copper(II) Cubane
Published in European Journal of Inorganic Chemistry (01-10-2007)“…A new tetranuclear cubane Cu4O4 complex has been synthesised from assembly of CuII ions and the polydentate ligand…”
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On the Use of Metal Purine Derivatives (M=Ir, Rh) for the Selective Labeling of Nucleosides and Nucleotides
Published in Chemistry : a European journal (24-03-2014)“…The reactions of neutral or cationic IrIII and RhIII derivatives of phenyl purine nucleobases with unsymmetrical alkynes produce new metallacycles in a…”
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16
Direct Assembly of Polyarenes via C−C Coupling Using PIFA/BF3·Et2O
Published in Journal of the American Chemical Society (29-12-2010)“…Direct oxidative Kita-type coupling between naphthalene and substituted benzenes was found to proceed via four-component coupling, leading to a linear…”
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Electrocatalytic Behavior of Tetrathiafulvalene (TTF) and Extended Tetrathiafulvalene (exTTF) [FeFe] Hydrogenase Mimics
Published in ACS Organic & Inorganic Au (02-02-2022)“…TTF- and exTTF-containing [(μ-S2)Fe2(CO)6] complexes have been prepared by the photochemical reaction of TTF or exTTF and [(μ-S2)Fe2(CO)6]. These complexes…”
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18
Alternating Ferro/Antiferromagnetic Copper(II) Chain Containing an Unprecedented Triple Formato/Hydroxido/Sulfato Bridge
Published in Inorganic chemistry (07-03-2016)“…The first example of a triple formato/hydroxido/sulfato (FHS) bridge for any metal is reported in compound [Cu2(bpym)(OH)(HCO2)(SO4)(H2O)2]·3H2O (1). Its…”
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Synthesis of Known and Previously Inaccessible Poly(pyrazolyl)Borates under Mild Conditions
Published in Journal of organic chemistry (07-07-2023)“…Poly(pyrazolyl)borate ligands have been obtained through the reaction of highly reactive haloboranes with in situ formed pyrazolides under very mild…”
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Host-Guest Chemistry: Oxoanion Recognition Based on Combined Charge-Assisted C−H or Halogen-Bonding Interactions and Anion⋅⋅⋅Anion Interactions Mediated by Hydrogen Bonds
Published in Chemistry : a European journal (23-05-2016)“…Several bis‐triazolium‐based receptors have been synthesized and their anion‐recognition capabilities have been studied. The central chiral 1,1′‐bi‐2‐naphthol…”
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